Material Safety Data Sheet
EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 03/26/2008
REVISION DATE: 03/25/2008
SECTION 1 - PRODUCT IDENTIFICATION / PREPARATION INFORMATION
Product Information
Trade name : EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Product code : 273C 02
Supplier : Euclid Canada
2835 Grande-All茅e
St-Hubert, QC J4T 2R4
Telephone : 1-800-667-0920
Emergency Phone: : (613) 996-6666
Product use : Sealant
Preparation Information
Prepared by: : Sewnauth Raghunandan
Date: : 03/25/2008
Telephone : (416) 421-3300
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Gray. Non-sag gunnable paste. May cause slight irritation to the respiratory system. May cause nausea,
headaches, and dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory
sensitization. Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical
attention. Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by
trained personnel.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause slight irritation to the respiratory system. May cause nausea, headaches, and
:
dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory
sensitization.
Eyes Direct contact may cause mild irritation.
:
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause sensitization resulting in irritation, itching and redness.
:
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Overexposure may cause dermatitis, asthma, skin and respiratory sensitization and decreased lung function.
Prolonged or repeated contact/exposure to aromatic petroleum distillates may cause defatting, drying, and
irritation of the skin, dermatitis, and central nervous system (CNS) effects. Inhalation of crystalline silica (quartz)
can cause cancer based on animal data, and IARC concludes sufficient evidence in humans (Group 1).
Prolonged and repeated overexposure to free crystalline silica dust above the TLV level may cause scarring of
the lungs with cough and shortness of breath. A delayed lung injury, silicosis may result from breathing free
silica. A long-term NTP study showed that oral exposure to toluene diisocyanate (TDI) caused cancer in rats
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Material Safety Data Sheet
EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 03/26/2008
REVISION DATE: 03/25/2008
and mice. A lifetime inhalation study sponsored by the International Isocyanate Institute did not show
carcinogenic activity in rats. May cause allergic skin and respiratory sensitization. Fillers are encapsulated and
not expected to be released from product under normal conditions of use.
Target Organs: Skin, Eye, Ingestion, Lung
SECTION 3 : HAZARDOUS INGREDIENTS
Chemical Name CAS-No. Weight % Range
Aromatic petroleum distillates 64742-95-6 5.0 - 10.0
Trimethyl benzene (mixed isomers) 25551-13-7 3.0 - 7.0
Titanium dioxide 13463-67-7 3.0 - 7.0
Adhesion Promoter 51721300-5355P 1.0 - 5.0
1,2,4-Trimethylbenzene 95-63-6 0.1 - 1.0
4,4'-Methylene bis(phenylisocyanate) 101-68-8 0.1 - 1.0
Xylene 1330-20-7 0.1 - 1.0
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 0.1 - 1.0
1,3,5-Trimethylbenzene 108-67-8 0.1 - 1.0
2,4-Toluene diisocyanate 584-84-9 0.1 - 1.0
The ingredients listed above are hazardous as defined in the controlled products regulation. (CPR).
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.Move to fresh air. If required, artificial respiration or administration
of oxygen can be performed by trained personnel.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5: FIRE / EXPLOSION HAZARDS
Flash point : Not available.
Method : Not available.
Burning rate : Non-flammable solid
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
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Material Safety Data Sheet
EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 03/26/2008
REVISION DATE: 03/25/2008
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Hydrocyanic acid and
products nitrogen oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
SECTION 6 - SPILLS / LEAKS / ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Scrape up and transfer to appropriate
container for disposal.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion and contact with skin, eyes and clothing. Preferably use entire contents
in one continuous work session. Do not smoke, weld, generate sparks, or use flame near container. Change
soiled work clothes frequently. Clean hands thoroughly after handling Do not store or use near food. Keep
container closed when not in use. Since emptied containers retain product residue and vapor, observe
precautions even after container is emptied. Store under dry warehouse conditions away from heat and all
ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or
supplied air respirator when airborne contaminant level(s) are expected to
exceed exposure limits indicated on the MSDS. Follow manufacturer's
directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Use safety glasses if eye contact is likely.
Skin and body protection : Use disposable or impervious clothing if work clothing contamination is likely.
Remove and wash contaminated clothing before reuse.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use general ventilation and/ or local exhaust to reduce the airborne
contaminant concentration below the exposure limit listed in the MSDS
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Trimethyl benzene (mixed 25551-13-7 Ontario TWA: 123 mg/m3
isomers) ACGIH TWA: 25 ppm
Titanium dioxide 13463-67-7 Ontario TWA: 10 mg/m3 Total dust.
ACGIH TWA: 10 mg/m3
1,2,4-Trimethylbenzene 95-63-6 Ontario TWA: 123 mg/m3
ACGIH TWA: 25 ppm
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Material Safety Data Sheet
EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 03/26/2008
REVISION DATE: 03/25/2008
Chemical Name CAS Number Regulation Limit Form
4,4'-Methylene 101-68-8 Ontario TWA: 0.005 ppm
bis(phenylisocyanate) ACGIH TWA: 0.005 ppm
Xylene 1330-20-7 Ontario TWA: 435 mg/m3
Ontario STEL: 650 mg/m3
ACGIH TWA: 100 ppm
ACGIH STEL: 150 ppm
Crystalline Silica (Quartz)/ 14808-60-7 Ontario TWA: 0.10 mg/m3 Respirable fraction.
Silica Sand ACGIH TWA: 0.025 mg/m3 Respirable fraction.
1,3,5-Trimethylbenzene 108-67-8 Ontario TWA: 123 mg/m3
ACGIH TWA: 25 ppm
2,4-Toluene diisocyanate 584-84-9 ACGIH TWA: 0.005 ppm
ACGIH STEL: 0.02 ppm
Ontario TWA: 0.005 ppm
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State : Liquid (paste)
Form : Non-sag gunnable paste
Color : Gray
Odor : Aromatic Solvent
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Insoluble
Evaporation Rate: : Not available.
Specific Gravity : 1.3
% Volatile Weight : 8%
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Amines.Water or moisture and oxidizing agents.Alcohols.Strong
acids.Strong bases.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur.
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Material Safety Data Sheet
EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 03/26/2008
REVISION DATE: 03/25/2008
SECTION 11 - TOXICOLOGICAL INFORMATION
Trimethyl benzene (mixed isomers), CAS-No.: 25551-13-7
Acute oral toxicity (LD-50 oral) 8,970 mg/kg ( Rat )
4,4'-Methylene bis(phenylisocyanate), CAS-No.: 101-68-8
Acute inhalation toxicity (LC-50) 0.369 mg/l for 4 h ( Rat ) 0.38 mg/l for 4 h ( Rat )
Xylene, CAS-No.: 1330-20-7
Acute oral toxicity (LD-50 oral) 4,300 mg/kg ( Rat ) 1,590 mg/kg ( Mouse ) 6,670 mg/kg (
Rat ) 3,523 - 8,600 mg/kg ( Rat ) 5,627 mg/kg ( Mouse )
Acute inhalation toxicity (LC-50) 6,350 mg/l for 4 h ( Rat ) 3,907 mg/l for 6 h ( Mouse ) 8,000
mg/l for 4 h ( Rat )
2,4-Toluene diisocyanate, CAS-No.: 584-84-9
Acute oral toxicity (LD-50 oral) 5,800 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 14 mg/l for 4 h ( Rat ) 10 mg/l for 4 h ( Mouse ) 13 mg/l for 4
h ( Guinea pig ) 11 mg/l for 4 h ( Rabbit )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
Disposal Method : Dispose as hazardous waste according to all local, state, federal and provincial
regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
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Material Safety Data Sheet
EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 03/26/2008
REVISION DATE: 03/25/2008
Canadian Regulations:
WHMIS Classification : D2A, D2B
This is a "controlled product" under the Canadian Workplace Hazardous Materials Information System
(WHMIS).
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.
Other Regulations:
Regulatory VOC (less water and : 114 g/l
exempt solvent)
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 1
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Sewnauth Raghunandan
Legend
ACGIH - American Conference of Governmental Hygienists OSHA - Occupational Safety and Health Administration
DOT - Department of Transportation PEL - Permissible Exposure Limit
DSL - Domestic Substance List RCRA - Resource Conservation and Recovery Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System
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