Mater ial S afety Data S heet

                                       Alcian B lue 8GX



S ection 1 - Chemical Pr oduct and Company I dentification

MS D S N am e: Alcian B lue 8GX

Cat alog N u m ber s : 10350

S yn on ym s : I ngr ain B lue

Com pan y I den t if icat ion :

             Electr on Micr os copy S ciences

             321 Mor r is Road * P.O. B ox 251

             For t Was hington, PA 19034

F or in f or m at ion in N or t h Am er ica, call: 215- 646- 1566

F or em er gen cies in t h e U S , call CH E MT R E C: 800- 424- 9300



S ection 2 - Compos ition, I nfor mation on I ngr edients







      CAS #                      Ch em i cal N am e                   P er cen t     E I N E CS / E L I N CS

                    Copper (4+ ),n,n',n'',n'''- 29h,31h-

   33864- 99- 2                                                          > 98            251- 705- 7

                    phthalocyaninetetr ayl tetr a







H az ar d S ym bols : None lis ted.

R is k P h r as es : None lis ted.





S ection 3 - Hazar ds I dentification







                                 E ME R GE N CY OVE R VI E W



Appear ance: Not available. Cau t ion ! May caus e eye and s kin ir r itation. T he

tox icological pr oper ties of this mater ial have not been fully inves tigated. May caus e

r es pir ator y and diges tive tr act ir r itation.

T ar get Or gan s : No data found.





P ot en t ial H ealt h E f f ect s

E ye: May caus e eye ir r itation.

S kin : May caus e s kin ir r itation.

I n ges t ion : May caus e ir r itation of the diges tive tr act. T he tox icological pr oper ties of

this s ubs tance have not been fully inves tigated.

I n h alat ion : May caus e r es pir ator y tr act ir r itation. T he tox icological pr oper ties of this

s ubs tance have not been fully inves tigated.

Ch r on ic: No infor mation found.

S ection 4 - Fir s t Aid Meas ur es







E yes : Flus h eyes with plenty of water for at leas t 15 minutes , occas ionally lifting the

upper and lower eyelids . Get medical aid.

S kin : Get medical aid. Flus h s kin with plenty of s oap and water for at leas t 15

minutes while r emoving contaminated clothing and s hoes . Was h clothing befor e

r eus e.

I n ges t ion : Never give anything by mouth to an uncons cious per s on. Get medical

aid. Do NOT induce vomiting. I f cons cious and aler t, r ins e mouth and dr ink 2- 4

cupfuls of milk or water .

I n h alat ion : Remove fr om ex pos ur e to fr es h air immediately. I f not br eathing, give

ar tificial r es pir ation. I f br eathing is difficult, give ox ygen. Get medical aid.

N ot es t o P h ys ician : T r eat s ymptomatically and s uppor tively.





S ection 5 - Fir e Fighting Meas ur es







Gen er al I n f or m at ion : As in any fir e, wear a s elf- contained br eathing appar atus in

pr es s ur e- demand, MS HA/NI OS H (appr oved or equivalent), and full pr otective gear .

Dus ts at s ufficient concentr ations can for m ex plos ive mix tur es with air . Dur ing a fir e,

ir r itating and highly tox ic gas es may be gener ated by ther mal decompos ition or

combus tion. Us e water s pr ay to keep fir e- ex pos ed container s cool.

E x t in gu is h in g Media: Us e agent mos t appr opr iate to ex tinguis h fir e. Us e water

s pr ay, dr y chemical, car bon diox ide, or appr opr iate foam.

F las h P oin t : Not applicable.

Au t oign it ion T em per at u r e: Not applicable.

E x plos ion L im it s , L ow er : Not available.

U pper : Not available.

N F P A R at in g: (es timated) Health: 1; Flammability: 0; I ns tability: 0





S ection 6 - Accidental Releas e Meas ur es







Gen er al I n f or m at ion : Us e pr oper per s onal pr otective equipment as indicated in

S ection 8.

S pills / L eaks : Clean up s pills immediately, obs er ving pr ecautions in the Pr otective

Equipment s ection. S weep up or abs or b mater ial, then place into a s uitable clean,

dr y, clos ed container for dis pos al. Avoid gener ating dus ty conditions . Pr ovide

ventilation.

S ection 7 - Handling and S tor age







H an dlin g: Was h thor oughly after handling. Remove contaminated clothing and was h

befor e r eus e. Us e with adequate ventilation. Minimiz e dus t gener ation and

accumulation. Avoid contact with eyes , s kin, and clothing. K eep container tightly

clos ed. Avoid inges tion and inhalation.

S t or age: S tor e in a tightly clos ed container . K eep fr om contact with ox idiz ing

mater ials . S tor e in a cool, dr y, well- ventilated ar ea away fr om incompatible

s ubs tances .





S ection 8 - Ex pos ur e Contr ols , Per s onal Pr otection







E n gin eer in g Con t r ols : Facilities s tor ing or utiliz ing this mater ial s hould be equipped

with an eyewas h facility and a s afety s hower . Us e adequate ventilation to keep

air bor ne concentr ations low.

E x pos u r e L im it s



   Ch em i cal N am e             ACGI H                   N I OS H           OS H A - F i n al P E L s

Copper (4+ ),n,n'

                ,n'',n'''

                        -

       29h,31h-

                          none lis ted                   none lis ted              none lis ted

 phthalocyaninetetr ayl

         tetr a







OS H A Vacat ed P E L s : Copper (4+ ),n,n',n'',n'''      - 29h,31h- phthalocyaninetetr ayl tetr a:

No OS HA Vacated PELs ar e lis ted for this chemical.

P er s on al P r ot ect ive E qu ipm en t

E yes : Wear appr opr iate pr otective eyeglas s es or chemical s afety goggles as

des cr ibed by OS HA's eye and face pr otection r egulations in 29 CFR 1910.133 or

Eur opean S tandar d EN166.

S kin : Wear appr opr iate pr otective gloves to pr event s kin ex pos ur e.

Clot h in g: Wear appr opr iate pr otective clothing to pr event s kin ex pos ur e.

R es pir at or s : A r es pir ator y pr otection pr ogr am that meets OS HA's 29 CFR

§1910.134 and ANS I Z 88.2 r equir ements or Eur opean S tandar d EN 149 mus t be

followed whenever wor kplace conditions war r ant a r es pir ator 's us e.





S ection 9 - Phys ical and Chemical Pr oper ties







P h ys ical S t at e: S olid

Appear an ce: Not available.

Odor : none r epor ted

pH : Not available.

Vapor P r es s u r e: Negligible.

Vapor D en s it y: Not available.

E vapor at ion R at e: Negligible.

Vis cos it y: Not available.

B oilin g P oin t : Not available.

F r eez in g/ Melt in g P oin t : 148 deg C

D ecom pos it ion T em per at u r e: Not available.

S olu bilit y: moder ately s oluble

S pecif ic Gr avit y/ D en s it y: Not available.

Molecu lar F or m u la: C56H68Cl4CuN16S 4

Molecu lar W eigh t : 1298.88





S ection 10 - S tability and Reactivity







Ch em ical S t abilit y: S table under nor mal temper atur es and pr es s ur es .

Con dit ion s t o Avoid: I ncompatible mater ials , dus t gener ation, ex ces s heat.

I n com pat ibilit ies w it h Ot h er Mat er ials : S tr ong ox idiz ing agents .

H az ar dou s D ecom pos it ion P r odu ct s : Hydr ogen chlor ide, car bon monox ide, ox ides

of nitr ogen, ox ides of s ulfur , ir r itating and tox ic fumes and gas es , car bon diox ide.

H az ar dou s P olym er iz at ion : Has not been r epor ted.





S ection 11 - T ox icological I nfor mation







R T E CS # :

CAS # 33864- 99- 2 unlis ted.

L D 5 0 / L C5 0 :

Not available.



Car cin ogen icit y:

CAS # 33864- 99- 2: Not lis ted by ACGI H, I ARC, NI OS H, NT P, or OS HA.

E pidem iology: No infor mation available.

T er at ogen icit y: No infor mation available.

R epr odu ct ive E f f ect s : No infor mation available.

N eu r ot ox icit y: No infor mation available.

Mu t agen icit y: No infor mation available.

Ot h er S t u dies : No infor mation available.





S ection 12 - Ecological I nfor mation





No infor mation available.

S ection 13 - Dis pos al Cons ider ations





Chemical was te gener ator s mus t deter mine whether a dis car ded chemical is

clas s ified as a haz ar dous was te. US EPA guidelines for the clas s ification

deter mination ar e lis ted in 40 CFR Par ts 261.3. Additionally, was te gener ator s mus t

cons ult s tate and local haz ar dous was te r egulations to ens ur e complete and accur ate

clas s ification.

R CR A P -S er ies : None lis ted.

R CR A U -S er ies : None lis ted.





S ection 14 - T r ans por t I nfor mation







                                                                                   Can ada

                         U S D OT     I AT A    R I D / AD R         I MO

                                                                                    T DG

                       No                                                             No

    S h i ppi n g

                       infor mation                                              infor mation

      N am e:

                       available.                                                 available.

 H az ar d Cl as s :

 U N N u m ber :

P acki n g Gr ou p:









S ection 15 - Regulator y I nfor mation





U S F E D E R AL



T S CA

CAS # 33864- 99- 2 is lis ted on the T S CA inventor y.

H ealt h & S af et y R epor t in g L is t

None of the chemicals ar e on the Health & S afety Repor ting Lis t.

Ch em ical T es t R u les

None of the chemicals in this pr oduct ar e under a Chemical T es t Rule.

S ect ion 1 2 b

None of the chemicals ar e lis ted under T S CA S ection 12b.

T S CA S ign if ican t N ew U s e R u le

None of the chemicals in this mater ial have a S NUR under T S CA.

S AR A



S ect ion 3 0 2 ( R Q)

None of the chemicals in this mater ial have an RQ.

S ect ion 3 0 2 ( T P Q)

None of the chemicals in this pr oduct have a T PQ.

S ect ion 3 1 3

T his mater ial contains Copper (4+ ),n,n',n'',n'''  - 29h,31h- phthalocyaninetetr ayl tetr a

(lis ted as Copper ), 98% , (CAS # 33864- 99- 2) which is s ubj ect to the r epor ting

r equir ements of S ection 313 of S ARA T itle I I I and 40 CFR Par t 373.

Clean Air Act :

T his mater ial does not contain any haz ar dous air pollutants . T his mater ial does not

contain any Clas s 1 Oz one depletor s . T his mater ial does not contain any Clas s 2

Oz one depletor s .

Clean W at er Act :

None of the chemicals in this pr oduct ar e lis ted as Haz ar dous S ubs tances under the

CWA. None of the chemicals in this pr oduct ar e lis ted as Pr ior ity Pollutants under the

CWA. None of the chemicals in this pr oduct ar e lis ted as T ox ic Pollutants under the

CWA.

OS H A:

None of the chemicals in this pr oduct ar e cons ider ed highly haz ar dous by OS HA.

S T AT E

CAS # 33864- 99- 2 is not pr es ent on s tate lis ts fr om CA, PA, MN, MA, FL, or NJ.

Califor nia No S ignificant Ris k Level: None of the chemicals in this pr oduct ar e lis ted.



E u r opean / I n t er n at ion al R egu lat ion s

E u r opean L abelin g in Accor dan ce w it h E C D ir ect ives

H az ar d S ym bols :

Not available.

R is k P h r as es :



S af et y P h r as es :

S 24/25 Avoid contact with s kin and eyes .



W GK ( W at er D an ger / P r ot ect ion )

CAS # 33864- 99- 2: No infor mation available.

Can ada - D S L / N D S L

CAS # 33864- 99- 2 is lis ted on Canada's DS L Lis t.

Can ada - W H MI S

WHMI S : Not available.

Can adian I n gr edien t D is clos u r e L is t

CAS # 33864- 99- 2 (lis ted as Copper ) is lis ted on the Canadian I ngr edient Dis clos ur e

Lis t.

E x pos u r e L im it s

CAS # 33864- 99- 2 (lis ted as copper ): OEL- ARAB Republic of Egypt: T WA 0.1

mg/m3 (fume) OEL- AUS T RALI A: T WA 0.2 mg/m3 (fume) OEL- AUS T RALI A: T WA 1

mg/m3 (dus t) OEL- B ELGI UM: T WA 0.2 mg/m3 (fume) OEL- B ELGI UM: T WA 1 mg/

m3 (dus t) OEL- DENMARK : T WA 0.1 mg/m3 (fume) OEL- DENMARK : T WA 1 mg/m3 (

dus t) OEL- FI NLAND: T WA 0.2 mg/m3 (fume) OEL- FI NLAND: T WA 1 mg/m3 OEL-

FI NLAND: T WA 1 mg/m3 (dus t) OEL- FRANCE: T WA 0.2 mg/m3 (fume) OEL- FRANC

E: T WA 1 mg/m3; S T EL 2 mg/m3 (dus t) OEL- GERMANY: T WA 0.1 mg/m3 (fume) O

EL- GERMANY: T WA 1 mg/m3 OEL- GERMANY: T WA 1 mg/m3 (dus t) OEL- HUNGARY: T W

A 0.2 mg/m3; S T EL 0.4 mg/m3 (dus t) OEL- I NDI A: T WA 0.2 mg/m3 (fume) OEL

- T HE NET HERLANDS : T WA 02 mg/m3 (fume) OEL- T HE NET HERLANDS : T WA 1 mg/m3

(dus t) OEL- T HE PHI LI PPI NES : T WA 1.0 mg/m3 (fume) OEL- POLAND: T WA 0.1 m

g/m3 (fume) OEL- RUS S I A: S T EL 0.5 ppm (1 mg/m3) (dus t) OEL- S WEDEN: T WA

0.2 mg/m3 (r es p. dus t) OEL- S WEDEN: T WA 0.2 mg/m3 (fume) OEL- S WEDEN: T W

A 1 mg/m3 (total dus t) OEL- S WI T Z ERLAND: T WA 0.1 mg/m3; S T EL 0.2 mg/m3 (

fume) OEL- S WI T Z ERLAND: T WA 1 mg/m3; S T EL 1 mg/m3 OEL- T HAI LAND: T WA 0.1

mg/m3 (fume) OEL- T HAI LAND: T WA 1 mg/m3 OEL- UNI T ED K I NGDOM: T WA 0.2 mg/

m3 (fume) OEL- UNI T ED K I NGDOM: T WA 1 mg/m3 OEL I N B ULGARI A, COLOMB I A,

JORDAN, K OREA check ACGI H T LV OEL I N NEW Z EAL





S ection 16 - Additional I nfor mation





MS D S Cr eat ion D at e: 9/02/1997

R evis ion # 2 D at e: 04/17/2003