===================== Product Identification =====================
MSDS NAME:PERMA-LOK HM 118, 78-4307
Status Code:A
MSDS Number: CKYXK
=== Responsible Party ===
Company:NATIONAL STARCH AND CHEMICAL CORP
Address:10 FINDERNE AVE
Box:6500
City:BRIDGEWATER
State:NJ
ZIP:08807
Country:US
Info Phone Num:908-685-5379; FAX:908685-5306
Emergency Phone Num:908-685-5000
Preparer's Name:PHILIP A. TOSCANO
CAGE:85091
=== Contractor Identification ===
Company:NATIONAL STARCH AND CHEMICAL CORP
Address:10 FINDERNE AVE
Box:6500
City:BRIDGEWATER
State:NJ
ZIP:08807
Country:US
Phone:908-685-5379; FAX:908685-5306
CAGE:85091
============= Composition/Information on Ingredients =============
Name:TETRAETHYLENE GLYCOL DIMETHACRYLATE
CAS:109-17-1
RTECS #:OZ4000000
> Wt:1.
Name:2-HYDROXYETHYL METHACRYLATE
CAS:868-77-9
RTECS #:OZ4725000
> Wt:1.
Other REC Limits:3 PPM (MANUFACTURER)
Name:CUMENE HYDROPEROXIDE
CAS:80-15-9
RTECS #:MX2450000
> Wt:1.
OSHA PEL:50 PPM (SKIN)
ACGIH TLV:50 PPM (SKIN)
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL RAT:382MG/KG CUMENE HYDROPEROXIDE
Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE IRRITANT. HARMFUL IF SWALLOWED.
EYE: IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED PROMPTLY.
SKIN CONTACT: FREQUENT OR PROLONGED CONTACT MAY IRRITATE AND CAUSE
DERMATITIS. MAY CAUSE SKIN SENSITIZATION, A PARTIAL OR WHOLE-BODY
DERMATITIC RASH EXPERIENCED AFTER EXPOSURE, HOWEVER MINIMAL.
INHALATION: BASED ON ITS LOW VOLATILITY, PRODUCT IS NOT CONSIDERED
TO BE A RESPIRATORY HAZARD UNDER NORMAL CONDITIONS OF USE.
IRRITATING AND/OR TOXIC VAPORS MAY BE RELEASED AT ELEVATED
TEMPERATURES. INGESTION: INGESTION EFFECTS HAVE NOT BEEN EVALUATED
BUT ARE ASSUMED TO CAUSE NAUSEA AND VOMITING. ( SIGNS AND SYMPTOMS
OF OVEREXPOSURE)
Explanation of Carcinogenicity:CARCINOGEN - NO.
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CONT):
CHRONIC (LONG TERM) EFFECTS OF EXPOSURE: ROUTE OF ENTRY: SKIN
CONTACT; EYE CONTACT; INGESTION. EFFECTS OF CHRONIC EXPOSURE: IN
CERTAIN INDIVIDUALS, SENSITIZAT ION MAY OCCUR CAUSING DERMATITIS
WITH EVEN MINIMAL CONTACT. DUE TO SKIN ABSORBTION WITH EXCESSIVE
CONTACT, PRODUCT MAY PRODUCT NERVOUS SYSTEM EFFECTS, I.E; ATAXIA.
TARGET ORGANS: SKIN; EYES.
Medical Cond Aggravated by Exposure:N/P.
======================= First Aid Measures =======================
First Aid:EYE: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR
AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER LIDS. GET PROMPT
MEDICAL ATTENTION. SKIN CONTACT: FLUSH EXPOSED AREAS THOROUGHLY
WITH SOAP AND WATER UNTIL ALL CHEMICAL IS REMOVED. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. INHALATION: FIRST
AID IS NOT NORMALLY REQUIRED. REMOVE TO FRESH AIR. IF BREATHING IS
DIFFICULT, GIVE OXYGEN . IF BREATHING HAS STOPPED, GIVE ARTIFICIAL
RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING. IF INDIVIDUAL IS CONSCIOUS, GIVE MILK / WATER TO DILUTE
STOMACH CONTENTS. KEEP WARM & QUIET. GET PROMPT (NEUTRALIZING
AGENT)
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=110.C, 230.F
Autoignition Temp:Autoignition Temp Text:N/D
Extinguishing Media:CO2; DRY CHEMICAL; FOAM; WATER FOG.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD BE EQUIPPED WITH
SELF-CONTAINED BREATHING APPARATUS (NIOSH APPROVED - ) TO PROTECT
AGAINST POTENTIALLY TOXIC AND IRRITATING FUMES; COOL EXPOSED
EQUIPMENT WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:POLYMERIZATION MAY TAKE PLACE AT ELEVATED
TEMPERATURES. NFPA FLAMMABILITY HAZARD CLASS: 1 = SLIGHT.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN
DO SO WITHOUT RISK. FOR SMALL SPILLS TAKE UP WITH SAND OR OTHER
INERT ABSORBENT MATERIAL AND PLACE IN A CONTAINER FOR LATER
DISPOSAL. NOTE: IN BULK QUANT ITIES, PRODUCT ABSORBED ON INERT
MATERIAL MAY POLYMERIZE GENERATING SIGNIFICANT HEAT AND PRESSURE.
VENT DISPOSAL CONTAINER TO PREVENT BUILDUP OF PRESSURE. CAN
CAREFULLY SOLIDIFY (OTHER INFORMATION)
Neutralizing Agent:N/P. FIRST AID (CONT): MEDICAL ATTENTION. DO NOT
ATTEMPT TO GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORAGE TEMPERATURE: ROOM TEMP.
SPECIAL SENSITIVITY: AVOID EXCESSIVE HEAT. HANDLING/STORAGE: STORE
OUT OF DIRECT SUNLIGHT IN A DRY AREA. MAXIMUM TEMPERATURE IS 100F.
VENTILATION REQUIREMENTS:GENE RAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED UNDER NORMAL HANDLING CONDITIONS.
USE NIOSH APPROVED RESPIRATOR, IF VAPOR OR MIST LEVELS ARE
IRRITATING.
Ventilation:GENERAL.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:NO SPECIAL CLOTHING REQUIRED FOR LOW VOLUME
ACTIVITY. EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:REMOVE CLOTHING AND LAUNDER BEFORE REUSE IF
CONTAMINATED WITH PRODUCT. WASH HANDS WITH SOAP AND WATER IF
CONTACT WITH PRODUCT OCCURS OR BEFORE EATING, DRINKING, SMOKING, OR
USING TOILET FACILITIES.
Supplemental Safety and Health
CAS NUMBER OF PRODUCT: UNASSIGNED. SYNONYM NAME(S): NONE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:POLYMERIZES 5.0 G/KG RAT. NOTES ON ORAL TOXICITY: LOW ORDER
OF TOXICITY. DERMAL LD50, SPECIES TESTED: > 5.0 G/KG RABBIT. NOTES
ON DERM AL TOXICITY: FREQUENT OR PROLONGED CONTACT MAY IRRITATE THE
SKIN. MAY CAUSE SKIN SENSITIZATION, A PARTIAL OR WHOLE-BODY
DERMATITIC RASH EXPERIENCED AFTER EXPOSURE, HOWEVER MINIMAL. MAY BE
ABSORBED THR OUGH THE SKIN. NOTES ON INHALATION TOXICITY: VAPORS
AND/OR AEROSOLS MAY CAUSE IRRITATION. VAPORS AND/OR AEROSOLS WHICH
MAY BE FORMED AT ELEVATED TEMPERATURES MAY BE IRRITATING TO EYES
AND RESPIRATORY TRACT. AVOID BREATHING (TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE DISPOSAL SHOULD BE IN ACCORDANCE WITH
EXISTING FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
EMPTY CONTAINER WARNINGS: EMPTY CONTAINERS MAY CONTAIN PRODUCT
RESIDUE;FOLLOW MSDS AND LABEL WARNINGS EVEN AFTER THEY HAVE BEEN
EMPTIED.
=================== MSDS Transport Information ===================
Transport Information:DOT SHIPPING NAME: NONE. DOT HAZARD CLASS: NOT
REGULATED. DOT REPORTABLE QUANTITY: NONE. UNITED NATIONS
INFORMATION: U.N. NUMBER: N/A. U.N. CLASS: N/A. ECOLOGICAL
INFO (CONT): VAPORS OR MIS TS. NOTES ON EYE IRRITATION: SEVERELY
IRRITATING. IF NOT REMOVED PROMPTLY, WILL INJURE EYE TISSUE, WHICH
MAY RESULT IN PERMANENT DAMAGE. OTHER NOTES ON TOXICITY:
SENSITIZER. RAW MATERIAL NAME: CUMEN E HYDROPEROXIDE. ORAL LD50,
SPECIES TESTED: 800.0 MG/GK RAT; 382.0 MG/KG RAT. NOTES ON ORAL
TOXICITY: CORROSIVE TO MOUTH, ESOPHAGUS AND STOMACH. NOTES ON
DERMAL TOXICITY: CORROSIVE, CAUSES PERMANENT S KIN DAMAGE. (SARA
III)
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT CONTAINS (OR IS) A TOXIC
CHEMICAL FOR ROUTINE ANNUAL CHEMICAL RELEASE REPORTING UNDER
SECTION 313: CUMENE HYDROPEROXIDE CAS# 80-15-9, 3%.
TRANSPORT INFO (CONT):INHALATION LC50, S PECIES TESTED: 700.0 PPM
6.00 HOURS RAT. NOTES ON INHALATION TOXICITY: INHALATION OF DUST OR
VAPOR MAY CAUSE SEVERE IRRITATION TO THE NASAL PASSAGES AND/OR THE
RESPIRATORY SYSTEM. MAY CAUSE BREATHING DISORDERS AND/OR LUNG
DAMAGE. AVOID BREATHING VAPORS OR MISTS. NOTES ON EYE IRRITATION:
CORROSIVE. WILL CAUSE BURNS AND PERMANENT TISSUE DAMAGE. AQUATIC
TOXICITY, SPECIES TEATED: 7.000 MG/L DAPHNIA MA GNA; 7.400 MG.L
GREEN ALGEA.
Federal Regulatory Information:TSCA-ALL COMPONENTS ARE ON THE TSCA
INVENTORY. FOR REGULAROTY INFORMATION CONTACT:PHILIP A.
TOSCANO, REGULATORY COORDINATOR, PERMABOND INTERNATIONAL DIVISION,
NATIONAL STARCH & CHEMICAL COMPANY, FINDERNE AVENUE, PO BOX 6500,
BRIDGEWATER, NJ 08807, USA, TELEPHONE 908-685-5379,
FAX:908-685-5306.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|