Material Safety Data Sheet
EUCON MSA - BULK
Version 1 Print Date 07/03/2007
REVISION DATE: 05/04/2005
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : EUCON MSA - BULK
Product code : 300 99
COMPANY : Euclid Chemical Company
19218 Redwood Road
Cleveland, OH 44110
Telephone : 1-800-321-7628
Emergency Phone: : U.S. only: 1-800-255-3924
International Users Call Collect: 1-813-248-0585
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Gray. Powder. Dust may irritate nose and throat. Dust irritating to the respiratory tract. Leave area to breathe
fresh air. Avoid further overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation Dust may irritate nose and throat. Dust irritating to the respiratory tract.
:
Eyes Direct contact may cause severe irritation. May cause mechanical irritation or abrasion,
:
and possible chemical burns. May cause temporary injury.
Ingestion May cause irritation to the mouth, throat and stomach. May cause gastrointestinal
:
irritation, nausea, and vomiting.
Skin May cause severe irritation. May cause dryness, cracking, irritation, and chemical burns.
:
May produce cement dermatitis due to primary irritation from alkaline, hydroscopic and
abrasive properties.
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC concludes sufficient
evidence in humans (Group 1). Prolonged and repeated overexposure to free crystalline silica dust above the
TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed lung injury, silicosis
may result from breathing free silica.
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Amorphous silica 69012-64-2 > 60.0
Crystalline Silica (Quartz)/ Silica
14808-60-7 - <1.0
Sand
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Material Safety Data Sheet
EUCON MSA - BULK
Version 1 Print Date 07/03/2007
REVISION DATE: 05/04/2005
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : Not available.
Method : Not available.
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : This product is not expected to burn under normal conditions of use.Use
that which is appropriate to the surroundings.
Hazardous combustion : Not available.
products
Protective equipment for : Not applicable. Product is not expected to burn.
firefighters
Fire and explosion conditions : This product not expected to ignite under normal conditions of use.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Dampen material with water to control
dusting. Scoop up and transfer to appropriate container for disposal. Flush spill area with water.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of dust and contact with skin and eyes. Clean hands thoroughly after handling. Precautions
also apply to emptied containers. Personal protective equipment must be worn during maintenance or repair of
contaminated mixer, reactor, or other equipment. Store in sealed containers in a cool, dry, ventilated
warehouse location.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
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Material Safety Data Sheet
EUCON MSA - BULK
Version 1 Print Date 07/03/2007
REVISION DATE: 05/04/2005
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved dust respirator
where airborne concentrations are expected to exceed exposure limits
indicated on the MSDS. Follow manufacturer's directions for respirator use.
Hand protection : Use suitable impervious rubber or vinyl gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing.
Protective measures : Use professional judgment in the selection, care, and use.Wear gloves, head
coverings and full body clothing as necessary to prevent skin irritation.
Washable or disposable clothing may be used. Do not take unwashed
clothing home. Work clothes should be washed separately from other clothing
and the washing machine rinsed thoroughly following use. Inform the
launderer of the proper procedures. Store work clothes and street clothes
separately to prevent contamination.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Amorphous silica 69012-64-2 ACGIH TWA: 2 mg/m3 Respirable fraction.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA TWA: 0.8 mg/m3
Crystalline Silica (Quartz)/ 14808-60-7 ACGIH TWA: 0.05 mg/m3 Respirable fraction.
Silica Sand OSHA TWA: 0.1 mg/m3 Respirable.
OSHA TWA: 0.3 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Powder
Color : Gray
Odor : Odourless
pH : Not available.
Vapour pressure : Not available.
Vapor density : Not available.
Melting point/range : Not available.
Freezing point : Not available.
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Material Safety Data Sheet
EUCON MSA - BULK
Version 1 Print Date 07/03/2007
REVISION DATE: 05/04/2005
Boiling point/range : Not available.
Water solubility : Insoluble
Specific Gravity : 2.2
% Volatile Weight : 0%
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Not Applicable.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
No Data Available
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Recycle or dispose of in compliance with local, provincial and federal regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : None present or none present in regulated quantities.
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components :
Amorphous silica 69012-64-2
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
OSHA Status: Considered : Irritant
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Material Safety Data Sheet
EUCON MSA - BULK
Version 1 Print Date 07/03/2007
REVISION DATE: 05/04/2005
hazardous based on the
following criteria:
OSHA Flammability : Not Regulated
Regulatory VOC (less water and : 0 g/l
exempt solvent)
VOC Method 310 : 0%
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
U.S. State Regulations:
MASS RTK Components : Amorphous silica 69012-64-2
Penn RTK Components : Amorphous silica 69012-64-2
NJ RTK Components : Amorphous silica 69012-64-2
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
14808-60-7 Crystalline Silica (Quartz)/ Silica Sand
Canadian Regulations:
WHMIS Classification : D2A, E
This is a "controlled product" under the Canadian Workplace Hazardous Materials Information System (WHMIS).
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 1 0 = Minimum
1 = Slight
Flammability 0
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
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Material Safety Data Sheet
EUCON MSA - BULK
Version 1 Print Date 07/03/2007
REVISION DATE: 05/04/2005
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
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