===================== Product Identification =====================
MSDS NAME:PROLINE SUPREME CEILING PAINT, 74-1000 BRIGHT WHITE
Status Code:A
MSDS Number: CKQLS
=== Responsible Party ===
Company:SHERWIN-WILLIAMS CO
Address:101 PROSPECT AVE N W
Box:6709
City:CLEVELAND
State:OH
ZIP:44101
Country:US
Info Phone Num:216-566-2902
Emergency Phone Num:216-566-2917
Resp. Party Other MSDS Num.:L-PRO/MS3
CAGE:54636
=== Contractor Identification ===
Company:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVE NW
Box:City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Phone:800-251-2486/216-566-2242
CAGE:54636
============= Composition/Information on Ingredients =============
Name:SILICA, CRYSTALLINE-CRISTOBALITE
CAS:14464-46-1
RTECS #:VV7325000
= Wt:2.
OSHA PEL:0.05 MG/M3 (DUST)
ACGIH TLV:0.05 MG/M3 (DUST)
Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
= Wt:20.
OSHA PEL:10 MG/M3 (RESP DUST)
OSHA STEL:5 MG/M3 (RESP DUST)
ACGIH TLV:10 MG/M3 (RESP DUST)
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
= Wt:57.4
Name:QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
= Wt:.2
OSHA PEL:0.1 MG/M3(RESP DUST)
ACGIH TLV:0.1 MG/M3(RESP DUST)
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN OR EYE
CNTCT, DEPENDING ON CNDTNS OF USE. TO MINIMIZE EXPOS, FOLLOW RECOMS
FOR PROPER USE, VENT & PERS PROT EQUIP. ACUTE: IRRIT OF EYES, SKIN
& UPPER RESP SYS. IN CONFI NED AREA VAPS IN HIGH CONC MAY CAUSE
HDCH, NAUS OR DIZZ. REDNESS & ITCH OR BURNING SENSATION MAY
INDICATE EYE OR EXCESSIVE SKIN EXPOS. CHRONIC: CARBON BLACK IS
CLASSIFIED BY IARC AS POSSIBLY CARCIN TO HUMANS (GROUP 2B) BASED
ON EXPERIMENTAL ANIMAL DATA, HOWEVER, THERE IS INSUFFICIENT EVID IN
HUMANS FOR ITS CARCIN. CRYSTALLINE SILICA (QUARTZ, CRISTOBALITE) IS
LISTED BY IARC & NTP. LONG TERM EXPOS T O HIGH LEVELS OF (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ AND
CRISTOBALITE: IARC MONOGRAPHS, VOL 68, PG 41, 1997:GROUP 1. NTP 9TH
ANNUAL REPORT ON CARCINOGENS, 1998:REASONABLY ANTICIPATED TO BE
HUMAN CARCINOGEN.
Effects of Overexposure:HLTH HAZS: SILICA DUST, WHICH CAN OCCUR ONLY
WHEN SANDING OR ABRADING DRY FILM, MAY CAUSE LUNG DMG (SILICOSIS) &
POSS CANCER. ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN. IT
HAS BEEN SHOWN TO EN SURE BIRTH DEFECTS IN RATS & MICE AT HIGH
DOSES WHEN GIVEN IN DRINKING WATER OR BY GAVAGE. THERE IS NO
EVIDENCE TO INDICATE IT CAUSES BIRTH DEFECTS IN HUMANS. PRLNGD
OVEREXP TO SOLV INGREDS LISTED MAY CAUSE ADVERSE EFTS TO LIVER &
URINARY SYSTEMS. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3
DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT
ATTAINABLE IN THE WORKPLACE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHALATION: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREAS
THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE REUSE. EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: GET
MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG
NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS
TO PREVENT PRESS URE BUILD-UP AND POSSIBLE AUTOIGNITION OR
EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
====================== Handling and Storage ======================
Handling and Storage Precautions:DOL STORAGE CATEGORY - NOT APPLICABLE.
KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED
CONTAINERS WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE
INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.
Other Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST.
AVOID CNTCT W/SKIN & EYES. WASH HANDS AFTER USING. THESE COATINGS
MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED "AS
DUST" IN INGRED SEC TION) WHICH MAY BE PRESENT AT HAZ LEVELS ONLY
DURING SANDING/ ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE
(SUPDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC
LIMS BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD
BY NIOSH FOR PROT AGAINST MATLS LISTED. WHEN SANDING, WIREBRUSHING,
ABRADING, BURNING OR WELDING DRIED FILM, WEAR PARTICULATE RESP
APPRVD BY NIOSH FOR PROT AGAINST NON-VOLATILE MATLS LISTED IN
INGRED SECTION.
Ventilation:LOC EXHST PREFERABLE. GEN EXHST ACCEPTABLE IF EXPOS TO
MATLS LISTED IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA
STDS 1910.94, 1910.107, 1910.108.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
Supplemental Safety and Health
OTHER PRECS: LISTED IN INGRED SECTION, APPLIC LIMITS FOR NUISANCE DUSTS
ARE ACGIH TLV 10 MG/M3 (TDUST), 5 MG/M3 (RESPIRABLE FRACTION), OSHA
PEL 15 MG/M3 (TDUST) 5 MG/M3 RESPIRABLE FRACTION. PHYSICAL D ATA -
WT PER GAL (LBS): 10.7. VOC TOTAL: 0.2 LBS/GAL; VOC LESS WATER &
FEDERALLY EXEMPT SOLVS: 0.9 LBS/GAL.
================== Physical/Chemical Properties ==================
Boiling Pt:>44.4C, 112.F
B.P. Text:112-477F
Vapor Pres:SEE INGREDS
Vapor Density:HVR/AIR
Spec Gravity:1.3-1.46
pH:9.0-9.1
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:45-82
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN INGREDIENT SECTION.
===================== Ecological Information =====================
Ecological:N/P. TOXICOLOGICAL INFO (CONT): DOGS; IN RATS AND RABBITS
IT WAS ALWAYS GIVEN IN COMBINATION WITH OTHER SEX HORMONES. WHEN
GIVEN ALONE, IT INCREASED THE INCIDENCE OF OVARIAN, UTERINE AND
MAMMARY TUM ORS IN MICE. NEONATAL TREATMENT WITH PROGESTERONE
ENHANCED THE OCCURRENCE OF PRECANCEROUS AND CANCEROUS LESIONS OF
THE GENITAL TRACT AND RESULTED IN INCREASED MAMMARY TUMORIGENESIS
IN FEMALE RATS. AC UTE TOXICITY LEVEL: INSUFFICIENT DATA. TARGET
EFFECTS: POISONING MAY AFFECT THE LIVER.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM PRODUCTS IS NOT CONSIDERED HAZARDOUS
AS DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA)
40 CFR 261. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE
CLOSED CONTAINER. DISP OSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS REGARDING POLLUTION.
=================== MSDS Transport Information ===================
Transport Information:N/P. WORK HYGIENE PRACTICES (CONT): OPERATED IN
CONTINUOUS-FLOW MODE. ANY SELF-CONTAINED BREATHING APPARATUS WITH A
FULL FACEPIECE OPERATED IN PRESS-DEMAND MODE OR OTHER POS PRESSURE
MODE. FOR FIREFI GHTING & OTHER IMMED DANGEROUS TO LIFE OR HEALTH
CONDITIONS: ANY SELF-CONTAINED BREATHING APP W/FULL FACEPIECE &
OPERATED IN PRESSURE-DEMAND/OTHER POSITIVE-PRESSURE MODE. ANY
SUPPLIED-AIR RESP W/FULL FACEPIECE & OPERATED IN PRESSURE
DEMAND/OTHER POSITIVE-PRESSURE MODE IN COMBINATION WITH AN
AUXILIARY SELF-CONTAINED BREATHING APPARATUS OPERATED IN
PRESSURE-DEMAND OR OTHER POSITIVE-PRESSURE MODE.
===================== Regulatory Information =====================
SARA Title III Information:ETHYLENE GLYCOL IS SUBJECT TO THE REPORTING
REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
(SARA) SECTION 313, 40 CFR 372.65 C.
Federal Regulatory Information:ALL CHEMICALS IN THESE PRODUCTS ARE
LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY.
State Regulatory Information:CALIFORNIA PROPOSITION 45: WARNING: THESE
PRODUCTS CONTAIN CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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