===================== Product Identification =====================
MSDS NAME:HT90-1, CRYSTAL VIOLET SOLUTION
Status Code:A
MSDS Number: CLLQD
=== Responsible Party ===
Company:SIGMA-ALDRICH
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:314-771-5765
CAGE:JO751
=== Contractor Identification ===
Company:SIGMA-ALDRICH COMPANY
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:JO751
============= Composition/Information on Ingredients =============
Name:METHYL ALCOHOL
CAS:67-56-1
RTECS #:PC1400000
OSHA PEL:260 MG/M3;200 PPM
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ETHYL ALCOHOL
CAS:64-17-5
RTECS #:KQ6300000
OSHA PEL:1900 MG/M3;1000 PPM
ACGIH TLV:1880 MG/M3;1000 PPM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:TARGET ORGANS: NERVES, EYES, KIDNEYS,
LIVER, HEART. MAY BE HARMFUL BY INHALTION, INGESTION, OR SKIN
ABSORPTION. CAUSES SKIN IRRITATION. VAPOR OR MSIT IS IRRITATING TO
THE EYES, MUCOUS MEMBRANES AND UP PER RESPIRATORY TRACT.IRRITATING
TO EYES, SKIN AND RESPIRATORY SYSTEM.
Effects of Overexposure:MAY BE HARMFUL BY INHALTION, INGESTION, OR SKIN
ABSORPTION. CAUSES SKIN IRRITATION. VAPOR OR MSIT IS IRRITATING TO
THE EYES, MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT.AVOID
CONTACT WITH SKIN.
======================= First Aid Measures =======================
First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.SEEK MEDICAL ADVICE. IN
CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS
AMOUNTS OF WATER. IF INHALED, REMOVE TO FRESH AIR. IF NOT
BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED
PERSON IS CONSCIOUS. CALL PHYSIC IAN. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
===================== Fire Fighting Measures =====================
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.
COMBUSTIBLE LIQUID.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF
IGNITION. WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND
HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE AND PLACE IN
CLOSED CONTAINERS FOR DISPOSA L. USE NON SPARKING TOOLS. VENTILATE
AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM SOURCES OF IGNITION. NO
SMOKING.
Other Precautions:IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH
PLENTY OF WATER AND SEEK MEDICAL ADVICE. AVOID CONTACT WITH SKIN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR
Ventilation:USE ONLY IN CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES
Eye Protection:GOGGLES
Other Protective Equipment:SAFETY SHOWER AND EYE BATH, OTHER PROTECTIVE
CLOTHING. USE NON SPARKING TOOLS.
Work Hygienic Practices:DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON
SKIN, ON CLOTHING. WASH THOROUGHLY AFTER HANDLING. AVOID
PROLONGED/REPEATED EXPOSURE. KEEP TIGHTLY CLOSED. KEEP AWAY FROM
HEAT AND OPEN FLAME.
Supplemental Safety and Health
STORE IN A COOL DRY PLACE.
================== Physical/Chemical Properties ==================
HCC:F2
Appearance and Odor:LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, PEROXIDES, ACIDS, ACID CHLORIDES, ACID
ANHYDRIDES, ALKALI METALS, AMMONIA
Stability Condition to Avoid:MOISTURE
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON
DIOXIDE, NITROGEN OXIDES, HYDROGEN CHLORIDE GAS
=================== Toxicological Information ===================
Toxicological Information:ACUTE EFFECTS:MAY BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. CAUSES SKIN IRRITATION. VAPOR OR
MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT. TARGET ORGANS: NERVES,EYES,KIDNEYS,LIVER,HEART.
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE
==================== Disposal Considerations ====================
Waste Disposal Methods:THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DATA NOT PROVIDED BY MANUFACTURER.
===================== Regulatory Information =====================
SARA Title III Information:1% METHANOL (67-56-1); THIS PRODUCT IS
SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS.
Federal Regulatory Information:EUROPEAN INFORMATION:CAUTION; FLAMMABLE,
IRRITANT, IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. KEEP
AWAY FROM SOURCES OF IGNITION-NO SMOKING. IN CASE OF CONTACT WITH
EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL
ADVICE.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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