===================== Product Identification =====================
MSDS NAME:HYDROXYLAMINE HYDROCHLORIDE,CRYSTAL,2196
Status Code:A
MSDS Number: CJRHG
=== Responsible Party ===
Company:MALLINKRODT BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:908-859-2151
Resp. Party Other MSDS Num.:HS960-06
Chemtrec Ind/Phone:(800)424-9300
CAGE:70829
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:HYDROXYAMINE HYDROCHLORIDE
CAS:5470-11-1
RTECS #:NC3675000
Minumum % Wt:96.
Maxumum % Wt:100.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: BASED ON ANIMAL DATA MAY CAUSE
BLOOD DISORDERS AND/OR CYANOSIS (BLUE-GREY SKIN AND LIPS CAUSED BY
LACK OF OXYGEN). INHAL: HARMFUL IF INHALED. DUST IRRITATING TO
RESPIRATORY TRACT. INHAL: HEADAC HE, COUGHING, DIFFICULT BREATHING,
CHEST PAINS. SEV LUNG IRRIT, PULM EDEMA. SKIN/EYE CONT: SEV IRRIT
OR BURNS. SKIN ABSORP: DERMATITIS. INGEST: IS HARMFUL & MAY BE
FATAL. CYANOSIS, CONVULSIONS, PARALY SIS. BURNS TO MOUTH & THROAT.
CHRONIC EFTS: DMG TO BLOOD, LIVER, KIDNEYS, SPLEEN, HEART, STOMACH,
LUNGS, CAUSES METHEMOGLOBULIN FORMATION IN BLOOD. REPRODUCTIVE
EFTS: TESTS ON LAB ANIMALS INDICATE MAT L (EFTS OF OVEREXP)
Explanation of Carcinogenicity:THE MATERIAL IS NOT LISTED (IARC, NTP,
OSHA) AS CANCER CAUSING AGENT.
Effects of Overexposure:HLTH HAZS: MAY BE MUTAGENIC AND TERATOGENIC.
TARGET ORGANS: BLOOD, LIVER, KIDNEYS, EYES, SKIN, LUNGS, SPLEEN,
HEART, STOMACH.
Medical Cond Aggravated by Exposure:RESPIRATORY SYSTEM DISEASE, KIDNEY,
LIVER, OR BLOOD DISORDERS.
======================= First Aid Measures =======================
First Aid:INGEST: CALL PHYS. IF SWALLOWED, IF CONSCIOUS, GIVE LG AMTS
OF WATER. INDUCE VOMIT. INHAL: IF INHALED, REMOVE TO FRESH AIR. IF
NOT BRTHG, GIVE ARTIF RESP. IF BRTHG IS DFCLT, GIVE OXYG. PROMPT
ACTION I S ESSENTIAL. SKIN CONT: IMMEDIATELY FLUSH W/PLENTY OF
WATER FOR AT LEAST 15 MINUTES. EYE CONT: IMMEDIATELY FLUSH W/PLENTY
OF WATER FOR AT LEAST 15 MINUTES.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT ( ). MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE
WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
EXPLOSION DATA-SENSITIVI TY TO MECHANICAL IMPACT: YES. EXPLOSION
DATA -SENSITIVITY TO STATIC DISCHARGE: NONE IDENTIFIED.
Unusual Fire/Explosion Hazard:MATL NORMALLY STABLE, BUT BECOMES
UNSTABLE WHEN EXPOSED TO HEAT, MECHANICAL SHOCK/FRICTION,
W/VIOLENT DECOMP. CLSD CNTNRS EXPOSED TO HEAT MAY EXPLODE. TOXIC
GASES PRDCD: AMMONIA, HYDROGEN CHLORID E, OXIDES OF NITROGEN.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT CLTHG. WITH
CLEAN SHOVEL, PLACE MATL INTO CLEAN, DRY CONTAINER AND COVER. MOVE
CONTAINER(S) FROM SPILL AREA. FLUSH AREA WITH FLOODING AMOUNTS OF
WATER. (USE CAUTION) .
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD. STORE IN
COOL, DRY, WELL-VENTILATED AREA AWAY FROM HEAT, SPARKS/FLAME.
ISOLATE FROM INCOMPAT MATLS. AVOID TEMPS >100C. VIOLENTLY
DECOMPOSES >150C MATL IS HYGROSCOPIC. POISON D ANGER. POSS BIRTH
DEFECT HAZARD MAY CAUSE BIRTH DEFECTS BASED ON ANIMAL DATA.
Other Precautions:MAY BE FATAL IF SWALLOWED. HIGHLY CORR TO TISS.
MODERATELY COMBUSTIBLE SOLID HEAT/CONT W/OTHER MATL MAY CAUSE
FIRE/EXPLO DECOMP. AVOID CONT W/EYES, SKIN, CLTHG. DO NOT BREATHE
DUST. KEEP IN TIGHTLY CL SD CNTNR. USE W/ADEQ VENT. RISK OF SERIOUS
DMG TO EYES. POSSIBLE SENSITIZER. TAKE OFF IMMED ALL (SUP DAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENT CONDITIONS
EXIST. IF AIRBORNE CONCENTRATION IS HIGH, A NIOSH APPROVED
DUST/MIST RESPIRATOR IS RECOMMENDED. IF CONCENTRATION EXCEEDS
CAPACITY OF RESPIRATOR, A NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS IS ADVISED.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
FUME OR DUST LEVELS AS LOW AS POSSIBLE.
Protective Gloves:RUBBER GLOVES ARE RECOMMENDED.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . UNIFORM AND APRON ARE RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
OTHER PREC: CONTAMD CLTHG. KEEP IN TIGHTLY CLSD CNTNR. IN CASE OF FIRE,
USE WATER SPRAY. FOAM, DRY CHEM/CARBON DIOXIDE, FLUSH SPILL AREA
W/WATER SPRAY. HARMFUL BY INHAL & IF SWALLOWED. IRRIT TO EYES &
SKIN. KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM FOOD, DRINK &
ANIMAL FEEDING STUFFS.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:=150.6C, 303.F
M.P/F.P Text:DECOMPOSES
Spec Gravity:1.67 (H*2O =1)
Solubility in Water:APPRECIABLE (>10%)
Appearance and Odor:COLORLESS CRYSTALS. ODORLESS.
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES, STRONG OXIDIZING AGENTS, COPPER, ALUMINUM, IRON.
Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION,
SHOCK, MOISTURE.
Hazardous Decomposition Products:OXIDES OF NITROGEN, AMMONIA, HYDROGEN
CHLORIDE.
=================== Toxicological Information ===================
Toxicological Information:TOXICITY OF COMPONENTS: ORAL MOUSE LD50 FOR
HYDROCYLAMINE HYDROCHLORIDE 408 MG/KG. INTRAPERITONEAL MOUSE LD50
FOR HYDROXYLAMINE HYDROCHLORIDE 100 MG/KG. REPRODUCTIVE EFTS: TEST
ON LAB ANIMAL INDICATE MATERIAL MAY BE MUTAGENIC & TERATOGENIC.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE, AND LOCAL ENVIORNMENTAL REGULATIONS. EPA HAZARDOUS
WASTE NUMBER: D003 (REACTIVE WASTE).
=================== MSDS Transport Information ===================
Transport Information:DOMESTIC D.O.T. PROPER SHIPPING NAME: CORROSIVE
SOLID, ACIDIC, INORGANIC N.O.S. (HYDROXYLAMINE HYDROCHLORIDE).
HAZARD CLASS8. UN/NA: UN3260. LABELS: 8 CORROSIVE. REGULATORY
REFERENCES: 49CFR 172.101. PACKING GROUP: III. INTERNATION
(I.M.O.) PROPER SHIPPING NAME: CORROSIVE SOLID, ACIDIC, INORGANIC,
N.O.S. (HYDROXYLAMINE HYDROCHLORIDE). HAZARD CLASS: 8. UN: UN3260.
MARINE POLLUTANTS: NO. LABELS: 8 C ORR. REGULATORY REFERENCES:
49CFR PART 176; IMDG CODE. I.MO.O. PAGE: 8150-1. PACKING GROUP:
III. AIR (.C.A.O.). PROPER SHIPPING NAME: CORROSIVE SOLID, ACIDIC,
INORGANIC, (OTHER INFO)
===================== Regulatory Information =====================
SARA Title III Information:SARA TITLE III HAZARD CATEGORIES AND LISTS:
ACUTE: YES, CHRONIC: YES, FLAMMABILITY: YES, PRESSURE: NO,
REACTIVITY: YES. EXTREMELY HAZARDOUS SUBSTANCE: NO. CERCLA
HAZARDOUS SUBSTANCE: NO. SARA 313 TOXIC CHEMICALS: NO. TSCA
INVENTORY: YES.
State Regulatory Information:
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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