=====================  Product Identification  =====================

MSDS NAME:L9645, L-LYSINE MONOHYDROCHLORIDE (SUPDAT)
NIIN:00N092576
Status Code:A
MSDS Number: CJTHJ
=== Responsible Party ===
Company:SIGMA CHEMICAL CO
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:314-771-5765
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076

=============  Composition/Information on Ingredients  =============

Name:L-LYSINE MONOHYDROCHLORIDE CALIBRATION MARKER
CAS:657-27-2
RTECS #:OL5650000
Code:F
= Wt:100.

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50: (ORAL,RAT) 10 GM/IKG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION,
    INGESTION, OR SKIN ABSORPTION. MAY CAUSE EYE IRRITATION. MAY CAUSE
    SKIN IRRITATION. MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND
    UPPER RESPIRATORY TRACT. TO  THE BEST OF MANUFACTURER'S KNOWLEDGE,
    THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN
    THOROUGHLY INVESTIGATED.
Effects of Overexposure:SEE HEALTH HAZARDS.

=======================  First Aid Measures  =======================

First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS
    AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. IN CASE OF CONTACT,
    IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. IF
    INHALED, REMOVE T O FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED,
    WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONCSIOUS. CALL A
    PHYSICIAN. WASH CONTAMIN ATED CLOTHING BEFORE REUSE.

=====================  Fire Fighting Measures  =====================

Upper Limits:N/
Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
    APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
    APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND
    EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
    APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND
    EYES.
Neutralizing Agent:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

======================	Handling and Storage  ======================

Handling and Storage Precautions:AVOID INHALATION. AVOID CONTACT WITH
    EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. KEEP TIGHTLY CLOSED.
    STORE IN A COOL DRY PLACE.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:COMPATIBLE CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MFR TRADE NAME/PART NO: CALIBRATION MARKER.

==================  Physical/Chemical Properties  ==================

Appearance and Odor:SOLID.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
    CARBON DIOXIDE, NITROGEN OXIDES, HYDROGEN CHLORIDE GAS.

===================  Toxicological Information	===================

Toxicological Information:TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL,
    PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY
    INVESTIGATED. RTECS #:OL5650000. LYSINE, MONOHYDROCHLORIDE, L-.
    TOXICITY DATA: ORL-RAT LD50: 10 GM/KG. JPMSAE 62,49,1973. IPR-RAT
    LD50: 4019 MG/KG. ABBIA4 58,253,1955. ONLY SELECTED REGISTRY OF
    TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED
    HERE. SEE ACTUAL ENTRY IN RTECS FOR  COMPLETE INFORMATION.

=====================  Ecological Information  =====================

Ecological:DATA NOT YET AVAILABLE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
    SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
    AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
    ENVIRONMENTAL REGULATIONS.

===================  MSDS Transport Information  ===================

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
    INFORMATION.

=====================  Regulatory Information  =====================

Federal Regulatory Information:REVIEWS, STANDARDS AND REGULATIONS.
    OEL=MAK. NOES 1983: HZD X3664; NIS 4; TNF 612; NOS 19; TNE 5509;
    TFE 1728. EPA TSCA SECTION 8(B) CHEMICAL INVENTORY.

=======================  Other Information  =======================

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***