===================== Product Identification =====================
MSDS NAME:MAPPOLENE
NIIN:00N091857
Status Code:A
MSDS Number: CJPRB
=== Responsible Party ===
Company:BOC GROUP INC THE
Address:575 MOUNTAIN AVE
City:MURRAY HILL
State:NJ
ZIP:07974
Country:US
Info Phone Num:908-464-8100
Emergency Phone Num:905-501-0802
Resp. Party Other MSDS Num.:G-55
Chemtrec Ind/Phone:(800)424-9300
CAGE:80382
=== Contractor Identification ===
Company:BOC GASES, A DIVISION OF THE BOC GROUP, INC
Address:575 MOUNTAIN AVENUE
Box:City:MURRAY HILL
State:NJ
ZIP:07974
Country:US
Phone:908-464-8100
CAGE:80382
============= Composition/Information on Ingredients =============
Name:PROPYLENE
CAS:115-07-1
RTECS #:UC6740000
> Wt:96.
OSHA PEL:SIMPLE ASPHYXIANT
ACGIH TLV:SIMPLE ASPHYXIANT
Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
< Wt:4.
OSHA PEL:1800 MG/M3;1000 PPM
ACGIH TLV:SIMPLE ASPHYXIANT
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HEALTH EFTS - EXPOS LIMITS: NO;
IRRITANT: YES; SENSIT: NO; TERATOGEN: NO; REPRO HAZ: NO; MUTAGEN:
NO; SYNERGISTIC EFTS: NONE REPORTED. EYE EFTS: NONE ANTIC AS PROD
IS GAS AT ROOM TEMP. SKIN EFTS: NONE ANTIC. INGEST EFTS: INGEST IS
UNLIKELY. INHAL EFTS: PROD IS RELATIVELY NONTOXIC. SIMPLE
HYDROCARBONS CAN IRRIT EYES, MUC MEMBS & RESP SYSTEM AT HIGH CONCS.
INHAL OF HIGH CONCS MAY CAUSE DIZZ, DISORIE NTATION, INCOORD,
NARCOSIS, NAUS OR NARCOTIC EFTS. THIS PROD MAY DISPLACE OXYGEN IF
RELEASED IN CONFINED SPACE. MAINTAIN OXYGEN LEVELS ABOVE 19.5% AT
SEA LEVEL TO PREVENT ASPHYXIATION. EFTS OF OXYGEN DEFICIENCY RSLTG
FROM (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZS: SIMPLE ASPHYXIANTS MAY INCL: RAPID
BRTHG, DIMINISHED MENTAL ALERTNESS, IMPAIRED MUS COORD, FAULTY
JUDGMENT, DEPRESSION OF ALL SENSATIONS, EMOTIONAL INSTABILITY &
FATIGUE. AS ASPHYXIANT PROG RESSES, NAUS, VOMIT, PROSTRATION & LOSS
OF CONSCIOUSNESS MAY RSLT, EVENTUALLY LEADING TO CONVULSIONS, COMA
& DEATH. OXYGEN DEFICIENCY DURING PREGNANCY HAS PRODUCED
DEVELOPMENTAL ABNORMS IN HUMANS & EX PERIMENTAL ANIMALS. NFPA HAZ
CODES - HEALTH: 1; FLAMMABILITY: 4; REACTIVITY: 0. HMIS HAZ CODES -
HEALTH: 1; FLAMMABILITY: 4; REACTIVITY: 0. RATING SYSTEM - 0=NO
HAZ; 1=SLIGHT HAZ; 2=MOD HAZ; 3=SERIOUS HAZ; 4=SEV HAZ.
======================= First Aid Measures =======================
Eyes: IMMED FLUSH EYES W/POTABLE WATER FOR AT LST 15 MIN.
SEEK ASSISTANCE FROM MD . NEVER INTRODUCE OIL OR OINTMENT INTO EYES
W/OUT MED ADVICE! IF PAIN IS PRESENT, REFER VICTIM TO
OPHTHALMOLOGIS T FOR FURTHER TREATMENT & FOLLOW UP. SKIN: REMOVE
CONTAM CLTHG & FLUSH AFFECTED AREA W/COLD WATER & SOAP. IF IRRIT
PERSISTS, SEEK MED ATTN. INGEST: NOT NORMALLY REQD. SEEK IMMED MED
ATTN. INHAL: PROMP T MED ATTN IS MANDATORY IN ALL CASES OF OVEREXP
TO PROD. RESCUE PERS SHOULD BE EQUIPPED W/NIOSH APPRVD SCBA.
CONSCIOUS PERSONS SHOULD BE ASSISTED TO UNCONTAM AREA & INHALE
FRESH AIR. QUICK REMOVAL FRO M (SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=-107.8C, -162.F
Lower Limits:2.0%
Upper Limits:11.1%
Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . IF
POSS, STOP FLOW OF GAS W/REMOTE VALVE. USE WATER SPRAY TO COOL FIRE
EXPOSED CNTNRS. IF FIRE IS EXTINGUISHED & FLOW OF GAS IS CONTINUED,
INCREASE VENT TO PVNT A BUILD UP OF FLAMMABLE/EXPLOSIVE
ATMOSPHERE. EXTING SOURCES OF IGNIT. BE CAUTIOUS OF (STATE REG
INFO)
Unusual Fire/Explosion Hazard:THIS PRODUCT WILL IGNITE AT AMBIENT
TEMPERATURES & CAN BE EXPECTED TO FORM A FLAMMABLE MIXTURE UPON
RELEASE TO ATMOSPHERE. MAY BURN W/ALMOST INVISIBLE FLAME IN BRIGHT
LIGHT. CNDTNS OF FLAMMABILITY: FL AMMABLE LIQUID & VAPOR.
SENSITIVITY TO MECHANICAL SHOCK: NONE. SENSITIVITY TO STATIC
DISCHARGE: NOT AVAILABLE.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL PERS FROM AFFECTED AREA. USE
APPROP PROT EQUIP. INCREASE VENT TO PREVENT BUILD UP OF
FLAMMABLE/EXPLOSIVE ATMOSPHERE. EXTINGUISH ALL SOURCES OF IGNIT! IF
LEAK IS IN USER'S EQUIP, BE CERTAI N TO PURGE PIPING W/INERT GAS
PRIOR TO ATTEMPTING REPAIRS. IF LEAK IS IN CNTNR OR CNTNR VALVE,
CONTACT APPROP EMERGENCY TELEPHONE NUMBER LISTED IN SECTION 1 OR
CALL YOUR CLOSEST BOC LOCATION.
====================== Handling and Storage ======================
Handling and Storage Precautions:EARTH BOND & GROUND ALL LINES & EQUIP
ASSOC W/PROD SYS. ELEC EQUIP SHOULD BE NON-SPARKING & EXPLOSION
PROOF. USE ONLY IN WELL-VENTD AREAS. VALVE PROT CAPS MUST REMAIN IN
PLACE UNLESS CNTNR IS SECURED W/VALVE OUTLET PIPED TO USE POINT.
DO NOT DRAG, SLIDE OR ROLL CYLS. USE (SUPDAT)
Other Precautions:PROTECT CYLS FROM PHYSICAL DMG. STORE IN COOL, DRY,
WELL-VENTD AREA AWAY FROM HEAVILY TRAFFICKED AREAS & EMER EXITS. DO
NOT ALLOW TEMP WHERE CYLS ARE STORED TO EXCEED 130F(54C). CYLS
SHOULD BE STORED UPRIGHT & FIRMLY SECURED TO PVNT FALLING OR BEING
KNOCKED OVER. FULL & EMPTY CYLS SHOULD BE (ECOLOGI CAL INFO)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED POSITIVE PRESSURE AIR LINE WITH
FULL-FACE MASK AND ESCAPE BOTTLE OR SELF-CONTAINED BREATHING
APPARATUS SHOULD BE AVAILABLE FOR EMERGENCY USE.
Ventilation:USE LOC EXHST TO PVNT ACCUM. USE GEN VENT TO PREVENT BUILD
UP OF FLAMMABLE CONCS. MAY USE HOOD W/FORCED VENT WHEN HNDLG SMALL
QTYS. IF (STATE REG INFO)
Protective Gloves:PLASTIC RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
SAFETY SHOES.
Supplemental Safety and Health
FIRST AID PROC: CONTAM AREA IS MOST IMPORTANT. UNCON PERSONS SHOULD BE
MOVED TO UNCONTAM AREA, GIVEN ASSISTED (ARTF) RESP & SUPPLEMENTAL
OXYGEN. FURTHER TREATMENT SHOULD BE SYMPTOMATIC & SUPPORTIVE. H
NDLG/STOR PRECS: SUITABLE HAND TRUCK FOR CYL MOVEMENT. USE PRESS
REGULATOR (OTHER INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:=-47.8C, -54.F
Melt/Freeze Pt:M.P/F.P Text:NOT AVAIL
Vapor Pres:136 PSIA @ 70F
Vapor Density:NOT AVAIL
Spec Gravity:NOT AVAILABLE
pH:NOT AVAILABLE
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:0.018 WT% @ 100F
Appearance and Odor:A COLORLESS GAS WITH A NATURAL GAS ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, MINERAL ACIDS, HALOGENATED COMPOUNDS, NITROGEN DIOXIDE,
MOLTEN SULFUR.
Stability Condition to Avoid:KEEP AWAY FROM OPEN FLAMES, OXYGEN AND
OXIDIZING MATERIALS.
Hazardous Decomposition Products:CARBON MONOXIDE.
=================== Toxicological Information ===================
Toxicological Information:OXYGEN DEFICIENCY DURING PREGNANCY HAS
PRODUCED DEVELOPMENTAL ABNORMALITIES IN HUMANS AND EXPERIMENTAL
ANIMALS. NO CHRONIC EFFECTS DATA GIVEN IN REGISTRY OF TOXIC EFFECTS
OF CHEMICAL SUBSTANCES (RTECS ) OR SAX, DANGEROUS PROPERTIES OF
INDUSTRIAL MATERIALS, 7TH ED. LD50 OR LC50 FOR INGREDIENTS: NOT
AVAILABLE.
===================== Ecological Information =====================
Ecological:NO DATA GIVEN. --OTHER PRECS: SEGREGATED. USE "FIRST
IN-FIRST OUT" INVENTORY SYSTEM TO PREVENT FULL CYLS FROM BEING
STORED FOR EXCESSIVE PERIODS OF TIME. POST "NO SMOKING" SIGNS IN
STORAGE OR USE AREA S. FOR ADDNL RECOMS CONSULT COMPRESSED GAS
ASSOCIATION PAMPHLET P-1. NEVER CARRY COMPRESSED GAS CYL OR CNTNR
OF GAS IN CRYOGENIC LIQ FORM IN ENCLOSED SPACE SUCH AS CAR TRUNK,
VAN OR STATION WAGON. A L EAK CAN RESULT IN FIRE, EXPLOSION,
ASPHYXIATION OR A TOXIC EXPOSURE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . DO NOT ATTEMPT TO DISPOSE OF RESIDUAL
WASTE OR UNUSED QUANTITIES. RETURN IN SHIPPING CONTAINER PROPERLY
LABELED WITH AN Y VALVE OUTLET PLUGS OR CAPS SECURED AND VALVE
PROTECTION CAP IN PLACE TO BOC GASES OR AUTHORIZED DI STRIBUTOR FOR
PROPER DISPOSAL.
=================== MSDS Transport Information ===================
Transport Information:US DOT - PROPER SHIPPING NAME: PETROLEUM GASES,
LIQUEFIED; HAZARD CLASS: 2.1; IDENTIFICATION NUMBER: UN 1075;
SHIPPING LABEL: FLAMMABLE GAS. CANADA TDG - PROPER SHIPPING NAME:
PETROLEUM GASES, LIQUEFI ED; HAZARD CLASS: 2.1; IDENTIFICATION
NUMBER: UN 1075; SHIPPING LABEL: FLAMMABLE GAS.
===================== Regulatory Information =====================
SARA Title III Information:SARA TITLE III - SECTION 313 SUPPLIER
NOTIFICATION: THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE
EMERGENCY PLANNING AND COMMUNITY RIG HT-TO-KNOW ACT (EPCRA) OF 1986
AND OF 40 CFR 372: CAS NUMBER: 115-07-1; INGREDIENT NAME:
PROPYLENE; PERCENT BY VOLUME: >96.0. THIS INFORMATION MUST BE
INCLUDED ON ALL MSDSS THAT ARE COPIED AND DISTRIB UTED FOR THIS
MATERIAL. SARA TITLE III - HAZARD CLASSES: ACUTE HEALTH HAZARD;
FIRE HAZARD; SUDDEN RELEASE OF PRESSURE HAZARD.
Federal Regulatory Information:PROPYLENE & PROPANE ARE LISTED UNDER
ACCIDENT PREVENTION PROVISIONS OF SECTION 112(R) OF CLEAN AIR ACT
(CAA) W/THRESHOLD QTYS (TQS) OF 10,000 LBS. WHMIS CLASSIFICATION:
A, B1, D2B. EXPOS LIMS(*): PROP YLENE - PEL-OSHA(**): SIMPLE ASPHY;
TLV-ACGIH(***): SIMPLE ASPHY. PROPANE - PEL-OSHA(**): 1000 PPM;
TLV-ACGIH(***): SIMPLE ASPHY. * =REFER TO INDIVIDUAL STATE OF
PROVINCIAL REGS, AS APPLIC, FOR LIMS W HICH MAY BE MORE STRINGENT
THAN THOSE LISTED HERE. ** = AS STATED IN 29 CFR 1910, SUBPART Z
(REVISED JULY 1, 1993). *** = AS STATED IN ACGIH 1994-1995 TLVS
FOR CHEMICAL SUBSTANCES & PHYSICAL AGENTS.
State Regulatory Information:N/P --FIRE FIGHT PROC: BOILING LIQUID
EVAPORATING VAPOR EXPLOSION, BLEVE, IF FLAME IS IMPINGING ON
SURROUNDING CNTNRS. DIRECT 500 GPM WATER STREAM ONTO CNTNRS ABOVE
LIQ LEVEL W/REMOTE MONITORS. LIMIT NUMBER OF PERS IN PROXIMITY TO
FIRE. EVACUATE SURROUNDING AREAS TO AT LEAST 3000 FEET IN ALL
DIRECTIONS. --VENT: PROD IS HANDLED ROUTINELY WHERE POTNTL FOR
LEAKS EXISTS, ALL ELEC EQUIP MUST BE RATED F OR USE IN POTENTIALLY
FLAMMABLE ATMOSPHERES. CONSULT NATIONAL ELECTRICAL CODE FOR
DETAILS. --PHYSICA L DATA - PHYSICAL STATE: GAS; OIL/WATER
PARTITION COEFFICIENT: NOT AVAIL; ODOR THRESHOLD: NOT AVAIL.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|