===================== Product Identification =====================
MSDS NAME:NASON PAINT PRODUCTS 421-03
Status Code:A
MSDS Number: CKQMC
=== Responsible Party ===
Company:E I DUPONT DE NEMOURS & CO INC
Address:1007 MARKET ST
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-338-8083
Emergency Phone Num:800-441-3637
Resp. Party Other MSDS Num.:28
Chemtrec Ind/Phone:(800)424-9300
CAGE:18873
=== Contractor Identification ===
Company:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873
============= Composition/Information on Ingredients =============
Name:BUTYL ACETATE; VP: 8.0 MM HG @ 20C
CAS:123-86-4
RTECS #:AF7350000
Other REC Limits:N/K
OSHA PEL:710 MG/M3;150 PPM
OSHA STEL:N/K
ACGIH TLV:713 MG/M3;150 PPM
ACGIH STEL:950 MG/M3;200 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:TOLUENE; VP: 36.7 MM HG @ 20C
CAS:108-88-3
RTECS #:XS5250000
Minumum % Wt:6.
Maxumum % Wt:7.
Other REC Limits:N/K
OSHA PEL:SEE TABLE Z-2
OSHA STEL:N/K
ACGIH TLV:188 MG/M3;50 PPM
ACGIH STEL:N/K
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:VM&P NAPHTHA; VP: 15 MM HG @ 37.8C CAS# 64742-89-8
Other REC Limits:N/K
OSHA PEL:300 PPM
OSHA STEL:400 PPM
ACGIH TLV:300 PPM
ACGIH STEL:400 PPM
Name:XYLENE; VP: 7.0 MM HG @ 25C
CAS:1330-20-7
RTECS #:ZE2100000
Minumum % Wt:1.
Maxumum % Wt:3.
Other REC Limits:N/K
OSHA PEL:100 PPM
OSHA STEL:150 PPM
ACGIH TLV:434 MG/M3;100 PPM
ACGIH STEL:651 MG/M3;150 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:TITANIUM DIOXIDE; VP: NONE @ 20C
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Name:CARBON BLACK; VP: NONE @ 20C
CAS:1333-86-4
RTECS #:FF5800000
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Name:AMORPHOUS SILICA; VP: NONE @ 20C
CAS:7631-86-9
Name:ETHYL ALCOHOL-B; VP: 30.0 @ 20C
CAS:64-17-5
RTECS #:KQ6300000
OSHA PEL:1900 MG/M3;1000 PPM
ACGIH TLV:1880 MG/M3;1000 PPM
Name:ETHYLBENZENE; VP: 7.0 @ 20C
CAS:100-41-4
RTECS #:DA0700000
Minumum % Wt:0.
Maxumum % Wt:1.
OSHA PEL:435 MG/M3;100 PPM
ACGIH TLV:434 MG/M3;100 PPM
ACGIH STEL:543 MG/M3;125 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:GLYCERYL TRI-ACETOXY STEARATE; VP: UNKNOWN @ 20C
CAS:27233-00-7
Name:ISOPROPYL ALCOHOL; VP: 33 @ 20C
CAS:67-63-0
RTECS #:NT8050000
OSHA PEL:980 MG/M3;400 PPM
ACGIH TLV:983 MG/M3;400 PPM
ACGIH STEL:1230 MG/M3;500 PPM
Name:METHYL ETHYL KETONE; VP: 71.0 @ 20C
CAS:78-93-3
RTECS #:EL6475000
= Wt:17.
OSHA PEL:590 MG/M3;200 PPM
ACGIH TLV:590 MG/M3;200 PPM
ACGIH STEL:885 MG/M3;300 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:BUTYL ALCOHOL (N-BUTYL ALCOHOL); VP: 5.5 @ 20C
CAS:71-36-3
RTECS #:EO1400000
= Wt:4.
OSHA PEL:300 MG/M3;100 PPM
ACGIH STEL:C152 MG/M3;C50 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:NITROCELLULOSE; VP: UNKNOWN @ 20C
CAS:9004-70-0
RTECS #:QW0970000
Name:PETROLEUM NAPHTHA; VP:50.0 @ 25C
CAS:64742-89-8
Name:HYDROUS MAGNESIUM SILICATE; VP: NONE @ 20C
CAS:14807-96-6
RTECS #:WW2710000
Name:ALKYD RESIN-J; VP: NONE @ 20C (MFR CAS NO. 676770-61-2)
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:GEN EFTS: INGEST: GI DISTRESS. INHAL:
MAY CAUSE NOSE & THROAT IRRIT. RPTD & PRLNG OVEREXP TO SOLVS MAY
LEAD TO PERM BRAIN & NERV SYS DMG. EYE WATERING, HDCH, NAUS, DIZZ &
LOSS OF COORD ARE SIGNS THAT SOLV LEVELS ARE TOO HIGH. ADDNL EFTS
WHEN THIS MATL CONTAINS/IS MIXED W/ISOCYANATE ACTIVATOR/HARDENER:
EXPOS TO ISOCYANATES MAY CAUSE RESP SENSIT. THIS EFT MAY BE PERM.
THIS EFT MAY BE DELAYED FOR SEV ERAL HRS AFTER EXPOS. RPTD OVEREXP
TO ISOCYANATES MAY CAUSE DECR IN LUNG FUNC WHICH MAY BE PERM. EYES:
MAY CAUSE IRRIT/BURNING. SKIN: RPTD/PRLNG LIQ CONT MAY CAUSE IRRIT
W/DISCOMFORT & DERM. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS, VOLUME
65, PAGE 149, 1998: GROUP 2B. ANIMAL: LUNG.
Effects of Overexposure:HEALTH HAZARDS: TOLUENE APPEARS ON THE NAVY
OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST. CONSULT
APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST
INFORMATION & SAFE HANDLING & EXPOSU RE INFO . SPECIFIC EFFECTS:
PETROLEUM NAPHTHA/ VM & P NAPHTHA: LAB STUDIES W/RATS HAVE SHOWN
THAT PETROLEUM DISTILLATES CAN CAUSE KIDNEY DAMAGE & KIDNEY OR
LIVER TUMORS. THESE EFFECTS WERE NOT SEEN IN SIMILAR STUDIES
W/GUINEA PIGS, DOGS OR MONKEYS. SEVERAL STUDIES EVALUATING
PETROLEUM WORKERS HAVE NOT SHOWN A SIGNIFICANT INCR OF KIDNEY DMG
OR AN INCR IN KIDNEY OR LIVER TUMORS. (TOXICOLOGICA L INFO)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/BRTHG PROBLEMS/PRIOR
RXN TO ISOCYANATES MUST NOT BE EXPOSED TO VAPS/SPRAY MISTS OF THIS
PROD. INDIVIDUALS W/PREEXISTING DISEASES OF CNS, LUNGS,
LIVER/KIDNEYS MAY HAVE INCRD (SARA REGS)
======================= First Aid Measures =======================
First Aid:INGESTION: IN THE UNLIKELY EVENT OF INGESTION, CALL A
PHYSICIAN IMMEDIATELY AND HAVE THE NAMES OF THE INGREDIENTS
AVAILABLE. DO NOT INDUCE VOMITING. INHALATION: IF AFFECTED BY
INHALATION OF VAPOR OR S PRAY MIST, REMOVE TO FRESH AIR. IF
BREATHING DIFFICULTY PERSISTS OR OCCURS LATER, CONSULT A PHYSICIAN.
EYES: IN CASE EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR AT LEAST 15 MINUTES; CALL A PHYSICIAN. SKIN: WASH WITH SOAP
AND WATER. IF IRRITATION OCCURS, CONTACT A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:>-6.7C, 20.F
20F - 73F
Lower Limits:0.7%
Upper Limits:23.0%
Extinguishing Media:UNIVERSAL AQUEOUS FILM-FORMING FOAM, CARBON
DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD-UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASH POINT, EMITS
FLAMMABLE VAPORS WHICH, WHEN MIXED WITH AIR, CAN BURN OR BE
EXPLOSIVE. FINE MISTS OR SPRAYS MAY BE FLAMMABLE AT TEMPERATURES
BELOW THE FLASH POINT.
================== Accidental Release Measures ==================
Spill Release Procedures:VENT AREA. REMOVE IGNIT SOURCES. PVNT SKIN &
EYE CONT & BRTHG OF VAP. WEAR NIOSH APPRVD RESP, EYE PROT, GLOVES &
PROT CLTHG. CONFINE & REMOVE W/INERT ABSORB. IF MATL CONTAINS/IS
MIXED W/ISOCYANATE ACT IVATOR/HARDENER: WEAR POS-PRESS, SUPP-AIR
RESP (NIOSH APPRVD TC-19C). POUR LIQ DECONTAM SOLN OVER SPILL &
ALLOW TO SIT AT LEAST 10 MINS. TYPICAL DECONTAM SOLNS FOR
ISOCYANATES-CONTAINING (FED REGS)
====================== Handling and Storage ======================
Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
FROM HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND
CONTAINERS WHEN POURING. DO NOT STORE ABOVE 120F. OSHA STORAGE: IB.
Other Precautions:DO NOT SAND, FLAME CUT, BRAZE OR WELD DRY COATING
WITHOUT A NIOSH APPROVED RESPIRATOR OR APPROPRIATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DO NOT BREATHE VAPS/MISTS. WHEN PRODS ARE USED
W/PAINTS REQUIRING ISOCYANATE ACTIVATORS/HARDENERS, WEAR POS-PRESS,
SUPP-AIR RESP (NIOSH APPRVD TC-19C) WHILE MIXING ACTIVATOR/HARDENER
W/PAINT, DURING A PPLICATION & UNTIL ALL VAPS & SPRAY MISTS ARE
EXHAUSTED. IF PROD IS USED W/OUT ISOCYANATE ACTIVATORS/HARDENERS, A
PROPERLY FITTED AIR-PURIFYING (STATE REGS)
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO
KEEP CONTAMINANTS BELOW APPLICABLE EXPOSURE LIMITS.
Protective Gloves:NEOPRENE GLOVES ARE RECOMMENDED.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . COVERALLS ARE RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR SMOKING.
Supplemental Safety and Health
PHYS/CHEM PROP: GAL WT (#/GAL): 6.66-13.03; WT % VOLAT: 9.68%-100%; GAL
WT:9.28; WT PCT SOLIDS:47.41; VOL PCT SOLIDS: 28.43; SOLV
DENSITY:6.82; VOC LE: 4.9; VOC AP: 4.9.
================== Physical/Chemical Properties ==================
Boiling Pt:>26.C, 78.8F
B.P. Text:26C - 900C
Vapor Pres:SEE INGREDIENTS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:LESS THAN ETHER
Solubility in Water:MISCIBLE
Percent Volatiles by Volume:12.5% - 100%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
SMOKE, OXIDES OF HEAVY METALS IN INGREDIENTS SECTION.
=================== Toxicological Information ===================
Toxicological Information:OVEREXPOS: TOLUENE: RECURRENT OVEREXP MAY
RESULT IN LIVER & KIDNEY INJURY. HI AIRBORNE LEVEL PROD IRREG
HEARTBEAT IN ANIMAL & OCCASIONAL PALPITATION IN HUMAN. RAT EXPOSED
TO VERY HI AIRBORNE LEVEL EXH IBITED HI FREQ HEARING DEFICIT.
SIGNIFICANCE TO MAN IS UNKNOWN. CHROMOSOMAL CHANGES IN CIRCULATING
BLOOD OF EXPOSED WORKER HAVE BEEN RPTD. SIGNIFICANCE IS UNCLEAR
BECAUSE OF EXPOS TO OTHER SUBSTANCES. HYDROUS MAGNESIUM SILICATE:
RPTD/PRLNGD OVEREXPOS TO TALC MAY LEAD TO TYPICAL X-RAY CHANGES &
CHRONIC LUNG DISEASE. ISOPROPYL ALCOHOL: INGEST STUDIES ON LAB
ANIMAL SHOW VERY HI ORAL DOSES CAUSED INCR LIVER & KIDNEY WTS.
(ECOLOGICAL INFO)
===================== Ecological Information =====================
Ecological:TOX INFO: XYLENE: RECURRENT OVEREXPOSURE MAY RESULT IN LIVER
& KIDNEY INUURY. CAN BE ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS.
INDIVIDUALS W/PRE-EXISTING DISEASE OF THE CENTRAL NERVOUS SYSTEM,
KIDNEY S, LIVER, CARDIOVASCULAR SYSTEM, LUNGS OR BONE MARROW MAY
HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE
EXPOSURES. CANADA CLASSIFIES XYLENE AS A DEVELOPMENTAL TOXIN AS
HIGH EXPOSURES TO X YLENES IN SOME ANIMAL STUDIES HAVE BEEN
REPORTED TO CAUSE HEALTH EFFECTS ON THE DEVELOPING FETUS/EMBRYO.
THESE EFFECTS WERE OFTEN AT LEVELS TOXIC TO THE ADULT ANIMAL. THE
SIGNIFICANCE OF THESE EFFECTS TO HUMANS IS NOT KNOWN. (OTHER INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH
FEDERAL, STATE, AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED
CONTAINERS.
=================== MSDS Transport Information ===================
Transport Information:OTHER INFO: N-BUTYL ALCOHOL: LIQ SPLASHES IN EYE
MAY RESULT IN CHEM BURNS. MAY CAUSE ABNORMAL BLOOD FORMING FUNCTION
W/ANEMIA. RECURRENT OVEREXPOS MAY RESULT IN LIVER & KIDNEY INJURY.
CAN BE ABSORBED THRU SKIN IN HARMFUL AMTS. MEK: HI CONC CAUSED
EMBRYOTIC EFFECTS IN LAB ANIMAL. MEK HAS BEEN SHOWN TO POTENTIATE
THE PERIPHERAL NEUROPATHY CAUSED BY EITHER N-HEXANE OR METHYL
N-BUTYL KETONE. MEK BY I TSELF HAS NOT BEEN SHOWN TO CAUSE
PERIPHERAL NEUROPATHY. LIQ SPLASHES IN EYE MAY CAUSE CHEM BURNS.
ETHYL ALCOHOL-B: OVEREXP MAY CAUSE EYE, NOSE, THROAT IRRIT.
RPT/PRLG CONT MAY CAUSE SKIN IRRIT W/DISC OMFORT & DERM. (FED REGS)
===================== Regulatory Information =====================
SARA Title III Information:THE FOLLOWING CHEMICALS ARE SUBJECT TO
REPORTING REQUIREMENTS OF SECTION 313 OF EMERGENCY PLANNING &
RIGHT-TO-KNOW ACT OF 1986 & OF 40 CFR 372: TOLUENE, XYLENE,
METHYL ETHYL KETONE, ETHYLBENZENE, AN D N-BUTYL ALCOHOL. MEDICAL
CONDITIONS: SUSCEPTIBILITY TO TOXICITY OF EXCESS EXPOSURE.
INDIVIDUALS WITH PREEXISTING DISEASES OF KIDNEYS, LIVER,
CARDIOVASCULAR SYSTEM BONE MARROW MAY HAVE INCREASED SUS
CEPTIBILITY TO TOXICITY OF EXCESS EXPOSURE.
Federal Regulatory Information:SPILL PROC: MATLS ARE: 20% SURFACTANT
(TERGITOL TMN 10) & 80% H*2O OR 0-10% AMMONIA, 2-5% DETERGENT &
H*2O BALANCE). PRESS CAN BE GENERATED. DO NOT SEAL CNTNR. AFTER 48
HRS, MATL MAY BE SEALED & DISP OSED OF PROPERLY. IF MATL DOES NOT
CONTAIN/IS NOT MIXED W/ISOCYANATE ACTIVATOR/HARDENER: WEAR PROPERLY
FITTED AIR-PURIFYING RESP W/ORGANIC VAP CARTRIDGES (NIOSH APPRVD
TC-23C). TRANSPORT INFO: MAY CAU SE ABNORM LIVER FUNC W/JAUNDICE.
LAB ANIMAL SHOW CARDIOVASCULAR SYS EFT. MUTAGENIC ACTIVITY SHOWN IN
LAB CELL CULTURE TEST & IN LAB ANIMAL TEST. SOME LAB ANIMAL SHOW
COMPOUND MAY HAVE EMBRYOTOXIC ACTIVITY. TESTS IN ANIMAL SHOW
REPROD TOX.
State Regulatory Information:WARNING: TOLUENE IS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. RESP
PROT: RESPIRATOR W/ORGANIC VAPOR CARTRIDGES (NIOSH TC-23C) &
PARTICULATE FILTER (NIOSH TC-8 4A) MAY BE USED. FOLLOW RESP MFR'S
DIRECTIONS FOR RESP USE. DO NOT PERMIT ANYONE W/OUT PROTECTION IN
PAINTING AREA. REFER TO HARDENER/ACTIVATOR LABEL INSTRUCTIONS &
MSDS FOR FURTHER INFORMATION. PERSO NS WITH HISTORY OF
LUNG/BREATHING PROBLEMS/PRIOR REACTION TO ISOCYANATES SHOULD NOT
USE/BE EXPOSED T O PRODUCT IF MIXED WITH ISOCYANATE
ACTIVATORS/HARDENERS.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|