=====================  Product Identification  =====================

MSDS NAME:P4030, PHLOXINE B CERTIFIED
NIIN:00-281-1856
Status Code:A
MSDS Number: CLLNJ
=== Responsible Party ===
Company:SIGMA
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:314-771-5765
Preparer's Name:NOT PROVIDED
CAGE:UO068
=== Contractor Identification ===
Company:SIGMA
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178
Country:US
Phone:800-325-3010
CAGE:UO068

=============  Composition/Information on Ingredients  =============

Name:ACID RED 92
CAS:18472-87-2
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ORL RAT LD50: 8400 MG/KG
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION,
    INGESTION, OR SKIN ABSORPTION. MAY CAUSE EYE OR SKIN IRRITATION. TO
    THE BEST OF OUR KNOWLEDGE THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL
    PROPERTIES HAVE NOT BEEN TH OROUGHLY INVESTIGATED.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:NOT PROVIDED
Medical Cond Aggravated by Exposure:NOT PROVIDED

=======================  First Aid Measures  =======================

First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS
    AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. IN CASE OF CONTACT,
    IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. IF
    INHALED, REMOVE T O FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
    RESPIRATION. IF BRATHING IS DIFFICULT GIVE OXYGEN. CALL PHYSICIAN.
    WASH CONTAMINATED CLOTHING BEFORE REUSE.

=====================  Fire Fighting Measures  =====================

Flash Point:NOT PROVIDED
Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
    APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
    PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES,
    RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN A BAG AND
    HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND
    WASH SPILL SITE AFTER MATER IAL PICKUP IS COMPLETE.

======================	Handling and Storage  ======================

Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN COOL DRY
    PLACE. MECHANICAL EXHAUST REQUIRED.
Other Precautions:AVOID INHALTION. AVOID CONTACT WITH EYES, SKIN AND
    CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. WASH THOROUGHLY
    AFTER HANDLING.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:CHEMICAL SAFETY GOGGLES
Other Protective Equipment:SAFETY SHOWER AND EYE BATH.
Work Hygienic Practices:AVOID INHALTION. AVOID CONTACT WITH EYES, SKIN
    AND CLOTHING.. AVOID PROLONGED OR REPEATED EXPOSURE. WASH
    THOROUGHLY AFTER HANDLING. KEEP TIGHTLY CLOSED.
Supplemental Safety and Health
ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K =
    UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
    DETERMINED. N/E = NOT ESTABLISHED.

==================  Physical/Chemical Properties  ==================

HCC:N1
NRC/State Lic Num:NOT RELEVANT
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Spec Gravity:NOT PROVIDED
pH:NOT PROVIDED
Solubility in Water:NOT PROVIDED
Appearance and Odor:DARK-RED POWDER.
Corrosion Rate:NOT PROVIDED

=================  Stability and Reactivity Data  =================

STRONG OXIDIZING AGENTS
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
    CARBON DIOXIDE; HYDROGEN CHLORIDE GAS; HYDROGEN BROMIDE GAS.

===================  Toxicological Information	===================

Toxicological Information:LD50 (ORAL, RAT): 8400 MG/KG. ORAL-MUS LD50:
    310 MG/KG. IVN-MUS LD50: 310 MG/KG. ORL-DOG LD50: >4600 MG/KG

=====================  Ecological Information  =====================

Ecological:DATA NOT AVAILABLE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
    SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
    AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
    ENVIRONMENTAL REGULATIONS.

===================  MSDS Transport Information  ===================

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
    INFORMATION.

=====================  Regulatory Information  =====================

SARA Title III Information:NOT PROVIDED
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:NOT PROVIDED

=======================  Other Information  =======================

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***