===================== Product Identification =====================
MSDS NAME:BHYDRNAL COMPOSITE 1, 34827R
NIIN:00N0929246
Status Code:A
MSDS Number: CJWVV
=== Responsible Party ===
Company:SIGMA-ALDRICH
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:314-771-5765
CAGE:1FPM8
=== Contractor Identification ===
Company:SIGMA-ALDRICH CORP
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63103
Country:US
Phone:800-505-6275/ 314-771-5765
CAGE:1FPM8
============= Composition/Information on Ingredients =============
Name:DIETHYLENE GLYCOL MONOETHYL ETHER
CAS:111-90-0
RTECS #:KK8750000
< Wt:70.
Name:IMIDAZOLE
CAS:288-32-4
RTECS #:NI3325000
Minumum % Wt:10.
Maxumum % Wt:15.
Name:SULFUR DIOXIDE
CAS:7446-09-5
RTECS #:WS4550000
< Wt:10.
OSHA PEL:13 MG/M3;5 PPM
ACGIH TLV:5.2 MG/M3;2 PPM
ACGIH STEL:13 MG/M3;5 PPM
Name:IODINE
CAS:7553-56-2
RTECS #:NN1575000
< Wt:5.
OSHA PEL:C1 MG/M3;C0.1 PPM
ACGIH STEL:C1.0 MG/M3;C0.1 PPM
Name:HYDRIODIC ACID
CAS:10034-85-2
RTECS #:MW3760000
= Wt:1.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: TOXIC BY INHALATION, INGESTION
OR SKIN ABSORPTION. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF
THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN.
INHALATION MAY RESULT IN SPASM , INFLAMMATION AND EDEMA OF THE
LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA.
SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, H EADACHE, NAUSEA AND
VOMITING. MAY CAUSE ALLERGIC REACTION. TARGET ORGAN(S): LIVER,
KIDNEYS, CENTRAL NERVOUS SYSTEM, BLOOD, THYROID. (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZS: CHRONIC: MAY CAUSE CONGENITAL
MALFORMATION IN THE FETUS. OVEREXPOSURE MAY CAUSE REPRODUCTIVE
DISORDER(S) BASED ON TESTS WITH LABORATORY ANIMALS. TO THE BEST OF
MFR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL
PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
======================= First Aid Measures =======================
First Aid:IN CASE OF CONT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. IF INHALED, REMOVE TO FRESH AIR.
IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER
PROVIDED PERSON IS CONSCIOUS. CALL PHYSICIAN. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND
EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR NIOSH APPRVD
SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER
GLOVES. ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED
CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER
MATERIAL PICKUP IS COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE VAP. DO NOT GET IN
EYES, ON SKIN, ON CLTHG. KEEP TIGHTLY CLOSED. STORE IN COOL DRY
PLACE. HIGHLY TOXIC. MAY CAUSE HARM TO UNBORN CHILD. POSSIBLE RISK
OF IMPAIRED FERTILITY. TOXIC BY INH AL, IN CONT W/ SKIN & IF
SWALLOWED. CAUSES BURNS. MAY CAUSE SENSITIZATION BY INHAL & SKIN
CONT.
Other Precautions:TARGET ORGAN(S): LIVER, KIDNEYS. IN CASE OF
ACCIDENT/IF YOU FEEL UNWELL, SEEK MED ADVICE. IMMED (SHOW LABEL
WHERE POSSIBLE). AVOID EXPOSURE - OBTAIN SPEC INSTRUCTIONS BEFORE
USE. IN CASE OF CONT W/EYE S, RINSE IMMED W/PLENTY OF WATER & SEEK
MED ADVICE. WEAR SUITABLE PROT CLTHG, GLOVES & EYE/FACE PROT .
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
(FACESHIELD (8-INCH MINIMUM).
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FEDERAL REGULATORY INFO: U.S. INFO: 70% DIETHYLENE GLYCOL MONOETHYL
ETHER 111-90-0.
================== Physical/Chemical Properties ==================
Appearance and Odor:LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NOT KNOWN.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE, NITROGEN OXIDES, SULFUR OXIDES, IODINE, HYDROGEN
IODIDE.
=================== Toxicological Information ===================
Toxicological Information:SEE HEALTH HAZARDS.
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT IS SUBJECT TO SARA SECTION 313
REPORTING REQUIREMENTS.
Federal Regulatory Information:EUROPEAN INFO: CAUTION: SUBSTANCE NOT
YET FULLY TESTED. TOXIC. R 61. MAY CAUSE HARM TO UNBORN CHILD. R
62. POSSIBLE RISK OF IMPAIRED FERTILITY. R 23/24/25. TOXIC BY
INHALATION, IN CONTACT WITH SKIN AN D IF SWALLOWED. R 34. CAUSES
BURNS. R 42/43. MAY CAUSE SENSITIZATION BY INHAL & SKIN CONT. S 45.
IN CASE OF ACCIDENT/IF YOU FEEL UNWELL, SEEK MED ADVICE. IMMED
(SHOW LABEL WHERE POSSIBLE). S 53. AVOID EXPOSURE - OBTAIN SPEC
INSTRUCTIONS BEFORE USE. S 26. IN CASE OF CONT WEYES, RINSE IMMED
W/PLENTY O F WATER & SEEK MED ADVICE. S 36/37/39. WEAR SUITABLE
PROT CLTHG, GLOVES & EYE/FACE PROT. (SUPDAT)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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