===================== Product Identification =====================
MSDS NAME:ECCOFOAM FPH
NIIN:01-010-9357
MSDS Number: BGDCY
=== Responsible Party ===
Company:GRACE W R AND CO EMERSON & CUMING DEWEY & ALMY DIV
Address:869 WASHINGTON ST
City:CANTON
State:MA
ZIP:02021-2513
Country:US
Info Phone Num:800-225-9936
Emergency Phone Num:800-225-9936
Preparer's Name:DAVID HAAS
CAGE:0NAV2
=== Contractor Identification ===
Company:GRACE W R & CO EMERSON & CUMING DEWEY & ALMY CHEM
Address:869 WASHINGTON ST
City:CANTON
State:MA
ZIP:02021-2513
Country:US
Phone:617-935-4850
CAGE:04552
Company:GRACE W R AND CO
Address:919 18TH ST NW
City:WASHINGTON
State:DC
ZIP:20006
Country:US
Phone:410-659-9000
CAGE:0NAV2
============= Composition/Information on Ingredients =============
Name:TOLUENE-2,4-DIISOCYANATE (TDI) (SARA III)
CAS:584-84-9
RTECS #:CZ6300000
Fraction by Wt: 50-60%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C,0.02 PPM/0.02 STEL
ACGIH TLV:0.005PPM/0.02STEL;93
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:TOLUENE DIISOCYANATE-BASED PREPOLYMER
Fraction by Wt: 40-50%
Other REC Limits:NONE RECOMMENDED
Name:PIGMENT
Fraction by Wt: <0.1%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE-MAY CAUSE SEVERE BUT REVERSIBLE
EYE IRRITATION. SKIN-MAY CAUSE SKIN IRRITATIO. PROLONGED CONTACT
MAY RESULT IN DERMATITIS. INHALATION-MAY CAUSE RESPIRATORY
SENSITIZATION RESPONSES IN SUSCEPTIBLE I NDIVIDUALS.
INGESTION-HARMFUL IF SWALLOWED.
Explanation of Carcinogenicity:TDI IS INCLUDED IN THE NTP LIST OF
SUBSTANCES "REASONABLY ANTICIPATED" TO BE CARCINOGENIC TO HUMANS.
Effects of Overexposure:SKIN-SYMPTOMS MAY INCLUDE RASH, ITCHING, HIVES,
REDDENING, OR SWELLING OF THE EXTREMITIES. INHALATION-SYMPTOMS MAY
INCLUDE TIGHTNESS OF THE CHEST, ASTHMA-LIKE SYMPTOMS, RESPIRATORY
DISTRESS; SYMPTOMS MAY BE DELAYED.
Medical Cond Aggravated by Exposure:PERSONS WITH ASTHMA-TYPE
CONDITIONS, CHRONIC BRONCHITIS, OTHER CHRONIC RESPIRATORY DISEASES
OR RECURRENT SKIN EDEMA OR SENSITIZATION SHOULD BE EXCLUDED FROM
WORKING WITH ISOCYANATEWS.
======================= First Aid Measures =======================
First Aid:EYE-IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MIN. SEE
PHYSICIAN. SKIN-REMOVE ANY CONTAMINATED CLOTHES & FLUSH AREA OF THE
SKIN WITH PLENTY OF WATER. WASH WITH SOAP & WATER. SEE PHYSICIAN.
INHALATION-R EMOVE VICTIM TO FRESH AIR. PROVIDE OXYGEN IF HARD TO
BREATH. GIVE CPR IF NOT BREATHING. SEE PHYSICIAN. INGESTION-DO NOT
INDUCE VOMITING. IF CONSCIOUS, DILUTE BY GIVING WATER TO DRINK. SEE
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:270F,132C
Extinguishing Media:USE CAARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
AVOID USING DIRECT STREAMS OF WATER; FROTHING MAY OCCUR.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.
COOL EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY
BE TOXIC. CLOSED CONTAINERS MAY VIOLENTLY RUOTURE UNDER FIRE
CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:ACTIVATE ALL EXHAUST VENTILATION IN THE
IMMEDIATE AREA. WIPE UP, OR ABSORB SPILLED MATERIAL WITH
VERMICULITE OR OTHER SIMILIAR MATERIAL. WASH AREA WITH SOAPY WATER
& ALLOW TO PLOYMERIZE. COLLECT ABSOR BED WASTE & RINSES IN
APPROPIATE WASTE CONTAINERS.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A TIGHTLY SEALED COTAINER AT
ROOM TEMPERATURE. PROVIDE PROPER VENTILATION. KEEP BLANKETED IN
NITROGEN TO RETARD POLYMERIZATION.
Other Precautions:STORAGE: KEEP AWAY FROM OPEN FLAMES AND HEAT SOURCES.
CONSULT THE PRODUCT TECHNICAL BULLETIN FOR DETAILING STORAGE
INFORMATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE AN APPROPIATE, PROPERLY FITTED RESPIRATOR IF
EXPOSURE EXCEED PEL/TLV VALUES. THE TYPE OF RESPIRATORY PROTECTION
SELECTED WILL DEPEND ON THE CONDITIONS OF USE. OBSERVE OSHA
REGULATIONS.
Ventilation:PROVIDE EFFECTIVE MECHANICAL EXHAUST VENTILATION TO DRAW
VAPORS, MISTS OR FUMES AWAY FROM THE WORKER/PREVENT INHALATION.
Protective Gloves:WEAR APPROPIATE PROTECTIVE GLOVES
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:IF NECESSARY, A PROPER CHEMICAL-RESISTANT
APRON & ADDITIONAL IMPERVIOUS CLOTHING TO PREVENT SKIN CONTACT. EYE
WASH AREA.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
ALL COMPONENTS IN THIS PRODUCT ARE LISTED IN THE EPA TOXIC SUBSTANCE
CONTROL ACT (TSCA) INVENTORY. TOLUENE DIISOCYANATE IS LISTED IN
SARA SECTION 313 AMENDMENTS TO RCRA. VOC BY EPA METHOD #24= 763.1 G
M/L.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:ND
Decomp Temp:Decomp Text:NA
Vapor Pres:NEGLIGIBLE
Vapor Density:NA
Spec Gravity:1.12
pH:NA
Solubility in Water:REACTS WITH WATER.
Appearance and Odor:RED LIQUID, SHARP ODOR.
Percent Volatiles by Volume:ND
Corrosion Rate:ND
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDERS, ACIDS, BASES; UNCONTROLLED MIXING WITH AMINES, WATER,
POLYOLS OR ALCOHOLS.
Stability Condition to Avoid:OPEN FLAME OR HEAT SOURCES, UNCONTROLLED
MIXING WITH CURING AGENTS OR EXPOSURE TO INCOMPATIBLE SUBSTANCES.
Hazardous Decomposition Products:OXIDES OF CARBON, ISOCYANATES, ORGANIC
ACIDS, CYANIDES, AND ALDEHYDES, TRACES OF CYANIDE AND OTHER ORGANIC
SUBSTANCES.
Conditions to Avoid Polymerization:CONTAMINATION FROM INCOMPATIBLES,
UNCONTROLLED MIXING, AVOID STORAGE IN OPEN CONTAINERS, MAY LEAD TO
MIXTURE ABSORPTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP CONTAINERS LOOSELY SEALED IN VENTILATED
AREA FOR 24-48 HOURS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|