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MSDS Material Safety Data Sheet
CAS

9010-77-9

File Name: msds_dupont_com---PEN_09004a2f800063d1.asp
   The MSDS format adheres to the standards and regulatory requirements
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in other countries.

DuPont Page 1
Material Safety Data Sheet

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"NUCREL" HIGH-PERFORMANCE ADHESIVE AND SEALANT RESINS ALL IN SYNONYM
LIST NUC003
NUC003 Revised 24-MAR-2005
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CHEMICAL PRODUCT/COMPANY IDENTIFICATION
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Material Identification

"NUCREL" is a registered trademark of DuPont.

# Tradenames and Synonyms

"NUCREL" High-Performance Adhesive and Sealant Resins
"NUCREL" 2806,
"NUCREL" 3990, 3990BPI, 3990-E, 3990LG, 3990SB, 3990SB-V,
"NUCREL" 30311, 30705,
"NUCREL" 30707, 30707HS, 30707SR,
"NUCREL" 30907, 31001, 39901, 3990L,
"NUCREL" APD1959, ARX48,
"NUCREL" ARX84-1, ARX84-2, ARX85, ARX94, ARX96,
"NUCREL" ARX1004, ARX1050, #
"NUCREL" ARX3714, ARX3715,
"NUCREL" ARX3717-1, ARX3717-2,
"NUCREL" ARX3723, ARX3725, ARX3727, ARX3728, ARX3728-1
"NUCREL" ARX3731, ARX3740, ARX3748, ARX3920, ARX6390,
"NUCREL" BRE3990-E
"NUCREL" DH01, RX48, RX30907, SEP759, SH30-2,

Company Identification

MANUFACTURER/DISTRIBUTOR
DuPont Packaging & Industrial Polymers
1007 Market Street
Wilmington,DE 19898

PHONE NUMBERS
Product Information : 1-(800)-441-7515
Transport Emergency : 1-(800)-424-9300
Medical Emergency : 1-(800)-441-3637

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COMPOSITION/INFORMATION ON INGREDIENTS
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Components

Material CAS Number %
ETHYLENE-ACRYLIC ACID 9010-77-9 >99
COPOLYMER

Components (Remarks)

Material is not known to contain Toxic Chemicals under Section 313
of Title III of the Superfund Amendments and Reauthorization Act
of 1986 and 40 CFR part 372.
NUC003 DuPont Page 2
Material Safety Data Sheet

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HAZARDS IDENTIFICATION
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Potential Health Effects

ADDITIONAL HEALTH EFFECTS

Before using "NUCREL" High-Performance Adhesive and Sealant
Resins, read the bulletin on the safe handling of these polymers.

INGESTION: Not a probable route of exposure. Toxicity is
predicted to be low for all types but feeding tests have been
conducted only on two sodium ionomers. No pathologic changes in
any organ were seen in 90 day feeding tests with rats and dogs.

SKIN: No data are available. However, based on experience with
handling these polymers, no unusual dermatitis problem is expected
from routine handling. Molten polymer contacting the skin will
cause thermal burns.

EYE: Mechanical irritation only.

INHALATION: Polymer is not respirable as sold. At processing
temperatures above 325 deg C, fumes irritating to the eyes, nose
and throat may be evolved. Exposure may result in redness,
itching and tearing of the eyes and soreness in the nose and
throat together with coughing.

Carcinogenicity Information

None of the components present in this material at concentrations
equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH
as a carcinogen.

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FIRST AID MEASURES
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First Aid

INHALATION

If exposed to fumes from overheating or combustion, move to fresh
air. Consult a physician.

SKIN CONTACT

The compound is not likely to be hazardous by skin contact but
cleansing the skin after use is advisable.
If molten material gets on skin, cool rapidly with cold water. Do
not attempt to remove material from skin. Obtain medical treatment
for thermal burn.

EYE CONTACT

In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Call a physician.
NUC003 DuPont Page 3
Material Safety Data Sheet

(FIRST AID MEASURES - Continued)

INGESTION

No specific intervention is indicated as compound is not likely to
be hazardous by ingestion. Consult a physician if necessary.

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FIRE FIGHTING MEASURES
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Flammable Properties

Flash Point : NE
Method : NA

Fire and Explosion Hazards:

The solid polymer can be combusted only with difficulty.

HAZARDOUS COMBUSTION PRODUCTS Complete combustion gives carbon
dioxide and water. Incomplete combustion gives, in addition,
carbon monoxide and hydrocarbon oxidation products including
organic acids, aldehydes, and alcohols.

Extinguishing Media

Water, Foam, Dry Chemical, CO2.

Fire Fighting Instructions

Wear self-contained breathing apparatus.

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ACCIDENTAL RELEASE MEASURES
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Safeguards (Personnel)

NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.

Spill Clean Up

Sweep up to avoid slipping hazard.

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HANDLING AND STORAGE
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Handling (Personnel)

See FIRST AID and PERSONAL PROTECTIVE EQUIPMENT SECTIONS.

Storage

Store in a cool, dry place. Keep containers tightly closed to
prevent moisture absorption and contamination.
NUC003 DuPont Page 4
Material Safety Data Sheet

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EXPOSURE CONTROLS/PERSONAL PROTECTION
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Engineering Controls

VENTILATION: Local ventilation should be used over processing
equipment.

Personal Protective Equipment

EYE/FACE PROTECTION: Wear safety glasses or coverall chemical
splash goggles.

RESPIRATORS: Where there is potential for airborne exposures in
excess of applicable limits, wear NIOSH approved respiratory
protection.

PROTECTIVE CLOTHING: Where there is potential for skin contact
have available and wear as appropriate impervious gloves, apron,
pants, and jacket.

Exposure Guidelines

Exposure Limits
"NUCREL" HIGH-PERFORMANCE ADHESIVE AND SEALANT RESINS ALL IN
SYNONYM LIST NUC003
PEL (OSHA) : Particulates (Not Otherwise Regulated)
15 mg/m3, 8 Hr. TWA, total dust
5 mg/m3, 8 Hr. TWA, respirable dust

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PHYSICAL AND CHEMICAL PROPERTIES
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Physical Data

Melting Point : 78-105 C (172-221 F)
% Volatiles : Negligible
Solubility in Water : Negligible
Odor : Mild acid
Form : Pellets
Color : White
Specific Gravity : NA

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STABILITY AND REACTIVITY
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Chemical Stability

Stable at normal temperatures and storage conditions.

Conditions to Avoid

Temperatures above 325 C (617 F) .
NUC003 DuPont Page 5
Material Safety Data Sheet

(STABILITY AND REACTIVITY - Continued)

Incompatibility with Other Materials

None reasonably foreseeable.

Decomposition

HAZARDOUS DECOMPOSITION PRODUCTS Carbon monoxide and hydrocarbon
oxidation products including organic acids, aldehydes and alcohols.

Polymerization

Polymerization will not occur.

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ECOLOGICAL INFORMATION
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Ecotoxicological Information

AQUATIC TOXICITY:

No information is available. Toxicity is expected to be low based
on insolubility in water.

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DISPOSAL CONSIDERATIONS
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Waste Disposal

Preferred options for disposal are (1) recycling, (2) incin-
eration with energy recovery, and (3) landfill. The high fuel
value of this product makes option 2 very desirable for material
that cannot be recycled. Treatment, storage, transportation, and
disposal must be in accordance with applicable federal,
state/provincial, and local regulations.

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TRANSPORTATION INFORMATION
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Shipping Information

DOT
Proper Shipping Name : Plastic material, granulated, NOIBN
Hazard Class : Not regulated

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REGULATORY INFORMATION
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U.S. Federal Regulations

TSCA Inventory Status : In compliance with TSCA Inventory
requirements for commercial purposes.
NUC003 DuPont Page 6
Material Safety Data Sheet

(REGULATORY INFORMATION - Continued)

State Regulations (U.S.)

STATE RIGHT-TO-KNOW LAWS

No substances on the state hazardous substances list, for the
states indicated below, are used in the manufacture of products on
this Material Safety Data Sheet.

SUBSTANCES ON THE PENNSYLVANIA HAZARDOUS SUBSTANCES LIST PRESENT
AT A CONCENTRATION OF 1% OR MORE (0.01% FOR SPECIAL HAZARDOUS
SUBSTANCES): None known.

WARNING: SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: None known.

SUBSTANCES ON THE NEW JERSEY WORKPLACE HAZARDOUS SUBSTANCE LIST
PRESENT AT A CONCENTRATION OF 1 % OR MORE (0.1% FOR SUBSTANCES
IDENTIFIED AS CARCINOGENS, MUTAGENS OR TERATOGENS): None known.

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OTHER INFORMATION
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Additional Information

MEDICAL USE: CAUTION: Do not use in medical applications
involving permanent implantation in the human body. For other
medical applications see DuPont CAUTION Bulletin No. H-50102.

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The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.

Responsibility for MSDS : T. P. PRICE
DUPONT PACKAGING & INDUSTRIAL POLYMERS
Address : CHESTNUT RUN PLAZA 713
WILMINGTON, DE 19880-0713
Telephone : 302-999-4664

# Indicates updated section.

This information is based upon technical information believed to be
reliable. It is subject to revision as additional knowledge and
experience is gained.

End of MSDS

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