===================== Product Identification =====================
MSDS NAME:"SUVA" MP39 (R401A)
NIIN:01-391-9303
Status Code:A
MSDS Number: CJMHJ
=== Responsible Party ===
Company:DUPONT CHEMICALS
Address:1007 MARKET STREET
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-441-3637
Resp. Party Other MSDS Num.:3030FR
Chemtrec Ind/Phone:(800)424-9300
CAGE:KO192
=== Contractor Identification ===
Company:CONTRACTED OPERATIONS LOUISVILLE PACKAGING
Address:7753 NATIONAL TURNPIKE
Box:UNKNOW
City:LOUISVILLE
State:KY
ZIP:40214
Country:US
Phone:502-363-8000/2663
CAGE:089V0
Company:DU PONT FLUOROPRODUCTS
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:1-800-441-7515
Contract Num:SP045099MJG93
CAGE:2S827
Company:DUPONT CHEMICALS
Address:1007 MARKET STREET
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515/800-441-3637
CAGE:KO192
Company:DUPONT CHEMICALS
Address:CHESTNUT RUN
Box:80709
City:WILMINGTON
State:DE
ZIP:19880-0709
Country:US
Phone:302-999-4946
CAGE:TO002
============= Composition/Information on Ingredients =============
Name:CHLORODIFLUOROMETHANE (SARA 313) (CERCLA) (HCFC22)
CAS:75-45-6
RTECS #:PA6390000
= Wt:53.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9596
Ozone Depleting Chemical:2
Name:1,1-DIFLUOROETHANE (HFC152A)
CAS:75-37-6
RTECS #:KI1410000
= Wt:13.
Other REC Limits:NONE RECOMMENDED
Name:2-CHLORO-1,1,1,2-TETRAFLUOROETHANE (SARA 313) (HCFC 124)
CAS:2837-89-0
= Wt:34.
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF HIGH VAP0R CONCENTRATION
IS HARMFUL & MAY CAUSE HEART IRREGULARITIES, UNCONSCIOUSNESS, OR
DEATH. INTENTINAL MISUSE/DELIBERATE INHALATION MAY CAUSE DEATH
WITHOUT WARNING. VAPOR REDUCES OX YGEN AVAILABLE FOR BREATHING & IS
HEAVIER THAN AIR. LIQUID CONTACT CAN CAUSE FROSTBITE.
Explanation of Carcinogenicity:NONE OF THE COMPONENTS PRESENT AT
CONCENTRATIONS EQUAL TOOR GREATER THAN0.1% ARE LISTED BY
IARC,NTP,OSHA OR ACGIH AS A CARCINOGEN.
Effects of Overexposure:SKIN CONTACT MAY CAUSE FROSTBITE FROM EXPOSURE
TO THE LIQUID. INHALATION MAY INCLUDE NONSPECIFIC DISCOMFORT, SUCH
AS NAUSEA, OR WEAKNESS; OR TEMPORARY NERVOUS SYSTEM DEPRESSION WITH
ANESTHETIC EFFECTS SUCH AS DIZZINESS, HEADACHE,
CONFUSION,INCOORDINATION, & LOSS OF CONSCIOUSNESS. HIGHER EXPOSURES
TO VAPORS MAY LEAD OF THESE EFFECTS: TEMPORARY LUNG IRRITATION
EFFECTS WITH COUGH, DISCOMFORT, DIFFICU LTY BREATHING, TEMPORARY
ALTERATION OF THE HEART'S ELECTRICAL ACTIVITY WITH IRREGULAR PULSE,
PALPITATIONS, OR INADEQUATE CIRCULATION, ABNORMAL KIDNEY FUNCTION
OR FATALITY.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING
DISEASES OF THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM, LUNGS OR
KIDNEYS MAY HAVE INCREASE SUSCEPTIBILITY TO TOXICITY OF EXCESSIVE
EXPOSURES.
======================= First Aid Measures =======================
First Aid:INHALATION-IF HIGHER CONCENTRATIONS ARE INHALED, IMMEDIATELY
REMOVE TO FRESH AIR. KEEP PERSON CALM. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING DIFFICULT, GIVE OXYGEN. CALL A
PHYSICI AN. SKIN-FLUSH WITH WATER FOR 15 MIN. SEEK MEDICAL
ASSISTANCE IF IRRITATION PERSISTS. TREAT FOR FROSTBITE IF NEEDED BY
GENTLY WARMING AFFECTED AREA. EYES- IMMEDIATELYFLUSH EYES WITH
PLENTY OF WATER FO R 15 MIN. CALL A PHYSICIAN. INGESTION-NOT
CONSIDERED POTENTIAL EXPOSURE ROUTE.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:WILL NOT BURN
Autoignition Temp:=681.1C, 1258.F
Extinguishing Media:USE MEDIA APPROPRIATE FRO SURROUNDING MATERIAL.
Fire Fighting Procedures:COOL TANK/CONTAINER WITH WATER SPRAY.
SELF-CONTAINED BREATHING APPARATUS (SCBA) MAY BE REQUIRED IF
CYLINDERS RUPTURE OR RELEASE PRODUCT UNDER FIRE CONDITIONS.
Unusual Fire/Explosion Hazard:CYLINDERS MAY RUPTURE UNDER FIRE
CONDITIONS. DECOMPOSITION MAY OCCUR.
================== Accidental Release Measures ==================
Spill Release Procedures:COMPLY WITH FEDERAL, STATE, LOCAL REGULATIONS
FOR REPORTING RELEASES. USE APPROPR RIATE PERSONAL PROTITIVE
EQUIPMENT DURING CLEAN-UP. VENTILATE AREA, ESPECIALLY LOW OR
ENCLOSED PLACES WHERE HEAVY VAPA PORS MIGHT COLLECT. REMOVE OPEN
FLAMES.USE SELF-CONTAINED BREATHING APPARATUS (SCBA) IF LARGE SPILL
OR LEAK OCCURS.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID BREATHING VAPORS OR MIST. AVOID
CONTACT WITH EYES OR SKIN. USE WITH SUFFICIENT VENTILATION TO KEEP
WORKER EXPOSURE BELOW RECOMMENDED LIMITS. STORE IN A CLEAN, DRY
PLACE. DO NOT HEAT ABOVE 126F (52C).
Other Precautions:REFRIGERANT CONCENTRATION MONITORS MAY BE NECESSARY
TO DETERMINE VAPOR CONCENTRATIONS IN WORK AREAS, PRIOR TO USE OF
TORCHES OR OTHER OPEN FLAMES, OR IF WORKERS ENTER ENCLOSED AREAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS, NO
RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.
SELF-CONTAINED BREATHING APPARATUS (SCBA) IS REQUIRED IF LARGE
RELEASE OCCURS.
Ventilation:USE SUFFICIENT VENTILATION TO KEEP WORKER EXPOSURE BELOW
RECOMMENDED EXPOSURE LIMITS. LOCAL EXHAUST FOR LARGE AMOUNTS .
MECHANICAL IN LOW OR ENCLOSED PLACES.
Protective Gloves:LINED BUTYL GLOVES.
Eye Protection:CHEMICAL SPLASH GOGGLES.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:G3
Boiling Pt:=-32.8C, -27.F
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:112.1 PSIA AT 77F
Vapor Density:3.3 @26C
Spec Gravity:1.194 GM/CC @25C
pH:NP
Viscosity:NP
Evaporation Rate & Reference:>1, CCL4=1.0
Solubility in Water:0.1 WT % @26C, SLIGHT
Appearance and Odor:CLEAR, COLORLESS LIQUIFIED GAS, ETHER (SLIGHT) ODOR
Percent Volatiles by Volume:100
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE WITH ALKALI OR ALKALINE EARTH METALS-POWDERED AL, ZN, BE,
ETC.
Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:CAN DECOMPOSE BY HIGH TEMPERATURES
(OPEN FLAMES, GLOWING METAL SURFACES, ETC) FORMING HYDROCHLORIC AND
HYDROFLUORIC ACIDS, AND POSSIBLY CARBONYL HALIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:ANIMAL DATA: THE BLEND IS UNTESTED.
CHLORODIFLUOROMETHANE (HCFC-22). INHALATION 4-HOUR LC50: 220,000
PPM IN RATS. THE COMPOUND ISA SKIN IRRITANT AND A SLIGHT EYE
IRRITANT, BUT IS NOT A SKIN SENSITIZER IN ANIMALS. EFFECTS FROM
SINGLE HIGH EXPOSURES INCLUDE CENTRAL NERVOUS SYSTEM DEPRESSION,
ANESTHESIA, RAPID BREATHING, LUNG CONGESTION AND MICROSCOPIC LIVER
CHANGES. CARDIAC SENSITIZATION OCCURRED IN DOGS AT 50,000PPM OR
GREATER FROM THE ACTION OF EXOGENOUS EPINEPHRINE.
===================== Ecological Information =====================
Ecological:AQUATIC TOXICITY: HCFC-22. 48 HOUR EC50 - DAPHNIA MAGNA: 433
MG/L.
==================== Disposal Considerations ====================
Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION AND DIAPOSAL
MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, PROVINCIAL,
AND LOCAL REGULATIONS. RECOVER BY DISTILLATION OR REMOVE TO A
PERMITTED WASTE DISPOSAL FACILITY.
=================== MSDS Transport Information ===================
Transport Information:DOT/IMO PROPER SHIPPING NAME: LIQUEFIEDGAS,
N.O.S. (CHLORODIFLUOROMETHANE AND CHLOROTETRAFLUOROETHANE). HAZARD
CLASS: 2.2. UN NO.: 3163. DOT/IMO LABEL: NONFLAMMABLE GAS.
===================== Regulatory Information =====================
SARA Title III Information:ACUTE: YES. CHRONIC: NO. FIRE: NO.
REACTIVITY: NO. PRESSURE: YES. SARA EXTREMELY HAZARDOUS
SUBSTANCE:NO.
Federal Regulatory Information:TSCA INVENTORY STATUS:
REPORTED/INCLUDED. CERCLA HAZARDOUS SUBSTANCE: NO.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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