===================== Product Identification =====================
MSDS NAME:THIOCARBOHYDRAZIDE 98%, 20753-0000
NIIN:00N093109
Status Code:A
MSDS Number: CJWXN
=== Responsible Party ===
Company:ACROS ORGANICS
Address:ONE REAGENT LANE
City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:800-227-6701
Emergency Phone Num:800-424-9300
Chemtrec Ind/Phone:(800)424-9300
CAGE:ACR0S
=== Contractor Identification ===
Company:ACROS ORGANICS
Address:ONE REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Phone:800-227-6701
CAGE:ACR0S
============= Composition/Information on Ingredients =============
Name:THIOCARBOHYDRAZIDE. EINECS # 218-769-8.
CAS:2231-57-4
RTECS #:FF2975000
= Wt:98.
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT AVAILABLE.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE IRRITATION.
SKIN: MAY CAUSE IRRITATION. INGESTION: MAY BE FATAL IF SWALLOWED.
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION. THE
TOXICOLOGICAL PROPERTIES OF THIS SUBSTANCE H AVE NOT BEEN FULLY
INVESTIGATED. CHRONIC: NOT AVAILABLE.
Explanation of Carcinogenicity:THIOCARBOHYDRAZIDE - NOT LISTED BY
ACGIH, IARC, NIOSH, NTP, OR OSHA.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
Eyes: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES,
OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMEDIATELY.
SKIN: GET MED AID. FLUSH WITH PLENTY OF SOAP & WATER FOR AT LEAST
15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES. REMOVE
CONTAMINATED CLOTHING & SHOES. INGEST: GET MED AID IMMEDIATELY. IF
CONSCIOUS DRINK WATER, THEN INDUCE VOMITING. IF UNCONSCIOUS,
IMMEDIATELY TAKE V ICTIM TO MD & DO NOT ATTEMPT TO INDUCE VOMITING.
INHAL: GET MED AID IMMEDIATELY. REMOVE FROM EXPOSURE TO FRESH AIR
IMMEDIATELY. IF NOT BREATHING, GIVE ARTF RESP. IF BREATHING IS
DIFFICULT, GIVE OXYGEN . NOTES TO MD: TREAT SYMPTOMATICALLY.
===================== Fire Fighting Measures =====================
Flash Point:NOT AVAILABLE
Autoignition Temp:Autoignition Temp Text:N/AV
Lower Limits:NOT AVAIL
Upper Limits:NOT AVAIL
Extinguishing Media:IN CASE OF FIRE USE WATER SPRAY, DRY CHEMICAL,
CARBON DIOXIDE, OR CHEMICAL FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EXPOSURE TO HEAT MAY PROMOTE VIOLENT
DECOMPOSITION. FLAMMABLE SOLID. NFPA RATING: NOT PUBLISHED.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION SECTION. CLEAN
UP SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS IN THE PROTECTIVE
EQUIPMENT SECTION.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE DUST, VAPOR, MIST OR
GAS. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. USE ONLY IN A
CHEMICAL FUME HOOD. STORE IN A COOL, DRY PLACE. KEEP CONTAINER
CLOSED WHEN NOT IN USE. POISON ROOM L OCKED.
Other Precautions:EMERGENCY OVERVIEW: HIGHLY FLAMMABLE. VERY TOXIC IF
SWALLOWED. KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING. IN CASE
OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LAB EL WHERE POSSIBLE).
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH APPROVED RESPIRATORY PROTECTION PROGRAM
THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS OR
EUROPEAN STANDARD EN 149 MUST BE FOLLOWED WHENEVER WORKPLACE
CONDITIONS WARRANT A RESPI RATOR'S USE.
Ventilation:USE PROCESS ENCLOSURE, LOCAL EXHAUST VENTILATION, OR OTHER
ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT
WITH SKIN.
Work Hygienic Practices:AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH
PLENTY OF WATER.
Supplemental Safety and Health
PHYSICAL AND CHEMICAL PROPERTIES: DENSITY: NOT AVAILABLE. MOLECULAR
FORMULA: H2NNHCSNHNH2. MOLECULAR WEIGHT: 106.15.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NOT AVAILABLE
Melt/Freeze Pt:=171.C, 339.8F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:NOT AVAILABLE
Spec Gravity:NOT AVAILABLE
pH:NOT AVAILABLE
Viscosity:NOT AVAILABLE
Solubility in Water:NOT AVAILABLE
Appearance and Odor:WHITE POWDER; NO ODOR AVAILABLE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS.
Stability Condition to Avoid:MECHANICAL STOCK, INCOMPATIBLE MATERIALS,
TEMPERATURE ABOVE 75C.
Hazardous Decomposition Products:CARBON MONOXIDE, OXIDES OF NITROGEN,
OXIDES OF SULFUR, CARBON DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:SEE ACTUAL ENTY IN RTECS FOR COMPLETE
INFORMATION.
===================== Ecological Information =====================
Ecological:FOR FURTHER INFORMATION, CONTACT ACROS ORGANICS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:U.S. DOT & I.A.T.A.: SHIPPING NAME: TOXIC SOLID,
ORGANIC, N.O.S.*. HAZARD CLASS: 6.1. UN #: 2811. PACKING GROUP: II.
I.M.O.: SHIPPING NAME: TOXIC SOLID, ORGANIC, N.O.S. HAZARD CLASS:
6.1. UN #: 2811. PACKING GROUP: II. R.I.D./A.D.R.: SHIPPING NAME:
TOXIC SOLID, ORGANIC, N.O.S. UN #: 2811. DANGEROUS GOODS CODE:
6.1(25B). CANADIAN T.D.G.: SHIPPING NAME: FLAMMABLE SOLIDS
POISONOUS N.O.S. HAZARD CLASS : 4.1(6.1). UN #: UN2926. OTHER
INFORMATION: THIOCARBOHYDRAZIDE.
===================== Regulatory Information =====================
Federal Regulatory Information:EUROPEAN/INTERNATIONAL REGULATION:
EUROPEAN LABELING I/A/W EC DIRECTIVES: HAZARD SYMBOLS: T+ F. RISK
PHRASES: R 11 - HIGHLY FLAMMABLE; R 28 - VERY TOXIC IF SWALLOWED.
SAFETY PHRASES: S 16 - KEEP AWAY FROM SOURCES OF IGNITION - NO
SMOKING; S 45 - IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK
MEDICAL ADVICE IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE). S 28A -
AFTER CONTACT WITH SKIN, WASH IMMEDIA TELY WITH PLENTY OF WATER.
WGK (WATER DANGER/PROTECTION): CAS # 2231-57-4: NO INFORMATION
AVAILABLE. CANADA: CAS # 2231-57-4 IS LISTED ON CANADA'S DSL/NDSL
LIST. CAS # 2231-57-4 IS NOT LISTED ON CANDA'S INGREDIENT
DISCLOSURE (OTHER INFO)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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