Product #CH70 Page 1 of 7
MATERIAL SAFETY DATA SHEET
ClearHib 70
Section 01 - Chemical And Product And Company Information
Product Identifier 鈥︹?︹?︹?︹?︹?︹?︹??... ClearHib 70
Product Use 鈥︹?︹?︹?︹?︹?︹?︹?︹?︹?︹??. Corrosion inhibitor
Supplier Name鈥︹?︹?︹?︹?︹?︹?︹?︹??.鈥? ClearTech Industries Inc.
2302 Hanselman Avenue
Saskatoon, SK. Canada
S7L 5Z3
Prepared By................鈥︹?︹?︹?︹??..鈥?. ClearTech Industries Inc. Technical Department
Phone: (306)664-2522
Preparation Date.........鈥︹?︹?︹?︹??.鈥?.. July 18, 2007
24-Hour Emergency Phone鈥︹?︹?︹??.. 306-664-2522
Section 02 - Composition / Information on Ingredients
Hazardous Ingredients....鈥︹?︹?︹??... Propargyl Alcohol 3-7%
1-5%
Aromatic Hydrocarbon Mixture
30-45%
Methanol
CAS Number...................鈥︹??.鈥︹??.... Propargyl Alcohol 107-19-7
Aromatic Hydrocarbon Mixture 64741-67-9
Methanol 67-56-1
Synonym (s)...................鈥︹?︹?︹?︹??.. Not applicable
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Section 03 - Hazard Identification
Inhalation...................鈥︹?︹?︹??.鈥?..... Headache, dizziness, weakness, drowsiness, light-headedness, and
blurred vision. Massive exposures can cause unconsciousness, blindness
and death.
Skin Contact / Absorption鈥︹??.鈥?.... Repeated or prolonged contact causes drying, brittleness, cracking,
irritation and dermatitis.
Eye Contact................鈥︹?︹?︹??.鈥?.....Vapour can irritate the eyes. Liquid can cause severe irritation,
reddening, swelling and corneal burns.
Ingestion.....................鈥︹?︹?︹?︹?︹??..May be harmful if ingested. May be accompanied by shortness of breath,
severe upper abdominal pain, blindness, death.
Exposure Limits鈥︹?︹?︹?︹?︹?︹?︹??....Not available
Section 04 - First Aid Measures
Inhalation....................鈥︹?︹?︹?︹?︹??... Remove victim to fresh air. Give artificial respiration only if breathing has
stopped. If breathing is difficult, give oxygen. Seek immediate medical
attention.
Skin Contact / Absorption鈥︹?︹?︹??... Remove contaminated clothing. Wash affected area with soap and water.
Seek medical attention if irritation occurs or persists.
Eye Contact..................鈥︹?︹?︹?︹??..... Flush immediately with water for at least 20 minutes. Forcibly hold eyelids
apart to ensure complete irrigation of eye tissue. Seek immediate medical
attention.
Ingestion......................鈥︹?︹?︹?︹?︹??.. DO NOT INDUCE VOMITING. Never give anything by mouth if the victim
is rapidly losing consciousness or is unconscious or convulsing. Have
victim drink 300 mL of water to dilute the material. Obtain medical
attention immediately.
Additional Information.....鈥︹?︹?︹??....Provide general supportive measures (comfort, warmth, rest).Consult a
doctor for all exposures except minor instances of inhalation or skin
contact. Protect eyes from strong light.
Section 05 - Fire Fighting
Conditions of Flammability鈥︹?︹??..... Can be ignited under almost all normal temperature conditions (Flash
Point= 25飩癈).
Means of Extinction........鈥︹?︹?︹??..... For small fires use dry chemical, carbon dioxide, water spray or foam.
For large fires use water spray, fog or foam. Wear NIOSH/MSHA
approved, self-contained breathing apparatus and complete
personal protective equipment.
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Flash Point....鈥︹?︹?︹?︹?︹?︹?︹?︹?︹??... 25飩癈 (TCC)
Auto-ignition Temperature鈥︹?︹?︹??.. Not available
Upper Flammable Limit 鈥︹?︹?︹?︹??... Not available
Lower Flammable Limit...鈥︹?︹??.鈥?... Not available
Hazardous Combustible Products.... Carbon monoxide, carbon dioxide and oxides of nitrogen and oxides of
sulfur, on burning.
Special Fire Fighting Procedures...... Wear NIOSH-approved self-contained breathing apparatus and protective
clothing.
Explosion Hazards鈥︹?︹?︹?︹?︹?︹??.... Vapours may form explosive mixture with air.
Section 06 - Accidental Release Measures
Leak / Spill................鈥?.鈥︹?︹?︹?︹??... Wear appropriate personal protective equipment. Ventilate area. Stop or
reduce leak if safe to do so. Prevent material from entering sewers.
Deactivating Materials...鈥︹?︹??.鈥?.... Not available
Section 07 - Handling and Storage
Handling Procedures.......鈥︹?︹?︹??... Use proper equipment for lifting and transporting all containers. Use
sensible industrial hygiene and housekeeping practices. Wash thoroughly
after handling. Avoid all situations that could lead to harmful exposure.
Storage Requirements......鈥︹??...鈥?.. Store in well-ventilated area in tightly closed containers in a cool area
separate from work areas. No sources of heat, flame or sparks should be
present in storage area. Use properly grounded electrical equipment
when working with this product.
Section 08 - Personal Protection and Exposure Controls
Protective Equipment
Eyes.鈥︹?︹?︹?︹?︹?︹?︹?︹?︹??.鈥︹?︹??... Chemical goggles, full-face shield, or a full-face respirator is to be worn at
all times when product is handled. Contact lenses should not be worn; they
may contribute to severe eye injury.
Respiratory鈥︹?︹?︹?︹?︹?︹?︹?︹?︹??.....Chemical cartridge respirator with organic vapour cartridge for up to 1000
ppm. For emergency or planned entry into unknown concentrations use a
self-contained breathing apparatus (SCBA) and full face mask as needed.
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Gloves鈥︹?︹?︹?︹?︹?︹?︹?︹?︹?︹?︹??..... Impervious gloves of chemically resistant material (rubber or PVC) should
be worn at all times. Wash contaminated clothing and dry thoroughly
before reuse.
Clothing鈥︹?︹?︹?︹?︹?︹?︹?︹??..鈥︹??.... Body suits, aprons, and/or coveralls of chemical resistant material should
be worn at all times. Wash contaminated clothing and dry thoroughly
before reuse.
Footwear鈥︹?︹?︹?︹?︹?︹?︹?︹?︹?︹??..... Impervious boots of chemically resistant material should be worn at all
times.
Engineering Controls
Ventilation Requirements鈥︹?︹??...... Mechanical ventilation (dilution or local exhaust), process or personnel
enclosure and control of process conditions should be provided. Supply
sufficient replacement air to make up for air removed by exhaust systems.
Other鈥︹?︹?︹?︹?︹?︹?︹?︹?︹?︹?︹?︹??.....Not available
Section 09 - Physical and Chemical Properties
Physical State.......鈥︹??....鈥︹?︹?︹??.....Liquid
Odor and Appearance鈥?..鈥︹?︹?︹??....Clear, reddish brown colour; aromatic odour.
Odor Threshold....鈥︹?︹?︹?︹??............ Not available
Specific Gravity (Water=1)鈥︹?︹?︹??.. 0.933
Vapor Pressure (mm Hg, 20C)鈥?.鈥?.. Not available
Vapor Density (Air=1)..鈥︹?︹?︹?︹??.....>1
Evaporation Rate........鈥︹??..鈥︹??.鈥?... Not available
Boiling Point...............鈥︹?︹?︹??.鈥?..... Not available
Freeze/Melting Point....鈥︹?︹?︹?︹??.... Not available
pH............................鈥︹?︹?︹?︹?︹??.鈥?...3.3-4.3 (5% of product)
Water/Oil Distribution Coefficient.....Not available
Bulk Density..............鈥︹?︹?︹?︹??.鈥?... 0.933g/mL
% Volatiles by Volume鈥︹?︹??..鈥︹??... Not available
Solubility in Water...鈥︹?︹?︹?︹?︹??..... Not available
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Molecular Formula......鈥︹?︹?︹??.鈥?.... Not available
Molecular Weight........鈥︹?︹?︹?︹??..... Not available
Section 10 - Stability and Reactivity
Stability.................鈥︹?︹?︹??....鈥︹?︹?︹?︹??.Stable
Incompatibility..............鈥︹?︹?︹??..鈥︹?︹??..Strong oxidizing agents, concentrated nitric and sulfuric acids,
aldehydes.
Hazardous Products of Decomposition.. Carbon monoxide; oxides of nitrogen; and oxides of sulfur.
Polymerization...........鈥︹?︹?︹?︹??.鈥︹??.鈥?. Not available
Section 11 - Toxicological Information
Irritancy.................鈥︹??..鈥︹?︹?︹??.鈥?. Not available
Sensitization........鈥︹??.......鈥︹?︹?︹??..Not available
Chronic/Acute Effects鈥︹??...鈥︹?︹??.. Dermatitis, redness of the skin, scaling. Chronic exposure to high levels
can lead to impaired vision. May damage kidneys, heart and other organs.
Synergistic Materials...鈥︹??....鈥︹??... Not available
Animal Toxicity Data......鈥?..鈥︹?︹??...LD50(Rat, Oral)= 54mg/kg (propargyl alcohol)
LD50(Rabblt, Dermal)= 88mg/kg (propargyl alcohol)
LD50(Rat, Oral)= 7500mg/kg (methanol)
LD50(Rabblt, Skin)= 15800mg/kg (methanol)
Carcinogenicity......鈥︹??......鈥︹?︹??... Not available
Reproductive Toxicity..鈥?...鈥︹?︹??....Not available
Teratogenicity..........鈥?.....鈥︹?︹?︹??... Not available
Mutagenicity...........鈥︹??.....鈥︹?︹?︹??. Not available
Section 12 - Ecological Information
Fish Toxicity..................鈥︹?︹?︹?︹??... Not available
Biodegradability.............鈥︹?︹??.鈥?.... Not available
Product #CH70 Page 6 of 7
Environmental Effects鈥︹?︹?︹?︹?︹??. Not available
Section 13 - Disposal Consideration
Waste Disposal...........鈥?...鈥︹?︹?︹??.. Dispose in accordance with all federal, provincial, and/or local regulations
including the Canadian Environmental Protection Act.
Section 14 - Transportation Information
TDG Classification
Class鈥︹?︹?︹?︹??..鈥︹?︹?︹?︹?︹??..鈥?.... 3
Group...............鈥︹?︹?︹?︹??.......鈥︹??... III
PIN Number.................鈥︹??..鈥︹?︹??.... UN 1993
Other鈥︹?︹?︹?︹?︹?︹?︹?︹?︹?︹?︹?︹??..... Secure containers (full and/or empty) with suitable hold down devises
during shipment.
Section 15 - Regulatory Information
WHMIS Classification.......鈥︹?︹?︹??....B, D
NOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE
HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS MSDS
CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS.
Section 16 - Other Information
Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health
hazards and safety information contained herein as a guide and should take those precautions required in an
individual operation to instruct employees and develop work practice procedures for a safe work environment. The
information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions
of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages
incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and
regulations.
Attention: Receiver of the chemical goods / MSDS coordinator
As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible
Distribution庐 initiative, ClearTech Industries Inc. and its associated companies require, as a condition of sale, that
you forward the attached Material Safety Data Sheet(s) to all affected employees, customers, and end-users.
ClearTech will send any available supplementary handling, health, and safety information to you at your request.
If you have any questions or concerns please call our customer service or technical service department.
Product #CH70 Page 7 of 7
ClearTech Industries Inc. - Locations
Corporate Head Office: 2302 Hanselman Avenue, Saskatoon, SK, S7L 5Z3
Phone: 306-664-2522
Fax: 306-665-6216
www.ClearTech.ca
Location Address Postal Code Phone Number Fax Number
Richmond, B.C. 12431 Horseshoe Way V7A 4X6 604-272-4000 604-272-4596
Calgary, AB. 5516E - 40th St. S.E. T2C 2A1 403-279-1096 403-236-0989
Edmonton, AB. 11750 - 180th Street T5S 1N7 780-452-6000 780-452-4600
Saskatoon, SK. 2302 Hanselman Avenue S7L 5Z3 306-933-0177 306-933-3282
Regina, SK. 555 Henderson Drive S42 5X2 306-721-7737 306-721-8611
Winnipeg, MB. 340 Saulteaux Crescent R3J 3T2 204-987-9777 204-987-9770
Mississauga, ON. 7480 Bath Road L4T 1L2 905-612-0566 905-612-0575
24 Hour Emergency Number - All Locations - 306-664-2522
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