===================== Product Identification =====================
MSDS NAME:ZIRCONYL (IV)-CHLORIDE OCTAHYDRATE, 98+%, AC208370050
Status Code:A
MSDS Number: CLNCW
=== Responsible Party ===
Company:ACROS ORGANICS N.V.
Address:ONE REAGENT LANE
City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:800-227-6701
Emergency Phone Num:800-424-9300
Resp. Party Other MSDS Num.:REVISION #2
Chemtrec Ind/Phone:(800)424-9300
CAGE:TO107
=== Contractor Identification ===
Company:ACROS ORGANICS N.V.
Address:ONE REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Phone:800-227-6701;800-ACROS-01
CAGE:TO107
============= Composition/Information on Ingredients =============
Name:ZIRCONYL (IV) - CHLORIDE OCTAHYDRATE. (EINECS#: UNLISTED;
OSHA CONT'D: FINAL PELS: NONE LISTED, OSHA VACATED PELS: NO OSHA
VACATED PELS ARE LISTED FOR THIS CHEMICAL)
CAS:13520-92-8
RTECS #:ZH7250000
Fraction by Wt: 98%+%
Other REC Limits:OSHA: NONE LISTED
OSHA PEL:NONE LISTED
OSHA STEL:NONE LISTED
ACGIH TLV:NONE LISTED
ACGIH STEL:NONE LISTED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: DANGER! CORROSIVE.
HYGROSCOPIC. CAUSES EYE AND SKIN BURNS. MAY CAUSE SEVERE
RESPIRATORY TRACT IRRITATION WITH POSSIBLE BURNS. MAY CAUSE SEVERE
DIGESTIVE TRACT IRRITATION WITH POSSI BLE BURNS. TARGET ORGAN:
NONE. POTENTIAL HEALTH EFFECTS: INGESTION: MAY CAUSE SEVERE AND
PERMANENT DAMAGE TO DIGESTIVE TRACT. CAUSES GASTROINTESTINAL TRACT
BURNS. INHALATION: MAY CAUSE IRRITATION OF R ESPIRATORY TRACT WITH
BURNING PAIN IN NOSE AND THROAT, COUGHING, WHEEZING, SHORTNESS OF
BREATH AND PULMONARY EDEMA. CAUSES CHEMICAL BURNS TO RESPIRATORY
TRACT. INHALATION MAY BE FATAL AS A RESULT OF S PASM, INFLAMMATION,
(OVEREXPOSURE)
Explanation of Carcinogenicity:CARCINOGENICITY: ZIRCONYL (IV) CHLORIDE
OCTAHYDRATE: NOT LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA.
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CON'T): EDEMA
OF THE LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY
EDEMA. EYE: CAUSES EYE BURNS. SKIN: CAUSES SKIN BURNS. CHRONIC: NO
INFORMATION FOUND.
======================= First Aid Measures =======================
Eyes: GET MEDICAL AID IMMEDIATELY. DO NOT ALLOW VICTIM TO RUB
OR KEEP EYES CLOSED. EXTENSIVE IRRIGATION IS REQUIRED (AT LEAST 30
MINUTES). SKIN: GET MEDICAL AID IMMEDIATELY. IMMEDIATELY FLUSH SKIN
WIT H PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES WHILE
REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE
REUSE. DESTROY CONTAMINATED SHOES. INGESTION: DO NOT INDUCE
VOMITING. IF VICTIM IS CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF
MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL AID IMMEDIATELY. INHALATION: GET MEDICAL AID
IMMEDIATELY. REMOVE FROM EXPO SURE TO (TOXICOLOGICAL)
===================== Fire Fighting Measures =====================
Flash Point:NOT AVAILABLE
Extinguishing Media:USE EXTINGUISHING MEDIA MOST APPROPRIATE FOR THE
SURROUNDING FIRE.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED
BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH APPROVED OR
EQUIVALENT AND FULL PROTECTIVE GEAR. DURING A FIRE, IRRITATING AND
HIGHLY TOXIC GASES MAY BE GENERATED B Y THERMAL DECOMPOSITION OR
COMBUSTION.
Unusual Fire/Explosion Hazard:N/P. NFPA RATINGS: NOT PUBLISHED.
================== Accidental Release Measures ==================
Spill Release Procedures:GENERAL INFORMATION: USE PERSONAL PROTECTIVE
EQUIPMENT AS INDICATED IN CONTROL MEASURES SECTION. VACUUM OR SWEEP
UP MATERIAL AND PLACE INTO A SUITABLE DISPOSAL CONTAINER. CLEAN UP
SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS SPECIFIED IN THE CONTROL
MEASURES. AVOID GENERATING DUSTY CONDITIONS. PROVIDE VENTILATION.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING: DO NOT BREATHE DUST, VAPOR,
MIST OR GAS. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. KEEP
CONTAINER TIGHTLY CLOSED. DO NOT INGEST OR INHALE. USE WITH
ADEQUATE VENTILATION. USE ONLY IN A CHE MICAL FUME HOOD. DISCARD
CONTAMINATED SHOES. STORAGE: STORE IN A COOL, DRY (OTHER
PRECAUTIONS)
Other Precautions:HANDLING/STORAGE (CONT'D): PLACE. STORE IN A TIGHTLY
CLOSED CONTAINER. CORROSIVES AREA. FACILITIES STORING OR UTILIZING
THIS MATERIAL SHOULD BE EQUIPPED WITH AN EYEWASH FACILITY AND A
SAFETY SHOWER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A RESPIRATORY PROTECTION PROGRAM MEETING OSHA'S
29CFR 1910.134 & ANSI 288.2 REQUIREMENTS OR EUROPEAN STANDARED EN
149 MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. FOLLOW OSHA RESPIRATOR REGULATIONS FOUND IN
29CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE
NIOSH/EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW.
Protective Gloves:IMPERVIOUS GLOVES . WEAR APPROPRIATE GLOVES TO
PREVENT SKIN EXPOSURE.
Eye Protection:WEAR APPROPRIATE PROTECTIVE EYEGLASSES OR CHEMICAL
SAFETY (SUPPLEMENTAL SAFETY)
Other Protective Equipment:FACILITIES STORING OR UTILIZING THIS
MATERIAL SHOULD BE EQUIPPED WITH AN EYEWASH FACILITY AND A SAFETY
SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:WEAR APPROPRIATE PROTECTIVE CLOTHING TO
MINIMIZE CONTACT WITH SKIN.
Supplemental Safety and Health
EYE PROTECT (CONT'D): GOGGLES AS DESCRIBED BY OSHA'S EYE & FACE
PROTECTION REGULATIONS IN 29 CFR 1910.133 OR EUROPEAN STANDARD
EN166. PHYS/CHEM DATA (CON'T): SOLUBILITY: INSOLUBLE IN OTHER
ORGANIC SO LVENTS. MOLECULAR FORMULA: C12OZR.8H2O. MOLECULAR
WEIGHT: 322.25. SYNONYM: ZIRCONIUM (IV) OXIDE CHLORIDE
OCTAHYDRATE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NOT AVAILABLE
Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE
Decomp Temp:>150.C, 302.F
Vapor Pres:NOT AVAILABLE
Vapor Density:NOT AVAIL.
Spec Gravity:1.9100G/CM3
pH:NOT AVAILABLE
Viscosity:NOT AVAILABLE
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:(SEE SUPPLEMENTAL SAFETY)
Appearance and Odor:OFF WHITE SOLID. ODOR: NONE REPORTED.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG BASES.
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES. AVOID INCOMPATIBLE MATERIALS, EXCESS HEAT, TEMPERATURES
ABOVE 150 @ C.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, CHLORINE,
IRRITATING AND TOXIC FUMES AND GASES, CHLORIDE FUMES.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
=================== Toxicological Information ===================
Toxicological Information:LD50/LC50: NOT AVAILABLE. MUTAGENICITY,
EPIDEMIOLOGY, TERATOGENICITY, REPRODUCTIVE EFFECTS, NEUROTOXICITY,
OTHER STUDIES: NO INFORMATION AVAILABLE. FIRST AID (CONT'D):
FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. DO NOT USE
MOUTH-TO-MOUTH RESPIRATION. NOTES TO PHYSICIAN: TREAT
SYMPTOMATICALLY AND SUPPORTIVELY.
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NOT AVAILABLE. ENVIRONMENTAL FATE: NOT
AVAILABLE. PHYSICAL/CHEMICAL: NOT AVAILABLE. OTHER: NOT AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LIS TED. RCRA F-SERIES, RCRA P-SERIES, RCRA U-SERIES:
NONE LISTED. NOT LISTED AS A MATERIAL BANNED FROM LAND DISPOSAL
ACCORDING TO RCRA.
=================== MSDS Transport Information ===================
Transport Information:US DOT SHIPPING NAME: CORROSIVE SOLID, N.O.S.*
HAZARD CLASS: 8; UN NUMBER: 1759; PACKING GROUP: III. IMO SHIPPING
NAME: CORROSIVE SOLID, N.O.S.; HAZARD CLASS: 8; UN NUMBER: 1759;
PACKING GROUP: III. I ATA SHIPPING NAME: CORROSIVE SOLID, N.O.S.*;
HAZARD CLASS: 8; UN NUMBER: 1759; PACKING GROUP: III. RID/ADR
SHIPPING NAME: CORROSIVE SOLID, N.O.S.; DANGEROUS GOODS CODE: 8
(65C); UN NUMBER: 1759. CANAD IAN TDG SHIPPING NAME: CORROSIVE
SOLID NOS (ZIRCONYL (IV); HAZARD CLASS 8 (9.2); UN NUMBER UN1759;
OTHER INFORMATION: CHLORIDE.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN
THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS
IN THIS PRODUCT HAVE A TPQ. SECTION 313: NO CHEMICALS ARE
REPORTABLE UNDER SECTION 313.
Federal Regulatory Information:OSHA: NONE OF THE CHEMICALS IN THIS
PRODUCT ARE CONSIDERED HIGHLY HAZARDOUS BY OSHA. TSCA: CAS#
13520-92-8 IS NOT LISTED ON THE TSCA INVENTORY. IT IS FOR RESEARCH
& DEVELOPMENT USE ONLY. HEALTH & SAFE TY REPORTING LIST: NONE OF
THE CHEMICALS ARE ON THE HEALTH & SAFETY REPORTING LIST. CHEMICAL
TEST RULES: NONE OF THE CHEMICALS IN THIS PRODUCT ARE UNDER A
CHEMICAL TEST RULE. SECTION 12B: NONE OF THE CHEMICALS ARE LISTED
UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE
CHEMICALS IN THIS MATERIAL HAVE A SNUR UNDER TSCA. CLEAN AIR ACT:
THIS MATERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS, CLASS
1 OZONE (STATE )
State Regulatory Information:ZIRCONYL (IV) CHLORIDE OCTAHYDRATE IS NOT
PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL OR NJ. CALIFORNIA NO
SIGNIFICANT RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT ARE
LISTED. FEDERAL REGS (C ON'T): DEPLETORS OR CLASS 2 OZONE
DEPLETORS. CLEAN WATER ACT: NONE OF THE CHEMICALS IN THIS PRODUCT
ARE LISTED AS HAZARDOUS SUBSTANCES, PRIORITY POLLUTANTS, OR TOXIC
POLLUTANTS UNDER CWA. EUROPEAN/INT ERNATIONAL REGULATIONS: EUROPEAN
LABELING IN ACCORDANCE WITH EC DIRECTIVES: HAZARD SYMBOLS: C. RISK
PHRASES: R 34-CAUSES BURNS. SAFETY PHRASES: R 25- AVOID CONTACT
WITH EYES. S 36/37/39 WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES
(OTHER INFO)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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