Material Safety Data Sheet
REZ-SEAL - 55 GAL DRUM
Version 1.5 Print Date 12/16/2007
REVISION DATE: 12/15/2007
SECTION 1 - PRODUCT IDENTIFICATION / PREPARATION INFORMATION
Product Information
Trade name : REZ-SEAL - 55 GAL DRUM
Product code : 259 55
Supplier : Euclid Canada
2835 Grande-All茅e
St-Hubert, QC J4T 2R4
Telephone : 1-800-667-0920
Emergency Phone: : (613) 996-6666
Product use : Sealer
Preparation Information
Prepared by: : Sewnauth Raghunandan
Date: : 12/15/2007
Telephone : (416) 421-3300
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Clear. Liquid. May cause moderate irritation to the respiratory system. May cause nausea, headaches, and
dizziness. May cause drowsiness, weakness, and fatigue. Move to fresh air. If required, artificial respiration or
administration of oxygen can be performed by trained personnel. Leave area to breathe fresh air. Avoid further
overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause moderate irritation to the respiratory system. May cause nausea, headaches,
:
and dizziness. May cause drowsiness, weakness, and fatigue.
Eyes Vapor and/or mist may cause eye irritation. Direct contact may cause temporary redness
:
and discomfort.
Ingestion May cause irritation to the mouth, throat and stomach. May cause gastrointestinal
:
irritation, nausea, and vomiting.
Skin May cause moderate irritation.
:
Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately concentrating and inhaling contents may be
harmful or fatal. Prolonged or repeated exposure to xylene may cause defatting, drying, and irritation of the
skin, dermatitis, central nervous system (CNS) effects, heart muscle sensitization and arrhythmia, hearing loss,
and brain, liver, kidney damage. Xylene overexposure may affect fetal development. Prolonged or repeated
contact/exposure to aromatic petroleum distillates may cause defatting, drying, and irritation of the skin,
dermatitis, and central nervous system (CNS) effects. Di(2-ethylhexyl) phthalate, (dioctyl phthalate) given in the
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Material Safety Data Sheet
REZ-SEAL - 55 GAL DRUM
Version 1.5 Print Date 12/16/2007
REVISION DATE: 12/15/2007
diet, produced increased incidence of liver cancers in female rats and male and female mice. An increased
incidence of liver cancers or neoplasms were observed in male rats. The International Agency for Research on
Cancer (IARC) has evaluated ethylbenzene and classified it as a possible human carcinogen (Group 2B) based
on sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in
exposed humans. Styrene was reported to cause liver and kidney damage in experimental animals at high
levels of exposure. Fillers are encapsulated and not expected to be released from product under normal
conditions of use.
Target Organs: Skin, Eye, Lung, Liver, Kidney, Nerve, Reproductive
SECTION 3 : HAZARDOUS INGREDIENTS
Chemical Name CAS-No. Weight % Range
Aromatic petroleum distillates 64742-95-6 40.0 - 70.0
1,2,4-Trimethylbenzene 95-63-6 15.0 - 40.0
1,3,5-Trimethylbenzene 108-67-8 5.0 - 10.0
Diethylbenzene, Mixed Isomers 25340-17-4 1.0 - 5.0
Cumene 98-82-8 1.0 - 5.0
Dioctyl phthalate 117-81-7 1.0 - 5.0
Xylene 1330-20-7 0.5 - 1.5
Ethylbenzene 100-41-4 0.1 - 1.0
Styrene 100-42-5 0.1 - 1.0
The ingredients listed above are hazardous as defined in the controlled products regulation. (CPR).
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be
performed by trained personnel.Leave area to breathe fresh air. Avoid further
overexposure. If symptoms persist, get medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5: FIRE / EXPLOSION HAZARDS
Flash point : 110 掳 43 掳
F, C
Method : Setaflash Closed Cup
Lower explosion limit : 1.0 %(V) Solvent
Upper explosion limit : 7.0 %(V) Solvent
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
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Material Safety Data Sheet
REZ-SEAL - 55 GAL DRUM
Version 1.5 Print Date 12/16/2007
REVISION DATE: 12/15/2007
Hazardous combustion : Smoke, fumes.Carbon monoxide and carbon dioxide can form.Nitrogen
products oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).Water
may be used to cool containers to minimize pressure build-up.
Fire and explosion conditions : Vapor concentrations in enclosed areas may ignite explosively.Product
may ignite if heated in excess of its flash point.Vapors may travel to
sources of ignition and flashback.Closed container, may burst when
exposed to extreme heat.Empty containers may contain ignitable
vapors.
SECTION 6 - SPILLS / LEAKS / ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. To prevent generation of static discharges, use
bonding/grounding connection when pouring liquid. Extinguish all ignition sources including pilot lights, non-
explosion proof motors and electrical equipment until vapors dissipate. Personal protective equipment must be
worn during maintenance or repair of contaminated mixer, reactor, or other equipment. Keep container closed
when not in use. Vapor may migrate to sources of ignition. Do not smoke, weld, generate sparks, or use flame
near container. Store in sealed containers in a cool, dry, ventilated warehouse location.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or
supplied air respirator when airborne contaminant level(s) are expected to
exceed exposure limits indicated on the MSDS. Follow manufacturer's
directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Protective measures : Use professional judgment in the selection, care, and use.Inspect and replace
equipment at regular intervals.
: Use only in well ventilated areas. Provide maximum ventilation in enclosed
Engineering measures
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
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Material Safety Data Sheet
REZ-SEAL - 55 GAL DRUM
Version 1.5 Print Date 12/16/2007
REVISION DATE: 12/15/2007
Chemical Name CAS Number Regulation Limit Form
1,2,4-Trimethylbenzene 95-63-6 Ontario TWA: 123 mg/m3
ACGIH TWA: 25 ppm
1,3,5-Trimethylbenzene 108-67-8 Ontario TWA: 123 mg/m3
ACGIH TWA: 25 ppm
Cumene 98-82-8 Ontario TWA: 245 mg/m3
ACGIH TWA: 50 ppm
Dioctyl phthalate 117-81-7 Ontario TWA: 3 mg/m3
Ontario STEL: 5 mg/m3
ACGIH TWA: 5 mg/m3
Xylene 1330-20-7 Ontario TWA: 435 mg/m3
Ontario STEL: 650 mg/m3
ACGIH TWA: 100 ppm
ACGIH STEL: 150 ppm
Ethylbenzene 100-41-4 Ontario TWA: 435 mg/m3
Ontario STEL: 540 mg/m3
ACGIH TWA: 100 ppm
ACGIH STEL: 125 ppm
Styrene 100-42-5 Ontario TWA: 50 ppm
Ontario STEL: 100 ppm
ACGIH TWA: 20 ppm
ACGIH STEL: 40 ppm
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State : Liquid
Form : Liquid
Color : Clear
Odor : Aromatic Solvent
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Approximate327.5 掳 164 掳
F, C
Water solubility : Negligible
Evaporation Rate: : Not available.
Specific Gravity : 0.90
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Material Safety Data Sheet
REZ-SEAL - 55 GAL DRUM
Version 1.5 Print Date 12/16/2007
REVISION DATE: 12/15/2007
% Volatile Weight : 74 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Oxidizing agents.Strong acids.Strong bases.
Stability : Stable under normal conditions. Avoid welding arcs, flames or other high
temperature sources.
Hazardous polymerization : Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
Cumene, CAS-No.: 98-82-8
Acute oral toxicity (LD-50 oral) 2,910 mg/kg ( Rat ) 1,400 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 2,000 mg/l for 7 h ( Mouse ) 8,000 mg/l for 4 h ( Rat ) 24.7
mg/l for 2 h ( Mouse )
Dioctyl phthalate, CAS-No.: 117-81-7
Acute oral toxicity (LD-50 oral) 25,000 mg/kg ( Rat ) 30,000 mg/kg ( Mouse ) 33,900 mg/kg
( Rabbit ) 26,300 mg/kg ( Guinea pig )
Acute dermal toxicity (LD-50 dermal) 10,000 mg/kg ( Guinea pig ) 25,000 mg/kg ( Rabbit )
Xylene, CAS-No.: 1330-20-7
Acute oral toxicity (LD-50 oral) 4,300 mg/kg ( Rat ) 1,590 mg/kg ( Mouse ) 6,670 mg/kg (
Rat ) 3,523 - 8,600 mg/kg ( Rat ) 5,627 mg/kg ( Mouse )
Acute inhalation toxicity (LC-50) 6,350 mg/l for 4 h ( Rat ) 3,907 mg/l for 6 h ( Mouse ) 8,000
mg/l for 4 h ( Rat )
Ethylbenzene, CAS-No.: 100-41-4
Acute oral toxicity (LD-50 oral) 5,460 mg/kg ( Rat ) 3,500 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 17,800 mg/kg ( Rabbit )
Styrene, CAS-No.: 100-42-5
Acute oral toxicity (LD-50 oral) 5,000 mg/kg ( Rat ) 1,000 mg/kg ( Rat ) 316 mg/kg ( Mouse
)
Acute inhalation toxicity (LC-50) 4,940 mg/l for 2 h ( Mouse ) 2,770 mg/l for 4 h ( Rat ) 24 mg/l
for 4 h ( Rat )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
Disposal Method : Dispose according to all applicable regulations (hazardous household waste depot, or
as liquid industrial waste for industrial product).
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Material Safety Data Sheet
REZ-SEAL - 55 GAL DRUM
Version 1.5 Print Date 12/16/2007
REVISION DATE: 12/15/2007
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
Canadian Regulations:
WHMIS Classification : B3, D2A, D2B
This is a "controlled product" under the Canadian Workplace Hazardous Materials Information System
(WHMIS).
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.
Other Regulations:
Regulatory VOC (less water and : 666 g/l
exempt solvent)
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 2
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Sewnauth Raghunandan
Legend
ACGIH - American Conference of Governmental Hygienists OSHA - Occupational Safety and Health Administration
DOT - Department of Transportation PEL - Permissible Exposure Limit
DSL - Domestic Substance List RCRA - Resource Conservation and Recovery Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
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Material Safety Data Sheet
REZ-SEAL - 55 GAL DRUM
Version 1.5 Print Date 12/16/2007
REVISION DATE: 12/15/2007
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System
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