===================== Product Identification =====================
MSDS NAME:PHENOL, CRYSTALS, H602
Status Code:A
MSDS Number: CJTFM
=== Responsible Party ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:908-859-2151
Resp. Party Other MSDS Num.:P1949
Chemtrec Ind/Phone:(800)424-9300
CAGE:70829
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:PHENOL
CAS:108-95-2
RTECS #:SJ3325000
Minumum % Wt:99.
Maxumum % Wt:100.
OSHA PEL:19 MG/M3;5 PPM
ACGIH TLV:19 MG/M3;5 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL, RAT) 317 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MAJOR HAZ OF PHENOL IS ITS ABILITY TO
PENETRATE SKIN RAPIDLY, PARTICULARLY WHEN LIQ, CAUSING SEV INJURY
WHICH CAN BE FATAL. PHENOL ALSO HAS STRONG CORROSIVE EFT ON BODY
TISS CAUSING SEV CHEM BURNS. DU E TO ITS LOCAL ANESTHETIZING
PROPERTIES, SKIN BURNS MAY BE PAINLESS. INHAL: BRTHG VAP, DUST OR
MIST RSLTS IN DIGESTIVE DISTURBS (VOMIT, DFCLTY IN SWALLOWING,
DIARR, LOSS OF APPETITE). WILL IRRIT, POSS IBLY BURN RESP TRACT.
OTHER SYMPS LISTED UNDER INGEST MAY ALSO OCCUR. INGEST: POISON.
SYMPS MAY INCL BURNING PAIN IN MOUTH & THROAT, ABDOMINAL PAIN,
NAUS, VOMIT, HDCH, DIZZ, MUSC WEAK, CNS EFTS, INCR IN HEART RATE,
(EFTS OF OVEREXP)
Effects of Overexposure:HLTH EFTS: IRREGULAR BRTHG, COMA & POSS DEATH.
ACUTE EXPOS IS ALSO ASSOCIATED W/KIDNEY & LIVER DMG. INGESTION OF 1
GRAM HAS BEEN LETHAL TO HUMANS. SKIN CNTCT: CORROSIVE. RAPIDLY
ABSORBED THRU SKIN W/S YSTEMIC POISONING EFTS TO FOLLOW.
DISCOLORATION & SEV BURNS MAY OCCUR, BUT MAY BE DISGUISED BY LOSS
IN PAIN SENSATION. EYE CNTCT: CORROSIVE. EYE BURNS W/REDNESS, PAIN,
BLURRED VISION MAY OCCUR. MAY CA USE SEV DMG & BLINDNESS. CHRONIC
EXPOS: RPTD EXPOS MAY CAUSE SYMPS DESCRIBED FOR ACUTE POISONING AS
WELL AS EYE & SKIN DISCOLORATION.
Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN, EYE OR
CENTRAL NERVOUS SYSTEM DISORDERS, OR IMPAIRED LIVER, KIDNEY OR PULM
FUNCTION MAY BE MORE SUSCEPTIBLE TO EFTS OF THIS SUBSTANCE.
======================= First Aid Measures =======================
First Aid:IN CASE OF PHENOL POISONING, START FIRST AID TREATMENT IMMED,
THEN GET MED ATTN. PEOPLE ADMIN FIRST AID SHOULD TAKE PRECS TO
AVOID CNTCT W/PHENOL. PHENOL ANTIDOTE KIT (CASTOR OIL/OTHER
VEGETABLE OIL, POLYETHYLENE GLYCOL 300) SHOULD BE AVAILIN PHENOL
WORK AREA. PLAN & PRACTICE ACTIONS TO BE TAKEN IN CASE OF PHENOL
POIS BEFORE BEGINNING WORK W/PHENOL. CASTOR OIL &/OR POLYETHYLENE
GLYCOL CAN BE GIVEN BY FIRST RESPONDER BEFORE MED HELP ARRIVES.
INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG
DFCLT, GIVE OXYG. GET MED ATTN IMMED. INGEST: IMMED ADMIN CASTOR
OIL/OTHER VEGETABLE OIL. NEVER GIVE ANYTHING BY (SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=79.C, 174.2F
Autoignition Temp:=715.C, 1319.F
Lower Limits:1.3%
Upper Limits:8.6%
Extinguishing Media:WATER SPRAY, DRY CHEM, ALCOHOL FOAM OR CARBON
DIOXIDE. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS
COOL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . STRUCTURAL FIREFIGHTER'S PROTECTIVE CLOTHING IS
INEFFECTIVE FOR FIRES INVOLVING THIS MATERIAL. STAY AWAY FROM
SEALED CONTAINERS.
Unusual Fire/Explosion Hazard:FIRE: COMBUSTIBLE. CONTACT WITH STRONG
OXIDIZERS MAY CAUSE FIRE. EXPLOSION: ABOVE FLASH POINT, VAPOR-AIR
MIXTURES ARE EXPLOSIVE WITHIN FLAMMABLE LIMITS NOTED ABOVE. SEALED
CONTAINERS MAY RUPTURE WHEN HEATED.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL IGNIT SOURCES. VENT AREA OF
LEAK/SPILL. WEAR APPROP PPE AS SPECIFIED. CLEAN UP SPILLS IN MANNER
THAT DOES NOT DISPERSE DUST INTO AIR. USE NON-SPKG TOOLS & EQUIP.
REDUCE AIRBORNE DUST & PVNT SCATTERING BY MOISTENING W/WATER. PICK
UP SPILL FOR RECOVERY/DISP & PLACE IN CLSD CNTNR. DO NOT FLUSH TO
SEWER. DRY LIME/SODA ASH MAY BE USED ON SPILL FOR NEUT. US REGS
(CERCLA) REQ (SARA INFO)
Neutralizing Agent:DRY LIME OR SODA ASH MAY BE USED ON SPILL FOR
NEUTRALIZATION.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN TIGHTLY CLSD CNTNR. STORE IN
COOL, DRY, VENTD AREA AWAY FROM HEAT/IGNIT SOURCES. PROTECT AGAINST
PHYSICAL DMG. STORE SEPARATELY FROM REACTIVE OR COMBUST MATLS & OUT
OF DIRECT SUNLIGHT. AVOID D UST FORM & CTL IGNIT SOURCES. EMPLOY
GROUNDING, VENTING & EXPLO RELIEF PROVISIONS (FED REG INFO)
Other Precautions:EMPTY ONLY INTO INERT/NON-FLAM ATM; EMPTYING INTO
NON-INERT ATM WHERE FLAM VAPS MAY BE PRESENT COULD CAUSE FLASH
FIRE/EXPLO DUE TO ELECTROSTATIC DISCHARGE. PROPERLY TRAIN ALL
PHENOL WORKERS ON ITS HAZ S & PROPER PROT MEASURES REQD. TRAINING
SHOULD INCL EMER ACTIONS. ALL PHENOL OPERATIONS SHOULD BE (S TATE
REG INFO)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOS LIM EXCEEDED, NIOSH APPRVD FULL
FACEPIECE RESP W/ORG VAP CARTRIDGE & DUST/MIST FILTER MAY BE WORN
UP TO 50 TIMES EXPOS LIM OR MAX USE CONC SPECIFIED BY APPROP
REGULATORY AGENCY/RESP SUPPLIER, WHICHEVER IS LOWEST. FOR EMERS OR
INSTANCES WHERE EXPOS LEVELS NOT KNOWN, USE NIOSH APPRVD
FULL-FACEPIECE POS-PRESS, AIR-SUPPLIED (STATE REG INFO)
Ventilation:SYS OF LOC &/OR GEN EXHST RECOM TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GENERALLY PREF BECAUSE
IT CAN CTL EMISSIONS (STATE REG INFO)
Protective Gloves:IMPERVIOUS GLOVES; BUTYL RUBBER AND NEOPRENE ARE
SUITABLE MATERIALS.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH
FACESHIELD .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
IMPERVIOUS PROT CLTHG, INCL BOOTS, GLOVES, LAB COATS,
APRON/COVERALLS, AS APPROP, TO PVNT SKIN CNTCT. BUTYL RUB &
NEOPRENE ARE SUITABLE MATLS FOR PPE.
Supplemental Safety and Health
FIRST AID PROC: MOUTH IF UNCON. BE READY TO INDUCE VOMIT AT ADVICE OF
MD/POIS CTL CTR. CASTOR OIL (OR VEGETABLE OIL) DOSAGE SHOULD BE
BETWEEN 15-30 CC. GET MED ATTN IMMED. SKIN:IMMED FLUSH W/LG AMTS O
F WATER WHILE REMOVING CONTAM CLTHG & SHOES. AS SOON AS POSS,
RPTDLY APPLY POLYETHYLENE GLYCOL TO AFFECTED (OTHER INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:=182.C, 359.6F
Melt/Freeze Pt:=43.C, 109.4F
Vapor Pres:0.4 @ 20C(68F)
Vapor Density:3.2(AIR=1)
Spec Gravity:1.06 @ 20C/4C
pH:NO INFO FOUND
Evaporation Rate & Reference:<0.01 (BUAC=1)
Solubility in Water:1 G/15 ML OF WATER
Appearance and Odor:COLORLESS TO LIGHT PINK CRYSTALS; SHARP, MEDICINAL,
SWEET, TARRY ODOR.
Percent Volatiles by Volume:100 @ 21C
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ALUMINUM CHLORIDE & NITROBENZENE, CALCIUM HYPOCHLORITE,
BUTADIENE, HALOGENS, FORMALDEHYDE, MINERAL OXIDIZING ACIDS,
ISOCYANATES, SODIUM NITRITE & MANY OTHER MATLS. HOT LIQ PHENOL WILL
ATTACK ALUMINUM, MAGNESIUM,
Stability Condition to Avoid:STABLE UNDER CONDITIONS OF USE AND
STORAGE. HEAT WILL CONTRIBUTE TO INSTABILITY. AVOID HEAT, FLAMES,
IGNITION SOURCES AND INCOMPATIBLES.
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY
FORM WHEN HEATED TO DECOMPOSITION. TOXIC GASES AND VAPORS MAY BE
RELEASED IF INVOLVED IN A FIRE.
=================== Toxicological Information ===================
Toxicological Information:SKIN RABBIT LD50: 639 MG/KG; INHAL RAT LC50:
316 MG/M3; IRRIT DATA: SKIN RABBIT, STD DRAIZE, 500 MG/24H SEV; EYE
RABBIT, STD DRAIZE 5 MG/30S RINSE, MILD. INVESTIGATED AS TUMORIGEN,
MUTAGEN, REPRO EFFE CTOR. CANCER LISTS: PHENOL-NTP CARCIN:
KNOWN-NO; ANTIC-NO; IARC CATEGORY 3. OTHER INFO: AREA CHGS FROM
WHITE TO PINK. THIS CAN TAKE LONG TIME (20 MIN OR MORE).
POLYETHYLENE GLYCOL APPLICATN SHOULD BE DONE DURING TRANSPORT TO
HOSPITAL. IF POLYETHYLENE GLYCOL NOT AVAIL, FLUSH W/WATER FOR AT
LST 30 MIN PRIOR TO GOING TO TRANSPORT. GET MED ATTN IMMED.
EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 M IN, LIFTING
LOWER (TRANSPORT INFO)
===================== Ecological Information =====================
Ecological:WHEN RELSD INTO SOIL: MATL EXPECTED TO READILY BIODEGRADE;
NOT EXPECTED TO LEACH INTO GROUNDWATER; MAY EVAP TO MOD EXTENT;
EXPECTED TO HAVE HALF-LIFE BETWEEN 1-10 DAYS. WHEN RELSD INTO
WATER: EXPECTED TO READILY BIODEGRADE; NOT EXPECTED TO EVAP
SIGNIFICANTLY; EXPECTED TO HAVE HALF-LIFE BWTWEEN 10-30 DAYS; HAS
EST BIOCONC FACTOR (BDF) OF <100; NOT EXPECTED TO SIGNIFICANTLY
BIOACCUMULATE. WHEN RELSD INTO AIR: EXPECTED TO BE READILY
DEGRADED BY RXN W/PHOTOCHEMICALLY PRDCED HYDROXYL RADICALS; MAY BE
MOD DEGRADED BY PHOTOLYSIS; EXPECTED HAVE HALF-LIFE OF <1 DAY.TOX:
EXPECTED TO BE TOX TO AQ LIFE. L C50/96-HR VALUES FOR FISH:
10-100MG/L.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR
RECYCLING SHOULD BE HANDLED AS HAZ WASTE & SENT TO RCRA APPRVD
INCINERATOR OR DISPOSED IN RCRA APPRVD WASTE FACILITY. PROCESSING,
USE OR CONTAM OF PROD MAY CHA NGE WASTE MANAGEMENT OPTIONS. STATE &
LOCAL DISP REGS MAY DIFFER FROM FED DISP REGS. DISPOSE OF CNTN R &
UNUSED CONTENTS I/A/W FED, STATE & LOCAL REQS.
=================== MSDS Transport Information ===================
Transport Information:DOMESTIC (LAND, DOT) - PROPER SHIPPING NAME:
PHENOL, SOLID. HAZ CLASS: 6.1. UN/NA: UN1671. PACKING GROUP: II.
INFO REPORTED FOR PROD/SIZE: 2KG. INTERNATIONAL (WATER, IMO) -
PROPER SHIPPING NAME: PHENO L, SOLID. HAZ CLASS: 6.1. UN/NA:
UN1671. PACKING GROUP: II. INFO REPORTED FOR PROD/SIZE: 2KG.
INTERNATIONAL (AIR, ICAO) - PROPER SHIPPING NAME: PHENOL, SOLID.
HAZ CLASS: 6.1. UN/NA: UN1761. PACKING GR OUP: II. INFO REPORTED
FOR PROD/SIZE: 2KG. TOXICOLOGICAL INFO: LIDS OCCASNLY. GET MED ATTN
IMMED. NOTE TO MD:TREAT INGEST W/GASTRIC LAVAGE USING 40% AQ
BACTO-PEPTONE, MILK/WATER UNTIL PHENOLIC ODOR EL IM. THEN GIVE
15-50CC (SARA INFO)
===================== Regulatory Information =====================
SARA Title III Information:FED, STATE & INTERNATL REGS - PART 1: PHENOL
- SARA 302: RQ-1000; TPQ-500. SARA 313 - LIST-YES; CHEM CATG-NO.
SARA 311/312: ACUTE-YES; CHRONIC-YES; FIRE-YES; PRESS-NO;
REACTIVITY-NO (PURE/SOLID). TRAN SPORT INFO: CASTOR/VEGETABLE OIL.
DEBRIDE NECROTIC SKIN. MONITOR VITAL SIGNS, FLUID STATUS,
ELECTROLYTES, BUN, RENAL & HEPATIC FUNC & ELECTROCARDIOGRAM. MANAGE
SEDATION, SEIZURES, RENAL FAILURE & FLUI D ELECTROLYTE IMBALANCES
SYMPTOMATICALLY AS INDICATED. SPILL PROC: REPORTING SPILLS &
RELEASES TO SOIL, WATER & AIR IN EXCESS OF RQ. TOLL FREE NUMBER FOR
US COAST GUARD NRC IS 800-424-8802.
Federal Regulatory Information:PHENOL: CHEM INVENTORY STATUS-PART 1:
TSCA-YES; EC-YES; JAPAN-YES; AUSTRALIA-YES. CHEM INVENTORY
STATUS-PART 2: KOREA-YES; DSL-YES; NDSL-NO; PHIL-YES. FED, STATE &
INTERNATL REGS-PART 2: CERCLA-1000; RCRA 261.33-U188; TSCA
8(D)-NO. CHEM WEAPONS CONVENTION:NO. TSCA 12(B): NO.CDTA:NO.
AUSTRALIAN HAZCHEM CODE:2X. POIS SCHEDULE:S6. WHMIS: THIS MSDS HAS
BEEN PREPARED ACCORDG TO HAZ CRITERIA OF CONTROLL ED PRODS REGS
(CPR) & MSDS CNTNS ALL INFO REQD BY CPR. HNDLG/STOR PRECS: IN
ACCORD WITH ACCEPTED ENG INEERING PRACTS IN ANY PROCESS CAPABLE OF
GENERATING DUST &/OR STATIC ELEC.
State Regulatory Information:N/P. OTHER PRECS: ENCLOSED TO ELIMINATE
ANY POTNTL EXPOS ROUTES. CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTY
SINCE THEY RETAIN PROD RESIDUES (DUST, SOLIDS); OBSERVE ALL
WARNINGS & PRECS. RESP PROT: RESP . WARNING:AIR PURIFYING RESPS DO
NOT PROTECT WORKERS IN OXYG-DEFICIENT ATMS. VENT: OF CONTAMINANT AT
ITS SOURCE, PREVENTING DISPERSION OF IT INTO GEN WORK AREA. PLEASE
REFER TO ACGIH DOCUMENT, INDUS V ENT, A MANUAL OF RECOM PRACTS,
MOST RECENT EDITION, FOR DETAILS. AIRBORNE EXPOS LIMS: PHENOL:OSHA
PE L: 5 PPM (TWA) (SKIN). ACGIH TLV: 5 PPM (TWA) (SKIN). PHYSICAL
DATA: SOLUBILITY: VERY SOLUBLE IN ALCOHOL.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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