Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015315
MSDS Version 1.0
BAYER ADVANCED 3-IN-1 INSECT, DISEASE, & MITE
Revision Date: 06/21/2006
CONTROL READY-TO-SPRAY
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
BAYER ADVANCED 3-IN-1 INSECT, DISEASE, & MITE CONTROL READY-
Product Name
TO-SPRAY
102000015315
MSDS Number
72155-73
EPA Registration No.
Bayer Environmental Science
2 T.W. Alexander Drive
Research Triangle PK, NC 27709
USA
For MEDICAL, TRANSPORTATION or other EMERGENCY call: 1-800-334-7577 (24 hours/day)
For Product Information call: 1-800-331-2867
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Component Name CAS-No. Average % by Weight
Imidacloprid 138261-41-3 0.4708
tau-Fluvalinate 102851-06-9 0.6099
Tebuconazole 107534-96-3 0.6502
SECTION 3. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information.
Caution! Harmful if inhaled or absorbed through skin. Avoid breathing spray mist.
Emergency Overview
Avoid contact with skin, eyes and clothing. Highly toxic to fish. Highly toxic to
aquatic invertebrates. Toxic to bees.
liquid
Physical State
off-white
Appearance
Inhalation, Skin Absorption, Eye contact, Ingestion
Routes of Exposure
Immediate Effects
May cause mild irritation to eyes. Avoid contact with eyes.
Eye
Harmful if absorbed through skin. May cause slight irritation. Avoid contact with
Skin
skin and clothing.
Do not take internally.
Ingestion
Harmful if inhaled. Avoid breathing spray mist.
Inhalation
Page 1 of 7 Bayer Environmental Science
A Business Group of Bayer
CropScience
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015315
MSDS Version 1.0
BAYER ADVANCED 3-IN-1 INSECT, DISEASE, & MITE
CONTROL READY-TO-SPRAY
This product or its components may have target organ effects.
Chronic or Delayed
Long-Term
SECTION 4. FIRST AID MEASURES
When possible, have the product container or label with you when calling a
General
poison control center or doctor or going for treatment.
Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Eye
Remove contact lenses, if present, after the first 5 minutes, then continue rinsing
eye. Call a physician or poison control center immediately.
Wash off immediately with plenty of water for at least 15 minutes. Take off
Skin
contaminated clothing and shoes immediately. Call a physician or poison control
center immediately.
Call a physician or poison control center immediately. Rinse out mouth and give
Ingestion
water in small sips to drink. DO NOT induce vomiting unless directed to do so by
a physician or poison control center. Never give anything by mouth to an
unconscious person. Do not leave victim unattended.
Move to fresh air. If person is not breathing, call 911 or an ambulance, then give
Inhalation
artificial respiration, preferably mouth-to-mouth if possible. Call a physician or
poison control center immediately.
Notes to Physician
There is no specific antidote. Appropriate supportive and symptomatic treatment
Treatment
as indicated by the patient's condition is recommended.
SECTION 5. FIRE FIGHTING MEASURES
> 93.4 掳C / 200.1 掳F
Flash Point
water spray, foam, carbon dioxide (CO2), dry chemical
Suitable Extinguishing
Media
Keep out of smoke. Fight fire from upwind position. Cool closed containers
Fire Fighting
exposed to fire with water spray. Dike area to prevent runoff and contamination
Instructions
of water sources. Equipment or materials involved in pesticide fires may become
contaminated.
Wear self contained breathing apparatus for fire fighting if necessary. Wear full
protective suit.
Page 2 of 7
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015315
MSDS Version 1.0
BAYER ADVANCED 3-IN-1 INSECT, DISEASE, & MITE
CONTROL READY-TO-SPRAY
SECTION 6. ACCIDENTAL RELEASE MEASURES
Isolate hazard area. Keep unauthorized people away. Avoid contact with spilled
Personal Precautions
product or contaminated surfaces.
Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary
Methods for Cleaning Up
absorbent material). Keep in suitable, closed containers for disposal. Clean
contaminated floors and objects thoroughly, observing environmental
regulations.
Use personal protective equipment. Do not allow product to enter streams,
Additional Advice
sewers or other waterways.
SECTION 7. HANDLING AND STORAGE
Keep away from food, drink and animal feeding stuffs.
Handling Procedures
Store in original container and out of the reach of children, preferably in a locked
Storing Procedures
storage area.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
There are no known hazards associated with this product when used according
General Protection
to the label directions. The following guidelines should be followed.
Avoid inhalation of vapour or mist. Avoid contact with skin and eyes.
Wash hands thoroughly with soap and water after handling and before eating,
drinking, chewing gum, using tobacco, using the toilet or applying cosmetics.
Do not allow children or pets to enter the treated area until it has dried.
Exposure Limits
Glycerine 56-81-5 ACGIH TWA 10 mg/m3
Form of Exposure Mist.
OSHA Z1 PEL 5 mg/m3
Form of Exposure Respirable fraction.
OSHA Z1 PEL 15 mg/m3
Form of Exposure Total dust.
OSHA Z1A TWA 5 mg/m3
Form of Exposure Respirable fraction.
OSHA Z1A TWA 10 mg/m3
Form of Exposure Total dust.
US CA OEL TWA PEL 5 mg/m3
Form of Exposure Respirable fraction.
US CA OEL TWA PEL 10 mg/m3
Page 3 of 7
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015315
MSDS Version 1.0
BAYER ADVANCED 3-IN-1 INSECT, DISEASE, & MITE
CONTROL READY-TO-SPRAY
Form of Exposure Total dust.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
off-white
Appearance
liquid
Physical State
>= 5.0 (100 %)
pH
ca. 1.0276 g/cm鲁 at 20 掳C
Density
100 - 500 mPa.s
Viscosity
SECTION 10. STABILITY AND REACTIVITY
Stable under normal conditions.
Chemical Stability
SECTION 11. TOXICOLOGICAL INFORMATION
Only acute toxicity studies have been performed on this product as formulated. The non-acute information
pertains to the technical-grade active ingredients, imidacloprid, tau-fluvalinate and tebuconazole.
female rat: LD50: > 2,000 mg/kg
Acute Oral Toxicity
male/female rat: LD50: > 4,000 mg/kg
Acute Dermal Toxicity
male/female rat: LC50: > 5.1 mg/l
Acute Inhalation Toxicity
Exposure time: 4 h
Determined in the form of liquid aerosol.
(actual)
male/female rat: LC50: > 20.4 mg/l
Exposure time: 1 h
Determined in the form of liquid aerosol.
Extrapolated from the 4 hr LC50.
(actual)
rabbit: Slight irritation.
Skin Irritation
rabbit: Minimally irritating.
Eye Irritation
guinea pig: Non-sensitizing.
Sensitization
IMIDACLOPRID caused liver and/or thyroid effects in chronic studies in rats and
Chronic Toxicity
dogs.
Page 4 of 7
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015315
MSDS Version 1.0
BAYER ADVANCED 3-IN-1 INSECT, DISEASE, & MITE
CONTROL READY-TO-SPRAY
TAU-FLUVALINATE caused clinical signs of pyrethroid toxicity, decreased body
weights and/or liver effects in chronic toxicity studies in rats and dogs.
TEBUCONAZOLE caused liver, spleen, adrenal and/or eye effects at high doses
in chronic studies in rats and dogs.
Assessment Carcinogenicity
IMIDACLOPRID and TAU-FLUVALINATE were not considered carcinogenic in oncogenicity studies in rats
and mice.
TEBUCONAZOLE is classified by EPA as a Group C carcinogen (possible human carcinogen) based on
liver tumors in mice and no evidence of carcinogenicity in rats. As the liver tumors were seen only at a
dose exceeding a Maximum Tolerated Dose (MTD), no significant carcinogenic risk is posed for human
exposure.
ACGIH
None.
NTP
None.
IARC
None.
OSHA
None.
REPRODUCTION: IMIDACLOPRID, TAU-FLUVALINATE and
Reproductive &
TEBUCONAZOLE are not considered primary reproductive toxicants in rats.
Developmental Toxicity
Reproductive effects (e.g., decreased pup body weights) were observed at the
highest concentration but were considered secondary to maternal toxicity.
DEVELOPMENTAL TOXICITY: IMIDACLOPRID, TAU-FLUVALINATE and
TEBUCONAZOLE are not considered primary developmental toxicants in
laboratory animals. Developmental effects were observed only at doses that
caused maternal toxicity.
IMIDACLOPRID and TEBUCONAZOLE caused only transient neurobehavioral
Neurotoxicity
effects (e.g., decreased motor activity) in acute, subchronic and/or
developmental neurotoxicity studies in rats.
TAU-FLUVALINATE caused typical clinical signs associated with pyrethroid
neurotoxicity (e.g., transient hyperactivity) at high doses in rats.
IMIDACLOPRID, TAU-FLUVALINATE and TEBUCONAZOLE are not considered
Mutagenicity
genotoxic based on the overall weight of evidence in a battery of in vitro and in
vivo tests.
SECTION 12. ECOLOGICAL INFORMATION
Page 5 of 7
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015315
MSDS Version 1.0
BAYER ADVANCED 3-IN-1 INSECT, DISEASE, & MITE
CONTROL READY-TO-SPRAY
Highly toxic to fish. Highly toxic to aquatic invertebrates. Do not apply directly to
Environmental
water. Do not apply when weather conditions favor runoff or drift. Do not
Precautions
contaminate surface or ground water by cleaning equipment or disposal of
wastes, including equipment wash water. Apply this product as specified on the
label.
Toxic to bees. Applications should be timed to coincide with periods of minimum
bee activity, usually between late evening and early morning. Do not apply this
product or allow it to drift to blooming crops or weeds if bees are visiting the
treatment area.
SECTION 13. DISPOSAL CONSIDERATIONS
It is best to use all of the product in accordance with label directions. If it is
General Disposal
necessary to dispose of unused product, please follow container label
Guidance
instructions and applicable local guidelines. Never place unused product down
any indoor or outdoor drain.
Do not re-use empty containers. Place empty container in trash.
Container Disposal
SECTION 14. TRANSPORT INFORMATION
TRANSPORTATION CLASSIFICATION:
Not regulated for shipment by any mode of transportation
FREIGHT CLASSIFICATION:
Insecticides or Fungicicdes, N.O.I., other than poison
SECTION 15. REGULATORY INFORMATION
72155-73
EPA Registration No.
US Federal Regulations
TSCA list
None.
US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)
None.
SARA Title III - Section 302 - Notification and Information
None.
SARA Title III - Section 313 - Toxic Chemical Release Reporting
None.
US States Regulatory Reporting
CA Prop65
This product does not contain any substances known to the State of California to cause cancer.
Page 6 of 7
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015315
MSDS Version 1.0
BAYER ADVANCED 3-IN-1 INSECT, DISEASE, & MITE
CONTROL READY-TO-SPRAY
This product does not contain any substances known to the State of California to cause reproductive
harm.
US State Right-To-Know Ingredients
None.
Canadian Regulations
Canadian Domestic Substance List
None.
Environmental
CERCLA
None.
Clean Water Section 307 Priority Pollutants
None.
Safe Drinking Water Act Maximum Contaminant Levels
None.
SECTION 16. OTHER INFORMATION
NFPA 704 (National Fire Protection Association):
Health - 1 Flammability - 1 Reactivity - 0 Others - none
0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard
Reason to Revise: New Material Safety Data Sheet.
Revision Date: 06/21/2006
This information is provided in good faith but without express or implied warranty. The customer assumes all
responsibility for safety and use not in accordance with label instructions. The product names are registered
trademarks of Bayer.
Page 7 of 7
|