===================== Product Identification =====================
MSDS NAME:HYDROCHLORIC ACID REAGENT, 8885-032204
Status Code:A
Kit Part:Y
MSDS Number: CLBVL
=== Responsible Party ===
Company:SHERWOOD MEDICAL COMPANY
Address:1915 OLIVE STREET
City:ST. LOUIS
State:MO
ZIP:63103-1722
Country:US
Info Phone Num:(314) 241-5700
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:31-42861.4
Chemtrec Ind/Phone:(800)424-9300
CAGE:05963
=== Contractor Identification ===
Company:SHERWOOD MEDICAL COMPANY
Address:1915 OLIVE STREET
Box:City:ST. LOUIS
State:MO
ZIP:63103-1722
Country:US
Phone:(314) 241-5700
CAGE:05963
============= Composition/Information on Ingredients =============
Name:HYDROCHLORIC ACID. (SYNONYM: HYDROGEN CHLORIDE)
CAS:7647-01-0
RTECS #:MW4025000
= Wt:13.3
OSHA PEL:C7 MG/M3;C5 PPM
ACGIH STEL:C7.5 MG/M3;C5 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
= Wt:86.7
===================== Hazards Identification =====================
LD50 LC50 Mixture:HCL: INHAL: LC50 = 3124 PPM/1HR. (RAT)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PERTAINS TO EFFECTS ASSOCIATED WITH
AQUEOUS SOLUTIONS OF HYDROCHLORIC ACID. ACUTE: INHAL: CORROSIVE TO
TISSUES OF MUCOUS MEMBRANES, UPPER RESPIRATORY TRACT. AFTER SHORT
EXPOSURE TO 35 PPM, COMPOUND MA Y CAUSE IRRITATION TO THROAT.
INHALATION MAY BE FATAL AS RESULT OF SPASM, INFLAMMATION & FLUID
BUILD-UP IN LARYNX, BRONCHI & LUNG, & LUNG INFLAMMATION.
INGESTION: CORROSIVE TO MUCOUS MEMBRANES OF M OUTH, THROAT,
ESOPHAGUS, & STOMACH. CIRCULATORY COLLAPSE & DEATH MAY OCCUR. SKIN:
CORROSIVE TO SKIN. EYE: EXTREMELY DESTRUCTIVE TO EYES. IRRITATION,
PERMANENT VISUAL DAMAGE (INCLUDING LOSS OF VISION) MAY OCCUR.
(SIGNS/SYMP OF OVEREXPOSURE).
Explanation of Carcinogenicity:HYDROCHLORIC ACID IS NOT LISTED AS
CARCINOGENIC BY NTP, IARC OR OSHA. NO HUMAN DATA AVAILABLE. IN
ANIMAL DATA REPORTED IN LITERATURE, HYDROCHLORIC ACID WAS NOT FOUND
TO BE CARCINOGENIC. HOWEVER, THIS COMPOUND IS REPORTED TO BE
MUTAGENIC IN MAMMALIAN & BACTERIAL TEST SYSTEMS.
Effects of Overexposure:INHALATION: BURNING SENSATION, COUGHING,
WHEEZING, SNEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE,
NAUSEA, & VOMITING. INGESTION: DIFFICULTY SWALLOWING, NAUSEA,
VOMITING, INTENSE THIRST, DIARRHEA , INFLAMMATION OF KIDNEYS,
CHILLS, AND SHOCK. SKIN: BURNING, IRRITATION OR RASH & INCREASED
SENSITIVITY OF THE SKIN TO SUNLIGHT. EYE: IRRITATION & PERMANENT
VISION DAMAGE. HEALTH HAZARD ACUTE/CHRONIC (CONT'D): TARGET
ORGANS: RESPIRATORY SYSTEM, SKIN, & EYES. CHRONIC:
CHRONIC/PROLONGED EXPOS MAY RESULT IN CHANGES IN LUNG FUNCTION,
CHRONIC BRONCHITIS, DERMATITIS, DIGEST DISEASES (CHARACTERIZED BY E
ROSION OF DENTAL ENAMAL), (OTHER INFO)
Medical Cond Aggravated by Exposure:PERSONS WITH IMPAIRED LUNG FUNCTION
MAY BE AT INCREASED RISK FROM EXPOSURE TO HYDROCHLORIC ACID.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, PERFOM ARTF RESP.
IF BRTHG DFCLT, ADMIN OXYG. KEEP WARM. GET IMMED MED ATTN. INGEST:
IF SWALLOWED, DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE SEVERAL
GLASSES OF ICE WATER OR VERY COLD WATER TO DILUTE. CALL A MD OR
POIS CTL CTR IMMED. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. IF UNCONSCIOUS, KEEP AIRWAY OPEN AND LAY ON SIDE WITH HEAD
LOWER THAN BODY. GET IMMED MED ATTN. SKIN: REMOVE AND ISOLATE
CONTAM CLOTHING. WASH SKIN WITH SOAP AND FLUSH THOROUGHLY WITH
PLENTY OF WATER. OBTAIN MED ATTN IF IRRIT DEVELOPS, OR OTHER SYMPS
OCCUR. EYE: CHECK F OR CONTACT (OTHER PREC).
===================== Fire Fighting Measures =====================
Flash Point:NO DATA AVAIL.
Autoignition Temp:Autoignition Temp Text:N/AVAI
Lower Limits:NO DATA.
Upper Limits:NO DATA.
Extinguishing Media:THIS PRODUCT IS NOT FLAMMABLE. FOR FIRES INVOLVING
PACKAGING MATERIALS, USE AN AGENT APPROPRIATE FOR COMBUSTIBLES AND
SURROUNDING CLASS(ES) OF FIRE. AUTOIGNITION TEMP: NO DATA AVAIL.
Fire Fighting Procedures:KEEP UNNECESSARY PEOPLE AWAY. ISOLATE HAZARD
AREA AND DENY ENTRY. REMOVE CONTAINERS EXPOSED TO FIRE IF POSSIBLE,
OTHERWISE COOL THEM FROM THE SIDE WITH WATER SPRAY. EMERGENCY
EQUIPMENT INCLUDING NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS (SCBA) & FULL FIRE FIGHTING TURNOUT GEAR SHOULD BE WORN
BY FIRE FIGHTERS.
Unusual Fire/Explosion Hazard:HYDROCHLORIC ACID SOLUTIONS ARE NOT
COMBUSTIBLE. HOWEVER, CONTACT WITH COMMON METALS, PRODUCES HYDROGEN
WHICH MAY FORM EXPLOSIVE MIXTURES WITH AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:ISOLATE SPILL. WEAR SPLASH-PROOF SFTY GOGG &
CHEM RESIST GLOVES. CONFINE AND CONTAIN SMALL SPILLS USING INERT
MATL (E.G., PAPER TOWELS, SPILL CONTROL PILLOWS, ABSORB
PARTICULATE). FOR LARGE SPILLS, CO NTAIN BY DIKING W/DRY SAND,
SORBENT BOOMS OR OTHER ABSORB MATL. PVNT RUNOFF INTO SEWERS, STORM
DARAINS, SURFACE WATERS, AND SOIL. NEUT BY APPLYING BASIC
SUBSTANCES SUCH AS SODA ASH (WASTE DISPOSAL).
Neutralizing Agent:BASIC SUBSTANCES SUCH AS SODA ASH AND SLAKED LIME OR
USING A COMMERCIALLY AVAILABLE ACID SPILL KIT.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
STORE AT ROOM TEMPERATURE IN A DRY, WELL-VENTILATED AREA, AWAY FROM
INCOMPATIBLE MATL.
Other Precautions:FIRST AID (CONT'D): LENSES & REMOVE IF PRESENT. HOLD
EYELIDS OPEN AND IMMED FLUSH W/PLENTY OF H*20/NORMAL SALINE
SOLUTION (FOR AT LEAST 15 MINS) UNTIL WASH WATER PH IS NEUTRAL,
WHILE SEEKING IMMED ME D ATTN. DO NOT PUT ANY MEDICATIONS IN EYES
UNLESS INSTRUCTED BY PHYSICIAN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A RESPIRATOR IS NOT REQUIRED UNDER NORMAL
CONDITIONS OF USE IF EXPOSURE LIMITS ARE KEPT BELOW ESTABLISHED
LIMITS. IN THE EVENT THAT RESPIRATORY PROTECTION IS REQUIRED, A
NIOSH APPROVED ACID-RESISTANT RESPIRATOR MUST BE USED.
Ventilation:ADEQUATE LOCAL AND/OR GENERAL EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP AIRBORNE CONCENTRATIONS BELOW EXPOSURE
LIMITS.
Protective Gloves:IMPERVIOUS GLOVES. SELECTION OF APPROP GLOVES DEPENDS
ON (WORK HYGIENE)
Eye Protection:ANSI-APPROVED CHEMICAL SAFETY GOGGLES & FULL FACESHIELD
.
Other Protective Equipment:READILY ACCESSIBLE EYEWASH FACILITY AND
QUICK DRENCH SAFETY SHOWER MEETING ANSI DESIGN CRITERIA. DEPENDING
ON OPERATION, LABCOAT, APRON OR OTHER IMPERMEABLE CLOTHING MAY BE
APPROPRIATE.
Work Hygienic Practices:CLEAN CONTAMINATED CLOTHING BEFORE REUSE, OR
DISPOSE OF PROPERLY. GLOVES (CONT'D): PROPERTIES OF COMPOUND &
SPECIFIC CONDITIONS OF USE. NATURAL RUBBER GLOVES FOUND TO OFFER
GOOD PROTECTION (SUPP SAFETY)
Supplemental Safety and Health
WORK HYGIENE (CONT'D): AGAINST SOLUTIONS CONTAINING <30% HCL.
QUALITATIVE DATA INDICATES THE FOLLOWING GLOVE TYPES ALSO PROVIDE
GOOD RESISTANCE: POLYVINYL CHLORIDE, POLYETHYLENE, NITRILE &
POLYVINYL C HLORIDE, NEOPRENE, VITON & BUTYL RUBBER. POLYVINYL
ALCOHOL GLOVES PROVIDE POOR CHEMICAL RESISTANCE.
================== Physical/Chemical Properties ==================
Boiling Pt:=110.C, 230.F
B.P. Text:20.24% IN WATER.
Melt/Freeze Pt:M.P/F.P Text:NO DATA AVAILABLE.
Decomp Temp:Decomp Text:NO DATA AVAILABLE.
Vapor Pres:NO DATA AVAILABLE.
Vapor Density:NO DATA.
Spec Gravity:1.09
pH:<1.0
Viscosity:NO DATA AVAILABLE.
Solubility in Water:SEE FEDERAL REGULATIONS
Appearance and Odor:CLEAR LIQUID. ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BASES, AMINES, ALKALI METALS, COPPER, COPPER ALLOYS, & ALUMINUM. INCR
IN TEMP/ PRESS OCCUR WHEN HYDROCHLORIC ACID WAS MIXED W/ FOLLOWING
CHEMS IN CLOSED CONTR:ACETIC ANHYDRIDE, 2-AMINOETHANOL, AMMONIUM
HYDROXIDE, CHLOROSULF
Stability Condition to Avoid:STABLE UNDER NORMAL COND OF USE & WHEN
STORED AT ROOM TEMP. AVOID HEAT, HIGH TEMPS, PRESSURE, MECH SHOCK,
CONTACT W/HEAT & FLAMM MATL. AVOID HEATING OR RUBBING W/OXIDIZABLE
CMPDS.
Hazardous Decomposition Products:HYDROGEN CHLORIDE GAS. MATLS TO AVOID
(CONT'D): ETHYLENE DIAMINE, ETHYLENEMINE, OLEUM, PROPIOLACTONE
(BETA-), SODIUM HYDROXIDE, SULFURIC ACID, VINYL ACETATE. MAY
CORRODE STEEL & ATTACKS (COND TO AVOID)
Conditions to Avoid Polymerization:HAZ DECOMP (CONT'D): NEARLY ALL
FORMS OF METAL. INADVERTANT MIXING OF HCL W/FORMALDEHYDE COULD FORM
BIS(CHLOROMETHYL)ETHER.
=================== Toxicological Information ===================
Toxicological Information:HYDROCHLORIC ACID. INHALATION: LC50=3124
PPM/1HR. (RAT); 1108 PPM/1HR. (MOUSE). LCLO=1300 PPM/30 MIN.
(HUMAN); 3000 PPM/5 MIN. (HUMAN); 4413 PPM/30 MIN. (RABBIT), ACUTE
PULMONARY EDEMA, FATTY LIVER DE GENERATION; 4413 PPM/30 MIN.
(GUINEA PIG), ACUTE PULMONARY EDEMA; LIVER EFFECTS. INGEST: LD50 =
900 MG/KG (RABBIT). EYE: APPLICATION OF 5 MG TO EYES OF RABBIT FOR
30 SECONDS (FOLLOWED BY RINSING) CA USED MILD IRRIT. SKIN: NO DATA
AVAIL. TARGET ORGAN DATA: IN MULTIDOSE STUDIES W/RATS, INHAL (685
UG/M3 FOR 84 DAYS) CAUSED MUSCLE CONTRACTIONS OR CHANGE IN URINE
COMPOSITION/BIOCHEMICAL EFFECT. RPTD ORAL ADMIN OF DILUTE COMPOUND
(SARA)
===================== Ecological Information =====================
Ecological:NO DATA AVAILABLE FOR THE PRODUCT. THE FOLLOWING INFO HAS
BEEN REPORTED FOR THE INGREDIENT, HYDROCHLORIC ACID: LC50 = 100-330
PPM (48 HR, SHRIMP AND STARFISH); 240 MG/L (48 HR, CRAB); 3.6 MG/L
(48 HR , BLUEGILL); 178 MG/L (GOLDFISH). CHEMICAL FATE INFO: NO
DATA AVAILABLE FOR THE PRODUCT. THE FOLLOWING INFO HAS BEEN
REPORTED FOR THE INGREDIENT, HYDROCHLORIC ACID: WHEN RELEASED TO
SOIL, EXTENSIVE E VAPORATION WILL OCCUR, BUT HCI WILL TRANSPORT
THROUGH SOIL AND SOME ACID MAY REACH GROUNDWATER. HYDROGEN CHLORIDE
WILL ALMOST COMPLETELY DISSOCIATE IN WATER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE & LOCAL REGULATIONS. SPILL/RELEASE (CONT'D):
AND SLAKED LIME OR USING A COMMERCIALLY AVAIL ACID SPILL KIT.
DECONTAM AREA. PLACE CONT AMD SORBENT OR OTHER CONTAMD MATL INTO
APPRVD WASTE CONTR FOR DISP. COMPLY WITH ALL APPLIC REGS ON S PILL
REPORTING. PRACTICE CONTAMINATION AVOIDANCE.
=================== MSDS Transport Information ===================
Transport Information:U. S. DOT: HYDROCHLORIC ACID MIXTURES ARE
REGULATED BY DOT AS FOLLOWS: PROPER SHIPPING NAME: HYDROCHLORIC
ACID, SOLUTION. LABEL REQUIRED: CORROSIVE. HAZARD CLASS: 8.
IDENTIFICATION NUMBER: UN1789. PAC KAGING GROUP: II. ACCEPTABLE
MODES OF TRANSPORTATION: AIR, RAIL, ROAD, AND WATER. THE FOLLOWING
INTERNATIONAL REGULATIONS APPLY TO HYDROCHLORIC ACID SOLUTIONS
(INTERNATIONAL AIR AND WATER SHIPMENTS): IMO CLASS: 8, CORROSIVE.
UN NUMBER: 1789. LABEL REQUIRED: CORROSIVE. IMDG PACKAGING GROUP:
II.
===================== Regulatory Information =====================
SARA Title III Information:HYDROCHLORIC ACID: SARA TITLE III SECIONS
302, 313, DE MINIMUS CONCENTRATION: 1.0%. TOXICOLOGICAL (CONT'D):
TO DOGS INDUCED ACUTE/CHRONIC GASTRITIS & DUODENITIS & LED TO
ULCERS ON PYFORUS. MUTAGENIC E FFECTS: HCL: DNA REPAIR (E.COLI);
SEX CHROMOSOME LOSS & NONDISJUNCTION (D. MELANOGASTER-INHALATION,
ORAL); CYTOGENIC ANALYSIS (GRASSHOPPER-PARENTERAL; HAMSTER-LUNG,
OVARY). REPRODUCTIVE/TERATOGENIC E FFECTS: HCL: INHALATION OF 450
MG/M3 FOR 1 HOUR 1 DAY PRIOR TO MATING CAUSED FETOTOXICITY &
DEVELOPMENTAL ABNORMALITIES (HOMEOSTASIS) IN RATS.
Federal Regulatory Information:HYDROCHLORIC ACID: EPA TSCA CHEMICAL
INVENTORY; TSCA SECTION 8(E); EPA EXTREMELY HAZARDOUS SUBSTANCE
LIST; CERCLA HAZARDOUS SUBSTANCES, RQ: 5000 LB; CLEAN AIR ACT
SECTION 112; CLEAN WATER ACT SECTION 311. PHYSICAL/CHEMICAL
PROPERTIES: SOLUBILITY: WATER: VERY SOLUBLE (SOLUBLE IN LESS THAN
ONE PART WATER). OTHER SOLVENTS: SOLUBLE IN ALCOHOL, BENZENE,
ETHER. USE/SIZE: COMPONENT OF STONE ANALYSIS KIT USED FOR
QUANLITATIVE ANALYSIS OF THE CHEMICAL CONSTITUENTS OF URINARY
CALCULI/2 OZ.
State Regulatory Information:HYDROCHLORIC ACID: MASSACHUSETTS SUBSTANCE
LIST (EXTRAORDINARILY HAZARDOUS SUBSTANCE); NEW JERSEY RIGHT TO
KNOW HAZARDOUS SUBSTANCE LIST (ENVIRONMENTAL HAZARD); PENNSYLVANIA
HAZARDOUS SUBSTANCE LIST ( ENVIRONMENTAL HAZARD). EMERGENCY
OVERVIEW: HYDROCHLORIC ACID REAGENT IS CLEAR, ODORLESS LIQUID & IS
CORROSIVE. SOLUTIONS CONTAINING HYDROCHLORIC ACID ARE CORROSIVE TO
RESPIRATORY TRACT/SKIN/EYES. PROD UCT WILL DECOMPOSE TO HYDROGEN
CHLORIDE GAS. PRODUCT NOT COMBUSTIBLE; HOWEVER, ON CONTACT WITH
COMMO N METALS IT CAN PRODUCE HYDROGEN WHICH MAY FORM EXPLOSIVE
MIXTURES WITH AIR.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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