Thermal Ceramics
MATERIAL SAFETY DATA SHEET
MSDS No: 141 Date Prepared: 05/01/1987 Current Date: 4/12/2006
Last Revised: (04/10/2006)
1. PRODUCT AND COMPANY IDENTIFICATION
Product Group: REFRACTORY MORTAR
Chemical Name: Aluminosilicate Product
Intended Use: High Temperature Thermal Insulation
Trade Names: Air-Set鈩? (Dry, Wet); Smooth-Set (Dry, Wet); High Temp: IFB (Dry, Wet); SR庐-90 Dry;
Mul-Set鈩? F (Dry, Wet); Unistik庐 A; K庐-Bond (Dry, Wet); Cements; Cer-Flex庐 Mortars
Manufacturer/Supplier: Thermal Ceramics Inc.
P. O. Box 923; Dept. 300
Augusta, GA 30903-0923
For Product Stewardship and Emergency Information -
Hotline: 1-800-722-5681
Fax: 706-560-4054
For additional MSDSs and to confirm this is the most current MSDS for the
product, visit our web page [www.thermalceramics.com].
2. COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT &
% BY WEIGHT
CAS NUMBER OSHA PEL ACGIH TLV
15 mg/m3 (total dust); 10 mg/m3 (inhalable dust)
Aluminum silicate Up to 52
5 mg/m3 (respirable dust) 3 mg/m3 (respirable dust)
1302-76-7
15 mg/m3 (total dust); 10 mg/m3
Aluminum oxide Up to 50
5 mg/m3 (respirable dust)
1344-28-1
(80 mg/m3 梅 % SiO2) 10 mg/m3
Silica, amorphous Up to 40
7631-86-9 or 20 mppcf
15 mg/m3 2 mg/m3 (respirable dust)
Kaolin Up to 27
1332-58-7
See notes(1) 0.05 mg/m3 (respirable dust)
Crystalline silica Up to 20
14808-60-7 or 14464-46-1
Water 0 to 11 Not established Not established
7732-18-5
3
5 mg/m3
Borate, tetra, sodium salt, decahydrate 0 to 2 15 mg/m3 (total dust);
1303-96-4 5 mg/m (respirable dust)
Page 1 Of 6
MSDS No: 141 Date Prepared: 05/01/1987 Current Date: 4/12/2006
Last Revised: (04/10/2006)
NOTES:
(1)
Depending on the percentage and type(s) of silica in the mineral, the OSHA Permissible Exposure Limit (PEL) for respirable dust
containing crystalline silica (8 HR TWA) is based on the formula listed in 29 CFR 1910.1000, 鈥淎ir Contaminants鈥? under Table Z-3,
鈥淢ineral Dust鈥?. For quartz containing mineral dust, the PEL = 10 mg/m鲁 / (% of silica + 2); for cristobalite or tridymite, the PEL = 5
mg/m鲁/ (% of silica + 2); for mixtures, the PEL = 10 mg/m鲁 / (% of quartz + 2 (% of cristobalite) + 2 (% of tridymite) + 2).
(See Section 8 "Exposure Controls / Personal Protection" for exposure guidelines.)
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING!
Respirable dust from these products may contain crystalline silica, which is known to cause respiratory disease.
(See Section 11 for more information)
POSSIBLE HEALTH EFFECTS
Target Organs: Eyes, skin, nose and/or throat
Primary Entry Route: Inhalation
Acute effects: May cause temporary, mild mechanical irritation to the eyes, skin, nose and/or throat. Pre-
existing skin and respiratory conditions may be aggravated by exposure.
Chronic effects: Prolonged/repeated inhalation of respirable crystalline silica may cause delayed lung injury
(e.g.: silicosis, lung cancer).
HAZARD CLASSIFICATION
Dust samples from these products have not been tested for their specific toxicity, but may contain more than 0.1%
crystalline silica, for which the following apply:
The International Agency for Research on Cancer (IARC) has classified crystalline silica inhaled in the form of quartz
or cristobalite from occupational sources as carcinogenic to humans (Group 1).
The Ninth Annual Report on Carcinogens (2000), prepared by the National Toxicology Program (NTP), classified
silica, crystalline (respirable size), as a substance known to be a human carcinogen.
The American Conference of Governmental Industrial Hygienists (ACGIH) has classified crystalline silica (quartz)
as 鈥淎2-Suspected Human Carcinogen.鈥?
The State of California, pursuant to Proposition 65, The Safe Drinking Water and Toxic Enforcement Act of 1986, has
listed "silica, crystalline (airborne particles of respirable size)" as a chemical known to the State of California to cause
cancer.
The Canadian Workplace Hazardous Materials Information System (WHMIS) 鈥? Crystalline silica [quartz and
cristobalite] is classified as Class D2A - Materials Causing Other Toxic Effects.
The Hazardous Materials Identification System (HMIS) 鈥?
Health: 1* Flammability: 0 Reactivity: 0 Personal Protection Index: X (Employer determined)
(* denotes potential for chronic effects)
4. FIRST AID MEASURES
EYE IRRITATION:
Flush with large amounts of water for at least 15 minutes. Do not rub eyes.
SKIN IRRITATION:
Wash affected area gently with soap and water. Skin cream or lotion after washing may be helpful.
Page 2 Of 6
MSDS No: 141 Date Prepared: 05/01/1987 Current Date: 4/12/2006
Last Revised: (04/10/2006)
INGESTION:
Unlikely route of exposure.
INHALATION:
Remove affected person to dust free location. See Section 8 for additional measures to reduce or eliminate exposure.
- If symptoms persist, seek medical attention. -
5. FIRE FIGHTING MEASURES
NFPA CODES: Flammability: _ 0_ , Health: _ 1_ , Reactivity: _ 0_ , Special: _ 0_
NFPA Unusual Hazards: None
Flash Point: None
Extinguishing Media: Use extinguishing media suitable for type of surrounding fire.
Explosion Hazards: None
Hazardous Decomposition Products: None
6. ACCIDENTAL RELEASE MEASURES
SPILL/LEAK PROCEDURES:
Avoid creating airborne dust. Follow routine housekeeping procedures. Vacuum only with HEPA filtered equipment. If
sweeping is necessary, use a dust suppressant and place material in closed containers. Do not use compressed air for
clean-up. Personnel should wear gloves, goggles and approved respirator.
7. HANDLING AND STORAGE
HANDLING
Limit the use of power tools unless in conjunction with local exhaust. Use hand tools whenever possible. Frequently
clean the work area with HEPA filtered vacuum or wet sweeping to minimize the accumulation of debris. Do not use
compressed air for clean-up.
STORAGE
Store in original factory container in a dry area. Keep container closed when not in use.
EMPTY CONTAINERS
Product packaging may contain residue. Do not reuse.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS
Use engineering controls, such as ventilation and dust collection devices, to reduce airborne particulate concentrations
to the lowest attainable level.
RESPIRATORY PROTECTION
When it is not possible or feasible to reduce airborne crystalline silica or particulate levels below the PEL through
engineering controls, or until they are installed, employees are encouraged to use good work practices together with
respiratory protection. Before providing respirators to employees (especially negative pressure type), employers should
1) monitor for airborne crystalline silica and/or dust concentrations using appropriate NIOSH analytical methods and
select respiratory protection based upon the results of that monitoring , 2) have the workers evaluated by a physician to
determine the workers' ability to wear respirators, and 3) implement respiratory protection training programs. Use
NIOSH-certified particulate respirators (42 CFR 84), in compliance with OSHA Respiratory Protection Standard 29 CFR
1910.134 and 29 CFR 1926.103, for the particular hazard or airborne concentrations to be encountered in the work
environment. For the most current information on respirator selection, contact your supplier.
Page 3 Of 6
MSDS No: 141 Date Prepared: 05/01/1987 Current Date: 4/12/2006
Last Revised: (04/10/2006)
PROTECTIVE CLOTHING
Wear full body clothing, gloves, hat, and eye protection as necessary to prevent skin irritation. Washable or disposable
clothing may be used. If possible, do not take unwashed work clothing home. If soiled work clothing must be taken
home, employers should ensure employees are trained on the best practices to minimize or avoid non-work dust
exposure (e.g., vacuum clothes before leaving the work area, wash work clothing separately, rinse washer before
washing other household clothes, etc.).
EYE PROTECTION
Wear safety glasses with side shields or other forms of eye protection in compliance with appropriate OSHA standards
to prevent eye irritation. The use of contact lenses is not recommended, unless used in conjunction with appropriate
eye protection. Do not touch eyes with soiled body parts or materials. If possible, have eye-washing facilities readily
available where eye irritation can occur.
9. PHYSICAL AND CHEMICAL PROPERTIES
ODOR AND APPEARANCE: Concrete like material
CHEMICAL FAMILY: Refractory mortar
BOILING POINT: Not applicable
WATER SOLUBILITY (%): Not soluble in water
MELTING POINT: Up to 3200掳F (depending on the product)
SPECIFIC GRAVITY: Not applicable
VAPOR PRESSURE: Not applicable
pH: Not applicable
VAPOR DENSITY: Not applicable
VOLATILE BY VOLUME (%): Not applicable
MOLECULAR FORMULA: Not Applicable
10. STABILITY AND REACTIVITY
HAZARDOUS POLYMERIZATION: Will not occur
CHEMICAL INCOMPATIBILITIES: Powerful oxidizers; fluorine, manganese trioxide, oxygen disulfide
HAZARDOUS DECOMPOSITION PRODUCTS: None
11. TOXICOLOGICAL INFORMATION
TOXICOLOGY
Dust samples from these products have not been tested. They may contain respirable crystalline silica.
Crystalline silica
Some samples of crystalline silica administered to rats by inhalation and intratracheal instillation have caused fibrosis
and lung cancer. Mice and hamsters, similarly exposed, develop inflammatory disease including fibrosis but no lung
cancer.
EPIDEMIOLOGY
No studies have been undertaken on humans exposed to these products in occupational environments.
Crystalline silica
Exposure to crystalline silica can cause silicosis, and exacerbate pulmonary tuberculosis and bronchitis. IARC
(Monograph vol. 68, 1997) concluded that 鈥渃rystalline silica from occupational sources inhaled in the form of quartz or
cristobalite is carcinogenic to humans (Group 1)鈥?, and noted that 鈥渃arcinogenicity in humans was not detected in all
industrial circumstances studied鈥? and 鈥渕ay be dependent on inherent characteristics of the crystalline silica or on
external factors affecting its biological activity鈥?.
Page 4 Of 6
MSDS No: 141 Date Prepared: 05/01/1987 Current Date: 4/12/2006
Last Revised: (04/10/2006)
12. ECOLOGICAL INFORMATION
Adverse effects of this material on the environment are not anticipated.
13. DISPOSAL INFORMATION
WASTE MANAGEMENT
To prevent waste materials becoming airborne during waste storage, transportation and disposal, a covered container
or plastic bagging is recommended. Comply with federal, state and local regulations.
DISPOSAL
If discarded in its purchased form, this product would not be a hazardous waste under Federal regulations (40 CFR 261)
Any processing, use, alteration or chemical additions to the product, as purchased, may alter the disposal requirements.
Under Federal regulations, it is the waste generator鈥檚 responsibility to properly characterize a waste material, to
determine if it is a hazardous waste. Check local, regional, state or provincial regulations to identify all applicable
disposal requirements.
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
Hazard Class: Not Regulated United Nations (UN) Number: Not Applicable
Labels: Not Applicable North America (NA) Number: Not Applicable
Placards: Not Applicable Bill of Lading: Product Name
INTERNATIONAL
Canadian TDG Hazard Class & PIN: Not regulated
Not classified as dangerous goods under ADR (road), RID (train) or IMDG (ship).
15. REGULATORY INFORMATION
UNITED STATES REGULATIONS
SARA Title III: This product does not contain any substances reportable under Sections 302, 304, 313 (40
CFR 372). Sections 311 and 312 apply.
OSHA: Comply with Hazard Communication Standards 29 CFR 1910.1200 and 29 CFR 1926.59
and Respiratory Protection Standards 29 CFR 1910.134 and 29 CFR 1926.103.
TSCA: All substances contained in this product are listed in the TSCA Chemical Inventory
California: "Silica, crystalline (airborne particles of respirable size)" is listed in Proposition 65, The Safe
Drinking Water and Toxic Enforcement Act of 1986 as a chemical known to the State of
California to cause cancer.
Other States: Crystalline silica products are not known to be regulated by states other than California;
however, state and local OSHA and EPA regulations may apply to these products. Contact
your local agency if in doubt.
INTERNATIONAL REGULATIONS
Canadian WHMIS: Class D-2A Materials Causing Other Toxic Effects
Canadian EPA: All substances in this product are listed, as required, on the Domestic Substance List (DSL).
16. OTHER INFORMATION
SARA TITLE III HAZARD CATEGORIES
Acute Health: No Pressure Hazard: No
Chronic Health: Yes Reactivity Hazard: No
Fire Hazard: No
Page 5 Of 6
MSDS No: 141 Date Prepared: 05/01/1987 Current Date: 4/12/2006
Last Revised: (04/10/2006)
DEFINITIONS:
ACGIH: American Conference of Governmental Industrial Hygienists
ADR: Carriage of Dangerous Goods by Road (International Regulation)
CAA: Clean Air Act
CAS: Chemical Abstracts Service Registry Number
CERCLA: Comprehensive Environmental Response, Compensation and Liability Act
EPA: Environmental Protection Agency
EU: European Union
f/cc: Fibers per cubic centimeter
HEPA: High Efficiency Particulate Air
HMIS: Hazardous Materials Identification System
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
3
mg/m : Milligrams per cubic meter of air
mppcf: Million particles per cubic meter
MSHA: Mine Safety and Health Administration
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
PEL: Permissible Exposure Limit
PNOC: Particulates Not Otherwise Classified
PNOR: Particulates Not Otherwise Regulated
RCRA: Resource Conservation and Recovery Act
RID: Carriage of Dangerous Goods by Rail (International Regulation)
SARA: Superfund Amendments and Reauthorization Act
Title III: Emergency Planning and Community Right to Know Act
鈥ection 302: Extremely Hazardous Substances
鈥ection 304: Emergency Release
鈥ection 311: MSDS/List of Chemicals
鈥ection 312: Emergency and Hazardous Inventory
鈥ection 313: Toxic Chemicals Release Reporting
STEL: Short-Term Exposure Limit
TCLP: Toxicity Characteristics Leaching Procedures (EPA)
TLV: Threshold Limit Values (ACGIH)
TSCA: Toxic Substance Control Act
WHMIS: Workplace Hazardous Materials Information System (Canada)
29 CFR 1910.134 & 1926.103: OSHA Respiratory Protection Standards
29 CFR 1910.1200 & 1926.59: OSHA Hazard Communication Standards
Revision Summary: Section 1: Product Cer-Flex庐 added.
MSDS Prepared By: THERMAL CERAMICS ENVIRONMENTAL, HEALTH & SAFETY DEPARTMENT
DISCLAIMER
The information presented herein is presented in good faith and believed to be accurate as of the effective date of this Material Safety
Data Sheet. Employers may use this MSDS to supplement other information gathered by them in their efforts to assure the health
and safety of their employees and the proper use of the product. This summary of the relevant data reflects professional judgment;
employers should note that information perceived to be less relevant has not been included in this MSDS. Therefore, given the
summary nature of this document, Thermal Ceramics does not extend any warranty (expressed or implied), assume any
responsibility, or make any representation regarding the completeness of this information or its suitability for the purposes envisioned
by the user.
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