Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
XANADU EW225 4X5L JUG GB 1/8
Version 1 / GB Revision Date: 04.03.2004
102000001722 Print Date: 24.04.2006
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
Product information
Trade name XANADU EW225 4X5L JUG GB
Product code (UVP) 05923565
Product code (EXP) 31941A
Specification 12716
Usage herbicide
Company Bayer Environmental Science
230 Cambridge Science Park
Milton Road
Cambridge
Cambridgeshire CB4 0WB
Great Britain
Telephone +44(0)1223 226500
Telefax +44(0)1223 426240
Emergency telephone number 0800-220876 (UK 24 hr)
+44(0)1603-242424 (Overseas 24 hr)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Emulsion, oil in water (EW)
Glyphosate/Diuron 100:125 g/l
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Glyphosate isopropylamine 38641-94-0 12.80
salt 254-056-8
Diuron 330-54-1 Xn, N R22, R40, 11.80
206-354-4 R48/22,
R50/53
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Limited evidence of a carcinogenic effect.
Harmful: danger of serious damage to health by prolonged exposure if swallowed.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
Inhalation
Move the patient to fresh air and keep at rest. If symptoms persist, call a physician.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
XANADU EW225 4X5L JUG GB 2/8
Version 1 / GB Revision Date: 04.03.2004
102000001722 Print Date: 24.04.2006
Skin contact
Take off contaminated clothing and shoes immediately. When in contact with the skin, clean
with soap and water. If symptoms persist, call a physician.
Eye contact
In case of contact with eyes rinse thoroughly with plenty of water. If symptoms persist, seek
medical advice
Ingestion
Do not induce vomiting. Rinse mouth thoroughly with water. Take medical treatment.
Notes to physician
Symptoms
Systemic:, The absorption of this product into the body may lead to the formation of
methaemoglobine that, in sufficient concentration, causes cyanosis., If large amounts are
ingested, the following symptoms may occur:, dizziness, headache
Risks
Danger of formation of methaemoglobin.
Treatment
Local treatment:
Treat symptomatically.
Treatment
Systemic treatment:
In the event of a mouthful or more being ingested, the following measures should be
considered:
Monitoring of: cardiac, kidney and red blood cell count.
Observe specific parameters: methaemoglobinemia and serum potassium.
If ingested, irrigate the stomach using activated charcoal in addition.
If methaemoglobin level is less than 20%, administer 100% oxygen. If methaemoglobin level is
greater than 20% treat with 100% oxygen and slowly give 1% Methylene Blue/Toluidine Blue
solution intravenously, 1-2 mg/kg body weight.
Contraindications: alcohol
Recovery: Spontaneous.
Oxygen, if needed.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
water spray
alcohol-resistant foam
dry powder
carbon dioxide (CO2)
Extinguishing media which must not be used for safety reasons
high volume water jet
Specific hazards during fire fighting
In case of fire the evolution of dangerous gases is possible.
Special protective equipment for fire-fighters
In the event of fire and/or explosion do not breathe fumes.
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
Remove product from areas of fire, or otherwise cool containers with water in order to avoid
pressure being built up due to heat.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
XANADU EW225 4X5L JUG GB 3/8
Version 1 / GB Revision Date: 04.03.2004
102000001722 Print Date: 24.04.2006
Whenever possible, contain fire-fighting water by bunding area with sand or earth.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Avoid contact with spilled product or contaminated surfaces.
When dealing with a spillage do not eat, drink or smoke.
Environmental precautions
Keep people and animals away.
Do not discharge into the drains/surface water/groundwater.
If spillage enters drains leading to sewage works inform local water company immediately.
If spillage enters rivers or watercourses, inform the Environment Agency (emergency telephone
number 0800 807060).
Methods for cleaning up
Take up with absorbent material (e.g. sand, earth or a proprietary absorbent material).
Transfer collected material to heavy duty plastic drums and keep safe for disposal.
Clean contaminated floors and objects thoroughly, observing environmental regulations
Additional advice
Information regarding safe handling, see section 7.
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
Check also for any local site procedures.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
No specific precautions required when handling unopened packs/containers; follow relevant
manual handling advice.
Use only in area provided with appropriate exhaust ventilation.
Advice on protection against fire and explosion
The product can burn, but it is almost non-combustible.
Keep away from sources of ignition - No smoking.
Vapours may form explosive mixture with air.
Storage
Requirements for storage areas and containers
Keep containers tightly closed in a cool, well-ventilated place.
Store in a place accessible by authorized persons only.
Further information on storage conditions
Keep away from direct sunlight.
Protect against frost.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Storage stability
Storage temperature 0 - 30 掳C
Suitable materials
Keep in original packaging, tightly closed.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
XANADU EW225 4X5L JUG GB 4/8
Version 1 / GB Revision Date: 04.03.2004
102000001722 Print Date: 24.04.2006
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Refer to COSHH assessment (Control of substances Hazardous to Health Regulations 1999 as
amended). Engineering controls should be used in preference to personal protective equipment
wherever practicable.
Personal protective equipment
Respiratory protection Short term: filter apparatus, Filter A
Hand protection Chemical resistant gloves
PVC gloves
nitrile gloves
Eye protection Eye protection not required when used as recommended.
Skin and body protection Light protective clothing, PVC
PVC boots
Hygiene measures
When using, do not eat, drink or smoke.
Remove soiled clothing immediately.
Remove soaked clothing immediately.
Clean hands and face at work intervals and after work.
Work in an adequately ventilated room.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form Liquid
Colour white opaque
Odour characteristic
Safety data
pH 3.6 at 20 g/l
Flash point > 100 掳C
Density ca. 1.05 g/cm鲁 at 20 掳C
Water solubility Miscible
log Pow: 2.85
Partition coefficient (n-
octanol/water) The value mentioned relates to the active ingredient diuron.
log Pow: -5.4
Partition coefficient (n-
octanol/water) The value mentioned relates to the active ingredient glyphosate-
isopropylamine salt.
Other information The product can burn, but it is almost non-combustible.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
XANADU EW225 4X5L JUG GB 5/8
Version 1 / GB Revision Date: 04.03.2004
102000001722 Print Date: 24.04.2006
10. STABILITY AND REACTIVITY
Conditions to avoid Extremes of temperature and direct sunlight.
Materials to avoid None
Hazardous reactions No hazardous reactions when stored and handled according to
prescribed instructions.
Stable under recommended storage conditions.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity LD50 (rat) > 5,000 mg/kg
Acute dermal toxicity LD50 (rat) > 2,000 mg/kg
Skin irritation slight irritant effect - does not require labelling (rabbit)
Eye irritation No eye irritation (rabbit)
Sensitization non-sensitizing (guinea pig)
OECD Test Guideline 406, Buehler test
Assessment carcinogenicity
A possible carcinogenic effect at high doses in animal studies on the active substance diuron is
indicated.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 14.7 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient diuron.
Toxicity to fish LC50 (Rainbow trout (Oncorhynchus mykiss)) > 1,000 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient glyphosate-
isopropylamine salt.
Toxicity to fish LC50 (Lepomis macrochirus (Bluegill sunfisch)) > 1,000 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient glyphosate-
isopropylamine salt.
Toxicity to fish LC50 (Cyprinus carpio (Carp)) > 1,000 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient glyphosate-
isopropylamine salt.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
XANADU EW225 4X5L JUG GB 6/8
Version 1 / GB Revision Date: 04.03.2004
102000001722 Print Date: 24.04.2006
Toxicity to daphnia EC50 (Daphnia) 1.4 mg/l
Exposure time: 48 h
The value mentioned relates to the active ingredient diuron.
Toxicity to daphnia EC50 (Daphnia) 930 mg/l
Exposure time: 48 h
The value mentioned relates to the active ingredient glyphosate-
isopropylamine salt.
Toxicity to algae EC50 (Scenedesmus subspicatus) 0.022 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient diuron.
13. DISPOSAL CONSIDERATIONS
Product
In accordance with current regulations may be taken to waste disposal site or incineration plant,
after consultation with site operator and/or with the responsible authority
Can be landfilled or incinerated, when in compliance with local regulations.
Advice may be obtained from the local waste regulation authority (part of the Environment
Agency in the UK).
Contaminated packaging
Packaging that cannot be cleaned should be disposed of as product waste.
Empty containers can be landfilled after cleaning, when in compliance with the Environmental
Protection (Duty of Care) Regulations 1991.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
3082
UN-No
Labels 9
Packaging group III
Hazard no. 90
Description of the goods UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(DIURON SOLUTION)
IMDG
3082
UN-No
Class 9
Packaging group III
Marine pollutant Marine pollutant
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(DIURON SOLUTION )
IATA
3082
UN-No
Class 9
Packaging group III
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
XANADU EW225 4X5L JUG GB 7/8
Version 1 / GB Revision Date: 04.03.2004
102000001722 Print Date: 24.04.2006
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(DIURON SOLUTION )
CDG CPL
3082
UN-No
Class 9
Packaging group III
Hazard identification number 90
Emergency action code 2X
Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (DIURON)
15. REGULATORY INFORMATION
This product has been classified in accordance with The Chemicals (Hazard Information and
Packaging for Supply) Regulations 2002: CHIP 3.
Hazardous components which must be listed on the label:
鈥? Glyphosate
鈥? Diuron
Symbol(s)
Xn Harmful
N Dangerous for the environment
R-phrase(s)
R40 Limited evidence of a carcinogenic effect.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if
swallowed.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S35 This material and its container must be disposed of in a safe way.
S36/37 Wear suitable protective clothing and gloves.
S57 Use appropriate containment to avoid environmental contamination.
Exceptional labelling of special preparations
Restricted to professional users.
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: III (Slightly hazardous)
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R22 Harmful if swallowed.
R40 Limited evidence of a carcinogenic effect.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if
swallowed.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
XANADU EW225 4X5L JUG GB 8/8
Version 1 / GB Revision Date: 04.03.2004
102000001722 Print Date: 24.04.2006
The above information is intended to give general health and safety guidance on the storage and
transport of the product.
It is not intended to apply to the use of the product for which purposes the product label and any
appropriate technical usage literature available should be consulted and any relevant licenses,
consents or approvals complied with.
The requirements or recommendations of any relevant site or working procedure, system or policy in
force or arising from any risk assessment involving the substance or product should take precedence
over any of the guidance contained in this safety data sheet where there is a difference in the
information given.
The information provided in this safety data sheet is accurate at the date of publication and will be
updated as and when appropriate.
No liability will be accepted for any injury, loss or damage resulting from any failure to take account
of information or advice contained in this safety data sheet.
Changes since the last version will be highlighted in the margin. This version replaces all previous
versions.
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