===================== Product Identification =====================
MSDS NAME:NI-533 PRODUCT CODE: ZNI533-0010
NIIN:01-426-5420
Status Code:A
MSDS Number: CJWTM
=== Responsible Party ===
Company:PRAXAIR SURFACE TECHNOLOGIES INC
Address:1555 MAIN STREET
City:INDIANAPOLIS
State:IN
ZIP:46224-3283
Country:US
Info Phone Num:317-240-2650
Emergency Phone Num:(800)424-9300
Preparer's Name:MICHELLE ALEXANCER
Chemtrec Ind/Phone:(800)424-9300
CAGE:0FGH2
=== Contractor Identification ===
Company:PRAXAIR SURFACE TECHNOLOGIES INC
Address:1555 MAIN STREET
Box:City:INDIANAPOLIS
State:IN
ZIP:46224-3283
Country:US
Phone:317-240-2650
CAGE:0FGH2
Company:STARGHILL TECHNOLOGIES CORP
Address:3850 OAKMAN BLVD
Box:City:DETROIT
State:MI
ZIP:48204-1119
Country:US
Phone:313-933-4141
Contract Num:SP0450-95-D-4037
CAGE:0VYG8
============= Composition/Information on Ingredients =============
Name:CHROMIUM
CAS:7440-47-3
RTECS #:GB4200000
Minumum % Wt:5.
Maxumum % Wt:20.
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:NICKEL
CAS:7440-02-0
RTECS #:QR5950000
Minumum % Wt:50.
Maxumum % Wt:75.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Name:ALUMINUM
CAS:7429-90-5
RTECS #:BD0330000
Minumum % Wt:5.
Maxumum % Wt:20.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Name:MOLYBDENUM
CAS:7439-98-7
RTECS #:QA4680000
Minumum % Wt:1.
Maxumum % Wt:5.
ACGIH TLV:10 MG/M3
Name:COLUMBIUM/NIOBIUM
CAS:7440-03-1
RTECS #:QT9900000
Minumum % Wt:1.
Maxumum % Wt:5.
Name:TITANIUM
CAS:7440-32-6
RTECS #:XR1700000
Minumum % Wt:1.
Maxumum % Wt:5.
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:SKIN:MAY CAUSE ALLERGIC DERMATITIS,
WITH REDNESS & PAPULAR FORMATION IN SUSCEPTABLE INDIVIDUALS. MAY
CAUSE ULCERS PROGRESSING TO DRY & SCALY SKIN, FEVER. EYE:MAY CAUSE
IRRIATATION, EXPERIENCED AS REDN ESS & EXCESS REDNESS OF THE
CONJUCTIVA. SWALLOWING: MAY CAUSE NAUSEA, ABDOMINAL PAIN, VOMITING,
DIARRHEA, CENTRAL NERVOUS SYSTEM DEPRESSION, & BURNING SENSATION.
INHALATION:MAY CAUSE RESPIRATORY TRACT IRRITATION, WITH CHEST
PAIN, VOIMITING, DIARRHEA, BURNING SENSATION, & CENTRAL NERVOUS
SYSTEM DEPRESSION. MAY ALSO CAUSE INTERSTITIAL PNEUMONITIS &
SENSITIZATION OF THE RESPIRATORY TRACT IN SUSCEPTIB LE PERSONS.
Explanation of Carcinogenicity:NICKEL AND CHROMIUM HAVE BEEN DETERMINED
TO CAUSE CANCER IN EXPERMENTAL ANIMALS (IARC, NTP). NICKEL IS
LISTED AS A PROBABLE HUMAN CARCINOGEN. CHROMIUM IS LISTED AS A
HUMAN CARCINOGEN. CHRONIC ECZEMA/N EURODERMATITIS FROM NICKEL DOES
NOT REQUIRE CONTINUOUS METAL CONTACT.
Effects of Overexposure:MAY CAUSE SENSITIZATION IN SUSCEPTABLE
INDIVIDUALS. CHRONIC EXPOSURE TO THE EYE CAN CAUSE CORNEAL DAMAGE,
POLYCYTHEMIA, HYPERPLASIA OF THE THYROID GLAND AND DAMAGE TO THE
ALPHA CELLS OF THE PANCREAS. REPEATED INHALATION MAY CAUSE
EMPHYSEMA OR PULMONARY FIBROTIC DISEASE. CHRONIC SKIN CONTACT MAY
SPREAD TO THE WHOLE BODY WITH LESIONS, ITCHING, SORENESS, BURNING
SENSATION AND REDNESS.
Medical Cond Aggravated by Exposure:BREATHING OF DUST MAY AGGRAVATE
ASTHMA AND INFLAMMATORY OR FIBROTIC PULMONARY DISEASE. MAY ALSO
AGGRAVATE AN EXISTING DERMATITIS.
======================= First Aid Measures =======================
First Aid:SWALLOWING:GIVE AT LEAST 2 GLASSES OF MILK OR WATER. INDUCE
VOMITING, UNLESS PATIENT IS UNCONSCIOUS. CALL A PHYSICIAN.
SKIN:WASH THOROUGHLY WITH SOAP & WATER. INHALATIO: REMOVE TO FRESH
AIR. GIVE ARTI FICIAL RESPIRATION IF NOT BREATHING. OXYGEN MAY BE
GIVEN IF NECESSARY. CALL A PHYSICIAN. EYES: FLUSH THOROUGHLY WITH
PLENTY OF WATER. IF DISCOMFORT PERSISTS, SEEK MEDICAL ATTENTION.
PREFERABLY AN OPTH ALMOLOGIST. NOTES TO PHYSCIAN:THE HAZARDS OF
THIS MATERIAL ARE MAINLY DUE TO ITS SENSITIZING AND MILD IRRITATING
PROPERTIES. THERE IS NO SPECIFIC ANTIDOTE.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Upper Limits:0.00%
Extinguishing Media:USE SPECIAL DRY POWDER METAL EXTINGUISHING MATERIAL
TO EXTINGUISH METAL FIRES. USE APPROPRIATE EXTINGUISHER FOR
COMBUSTABLE MATERIALS THAT MAY BE IGNITED BY THE THERMAL SPRAY
FLAME.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT TO PROTECT AGAINST
HAZARDS AND DISPOSE OF PER WASTE DISPOSAL METHOD.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:CAUTION: WHEN THERMAL SPRAYING - ELECTRICITY CAN
CAUSE FATAL SHOCK! DO NOT TOUCH LIVE ELECTRICAL PARTS! ARC RAYS CAN
BURN EYES AND SKIN! WEAR RECOMMENDED EYE AND BODY PROTECTION.
FUMES, GAS, AND DUST CAN HARM YOUR HEALTH. PROVIDE ENOUGH
VENTILATION AND WEAR RESPIRATOR IF REQUIRED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DEPENDS UPON SPECIFIC USE, CONDITION, AND
LOCATION. IF THERE IS DUSTINESS, WEAR RESPRI-RATOR SELECTED PER
OSHA 1910.134, AND OSHA 29 CFR 1910.252 AND ANSI Z49.1.
Ventilation:LOCAL DUST PICK UP AND VENTILATION RECOMMENDED.
Protective Gloves:NOT REQUIRED.
Eye Protection:WHEN DUSTY USE GOGGLES PER OSHA 1910.13
Other Protective Equipment:SEE ANSI Z49.1, ANSI Z87.1, ANSI Z88.2 FOR
HELMETS, FACE SHIELDS AND GOGGLES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:NONE
Vapor Density:N/VOLATILE
Evaporation Rate & Reference:UNAVAILABLE
Appearance and Odor:DUSTY DARK GRAY POWDER
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:WHEN THERMAL SPRAYING, WILL VARY WITH
OPERATING CONDITIONS. REASONABLY EXPECTED DECOMPOSITION PRODUCTS OF
NORMAL OPERATION FROM THIS THERMAL SPRAY POWDER INCLUDE OXIDES OF
THE LISTED INGREDIENTS.
=================== Toxicological Information ===================
Toxicological Information:NONE SPECIFIED BY MANUFACTURER.
===================== Ecological Information =====================
Ecological:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE PER LOCAL, STATE, AND FEDERAL
REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:NONE SPECIFIED BY MANUFACTURER.
===================== Regulatory Information =====================
SARA Title III Information:PRODUCT CONTAINS THE FOLLOWING TOXIC
CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF
THE EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW ACT OF 1986 AND
OF 40 CFR 372: CHROMIUM, CAS# 7440-47-3, <20%; NICKEL, CAS#
7440-02-0, <75%.
Federal Regulatory Information:ALL COMPONENTS OF THIS PRODUCTS ARE
LISTED IN TSCA.
State Regulatory Information:CALIFORNIA PROPOSITION 65 (CARCINOGEN):
CHROMIUM, CAS# 7440-47-3; NICKEL, CAS# 7440-02-0. CALIFORNIA
PROPOSITION 65 (TERATOGENIC): NONE. CALIFORNIA PROPOSITION 65 (BOTH
TERATOGENIC AND CARCINOGEN): NO NE.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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