MATERIAL SAFETY DATA SHEET
The MSDS format adheres to the standards and regulatory requirements of the United States
and Canada and may not meet regulatory requirements in other countries.
1. PRODUCT INFORMATION
Product Name:
NORTH AMERICA CONTACT INFORMATION
KRONOS庐 TITANIUM
UNITED STATES CANADA
DIOXIDE PIGMENT
This MSDS covers the following Product MANUFACTURER SUPPLIER
Codes:
1000, 1001, 1002, 1014, 1025, 1050, 1071, 1074, KRONOS Canada, Inc.
KRONOS, Inc.
1075, 2020, 2044, 2047, 2063, 2064, 2071-U, 3390 Marie-Victorin
P.O. Box 4272
2073, 2075, 2078, 2081, 2084, 2090, 2101, 2160, Varennes QC
Houston, TX 77210-4272
2211, 2220, 2230, 2233, 2310, 2450, 2500, 2800, J3X 1T4
Gen. Info.: (800) 866-5600
2900, 2980, 3025, 3333 and 4311. Gen. Info.: 450-929-5113
EMERGENCY TELEPHONE:
EMERGENCY TELEPHONE:
CHEMTREC: (800) 424-9300
514-397-1550 (24 hrs/day)
Prepared by: KRONOS: (800) 866-5600
KRONOS NORTH AMERICA MANUFACTURER
5 Cedar Brook Drive
Cranbury, NJ 08512
KRONOS, Inc. and affiliates
P.O. Box 4272
Houston, TX 77210-4272
Revision date: October 17, 2006
Gen. Info.: (800) 866-5600
Supersedes date: June 7, 2006 EMERGENCY TELEPHONE:
KRONOS: (800) 866-5600
2. PRODUCT COMPOSITION
Product Component(s) C.A.S. No. Percent*
Titanium Dioxide -- primary particle diameter is greater than 100 nm. 13463-67-7 80 - 100
Aluminum Oxide 1344-28-1
KRONOS Product Code(s): 2020, 2073, 2075, 2081, 2084, 2160,
2211, 2220, 2230, 2233, 2310, 2450, 2500, 2800 and 4311. 1
Aluminum Hydroxide 21645-51-2
KRONOS Product Code(s): 1071,1074, 1075, 2020, 2044, 2047,
2063, 2064, 2081, 2084, 2090, 2101, 2160, 2211, 2220, 2310,
2800 and 4311. 1-5
Amorphous Silica 112926-00-8
KRONOS Product Code(s): 1075, 2047, 2081, 2101, 2160 and 1鈥?5
2220.
KRONOS Product Code(s): 2044. 5 鈥? 10
*Component percentages are stated on a dry basis.
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW:
Dry product: White odorless powder. Chemically stable. Product is non-combustible. Does not present a fire hazard
or other immediate concerns for emergency responders, except may create a slippery condition if gets wet.
Slurry product: Alkaline (pH = 8 - 10.5) white water slurry. Chemically stable. Does not pose a fire hazard. May
create a slippery condition.
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WARNING 鈥? POTENTIAL HEALTH EFFECTS:
EYE CONTACT: Powder may cause mechanical eye irritation. Alkaline slurry can irritate eyes.
SKIN CONTACT: Powder and alkaline slurry may irritate skin, especially if not promptly washed off skin.
SKIN ABSORPTION: This product is not expected to be absorbed through intact skin.
INGESTION: No adverse health effects anticipated by this route.
INHALATION:
ACUTE EFFECTS: Exposure to dust may cause temporary drying effect and/or mild irritation of the nose, throat,
and lungs, and may aggravate pre-existing respiratory conditions.
CHRONIC EFFECTS/CARCINOGENICITY: Titanium dioxide has been characterized by IARC as possibly
carcinogenic to humans (Group 2B) through inhalation (not ingestion). This classification is based upon animal
inhalation studies. Epidemiology studies do not suggest an increased risk of cancer in humans from occupational
exposure to titanium dioxide. See Section 11 for further detail.
4. FIRST AID MEASURES
Remove person to fresh air. If person appears to have difficulty breathing or respiratory irritation,
Inhalation:
seek medical attention.
Rinse eyes immediately with water for at least 15 minutes. See a physician.
Eye Contact:
Wash skin thoroughly with soap and water. See a physician if irritation persists.
Skin Contact:
Provide symptomatic treatment and seek medical attention.
Ingestion:
5. FIRE FIGHTING MEASURES
Flash Point: N.A. Method: N.A. LEL: N.A. UEL: N.A.
EXTINGUISHING MEDIA/FIRE FIGHTING PROCEDURES:
The pigment is noncombustible; its packaging is combustible. Subject to what would be an appropriate extinguishing
medium for, or in light of, the surrounding materials, use the following extinguishing media when fighting fires involving
this product: water fog, foam, dry chemical, or carbon dioxide.
UNUSUAL FIRE HAZARDS: None.
6. ACCIDENTAL RELEASE MEASURES
RELEASE RESPONSE
Minimize dusting. CAUTION: may cause a slippery condition when wet. Sweep/shovel up and transfer dry product into
a suitable container for re-use or disposal. Flush slurry product to internal wastewater facility or soak up with absorbent
and shovel into suitable container for disposal. Do not flush slurry product into surface water or sanitary sewer system.
PERSONAL PROTECTIVE EQUIPMENT: Please refer to Section 8 for personal protective equipment
information.
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7. HANDLING AND STORAGE
HANDLING
Avoid contact with the eyes.
飥燚o not breathe dust or mist.
Avoid high concentrations of dust or mist in air through the use of ventilation or other suitable controls.
Please refer to Section 8 for engineering control and personal protection equipment information.
o o
Warning: Titanium dioxide product may be packaged at temperatures of approximately 100 to 120 C (212 to 248
F) and stay hot for a long time depending on ambient temperatures and inventory storage practices. Due to the
potential of elevated pigment temperature, caution should be used while handling pigment and in solvent
applications.
STORAGE
Avoid freezing.
8. EXPOSURE CONTROL INFORMATION
OCCUPATIONAL EXPOSURE LIMITS (see Section 15 for other applicable OELs)
ACGIH 鈥? TLV (as 8 hr. TWA) U.S. OSHA 鈥? PEL (as 8 hr. TWA)
COMPONENT
10 mg/m3, total. 15 mg/m3, total.
Titanium Dioxide
3 mg/m3, respirable 5 mg/m3, respirable;
Nuisance Dust/PNOC
15 mg/m3, total
10 mg/m3, inhalable
Aluminum hydroxide Not established. Not established.
5 mg/m3, respirable;
Aluminum oxide 10 mg/m3, total.
15 mg/m3, total
80 mg/m3
Amorphous silica Withdrawn.
% SiO2
Particle size considerations
Fine particles are respirable particles with a primary particle diameter of at least 100 nm. Ultrafine particles are
respirable particles with a primary particle diameter less than 100 nm. This product is not manufactured to
contain ultrafine particles as defined above, and the level of any incidental ultrafine particles is not measurable
at this time. If, however, the user reduces the particle size of this product (through milling or some other
process) so that a significant portion is in the ultrafine range, the significance of the reduced particle size should
be taken into consideration.
ENGINEERING CONTROL MEASURES:
Use local exhaust ventilation if airborne concentrations would otherwise exceed applicable exposure limits.
PERSONAL PROTECTION EQUIPMENT:
Respiratory: Wear a NIOSH-approved air-purifying respirator equipped with an appropriate 100 series
filter for protection against dusts and mists, as appropriate for the exposure levels and
conditions of use. The respirator must be selected by a technically qualified individual.
Hand: Dry product: Use gloves appropriate to protect against abrasion or irritation from poorly
soluble dust. Slurry product: Use gloves appropriate to protect against skin contact with
alkaline slurry.
Eye: Wear eye protection that is compatible with any respiratory protection employed. If
splashing may occur, wear safety glasses with side shields, face shield, and/or vented
goggles.
OTHER CONTROL MEASURES: have emergency eye wash and shower available.
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8. EXPOSURE CONTROL INFORMATION
OCCUPATIONAL EXPOSURE LIMITS (see Section 15 for other applicable OELs)
Use good industrial hygiene practices. Wash hands and face before eating or drinking. Wash work clothing after
each shift.
9. PROPERTIES
DRY PRODUCT
Appearance: White powder Odor: None pH: N.A.
o
Boiling Range: N.A. Melting Range: > 1000 C Specific Gravity: 3.7 - 4.2
Solubility: Insoluble Vapor Density: N.A. Vapor Pressure: N.A.
o
% Volatile: 0 Freezing Point: N.A. Density at 20 C: 30 - 35 lbs/U.S.
gal.
SLURRY PRODUCT
Appearance: Milky white liquid Odor: None pH: 8.0 鈥? 10.5
o
Boiling Range: approx. 100 C Melting Range: N.A. Specific Gravity: 2.1 鈥? 2.4
Solubility: solids are insoluble Vapor Density: N.A. Vapor Pressure: same as water
o
Density at 20o C: 17 鈥? 20 lbs/U.S.
% Volatile: <30 Freezing Point: approx. 0 C
gal.
10. REACTIVITY INFORMATION
Conditions to Avoid: Avoid contact with metals at high temperatures.
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition: Hazardous decomposition will not occur.
Stability: This material is stable under normal operating conditions.
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11. HEALTH/TOXICITY INFORMATION
HEALTH HAZARDS
The following information regarding health hazards is based upon third-party research studies.
Effects of Acute Exposure
Inhalation: Inhalation of dust or mist can cause irritation of the eyes, nose, throat, and lungs.
Eye Contact: Like any foreign body, particles can cause mechanical irritation.
Skin Contact: This material can cause irritation if not promptly washed from the skin.
Skin Absorption: This product is not expected to be absorbed through intact skin.
Ingestion: This material is not expected to produce adverse effects.
Effects of Chronic Exposure
Titanium Dioxide: In lifetime inhalation studies of rats, airborne respirable-size titanium dioxide particles have
been shown to cause an increase in lung tumors at concentrations associated with substantial particle lung burdens
and consequential pulmonary overload and inflammation. The potential for these adverse health effects appears to
be closely related to the particle size and the amount of the exposed surface area that comes into contact with the
lung. However, tests with other laboratory animals, such as mice and hamsters, indicate that rats are
significantly more susceptible to the pulmonary overload and inflammation that causes lung cancer. Epidemiology
studies do not suggest an increased risk of cancer in humans from occupational exposure to titanium dioxide.
Titanium dioxide has been characterized by IARC as possibly carcinogenic to humans (Group 2B) through
inhalation (not ingestion). It has not been characterized as a potential carcinogen by either NTP or OSHA.
Aluminum Oxide, Aluminum Hydroxide and Amorphous Silica: Inhalation of dust particles composed of these
materials (or mist containing these materials) may cause drying of mucous membranes and irritation of nose,
throat, and lungs with nosebleeds, cough, difficulty breathing or shortness of breath. Based solely on animal
studies, long term inhalation exposure to high doses of ultrafine particles (or mist containing these particles) could
lead to pulmonary inflammation and could be a factor in the subsequent development of chronic lung disease.
Amorphous silica does not induce the lung effects associated with crystalline silica.
Medical Conditions Aggravated: Respiratory disorders.
Acute Toxicity: Titanium Dioxide
Oral LD50 > 10,000 mg/kg (rat)
Dermal LD50 > 10,000 mg/kg (rabbit)
Inhalation LC50 (4 hr) > 6.8 mg/l (rat)
12. ECOLOGICAL INFORMATION
None of significance.
13. DISPOSAL CONSIDERATIONS
Dispose of in accordance with local, state, and federal regulations. Use a licensed waste handler.
Do not flush slurry product into surface water or sanitary sewer system.
14. TRANSPORTATION
Shipping Name: Titanium Dioxide Pigment Label: N.A.
Hazard Class: Not regulated Packing Group: N.A. UN#: N.A.
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15. REGULATORY INFORMATION
CHEMICAL INVENTORIES In compliance denotes that all components are on the inventory or exempt.
U.S. TSCA Inventory: Listed
Canadian Domestic Substances List: Listed
SARA 313 Information: Not regulated.
REGULATORY STATUS
Canada: This product has been classified in accordance with hazard criteria of the Hazardous Products Act and
Controlled Product Regulations (WHMIS). This material is a Class D, Division 2, Subdivision B
controlled product under WHMIS, and this MSDS contains all information required by WHMIS.
U.S.: This product is a hazardous chemical under the OSHA Hazard Communication Standard.
OTHER OCCUPATIONAL EXPOSURE LIMITS (OELS).
**ALL OELS ARE EXPRESSED AS AN 8-HR TWA UNLESS NOTED OTHERWISE**
Country/Province/State Titanium dioxide Nuisance Dust (PNOC)
Total Dust Respirable Total Dust Respirable
Canada - Alberta 10 mg/m3 N.E. 10 mg/m3 3 mg/m3
Canada 鈥? New Brunswick 1997 ACGIH 1997 ACGIH TLV 1997 ACGIH TLV 1997 ACGIH TLV
TLV
Canada - Newfoundland 10 mg/m3 N.E. 10 mg/m3 3 mg/m3
and Labrador
Canada - NW Territories 10 mg/m3 5 mg/m3 10 mg/m3 5 mg/m3
Canada - Nova Scotia 10 mg/m3 N.E. 10 mg/m3 3 mg/m3
Canada - Ontario 10 mg/m3 N.E. 10 mg/m3 3 mg/m3
(inhalable)
Canada - Quebec 10 mg/m3 N.E. 10 mg/m3 N.E.
Canada - Saskatchewan 10 mg/m3. N.E. 10 mg/m3. 3 mg/m3.
20 mg/m3, 15- 20 mg/m3, 15-min. 6 mg/m3, 15-min.
min. avg. avg. avg.
Canada- Yukon 10 mg/m3. N.E. N.E. N.E.
Territories 20 mg/m3, 15-
min. avg.
Country/Province/State Amorphous silica
Total Dust Respirable
Canada - Alberta 10 mg/m3 N.E.
Canada 鈥? New Brunswick 1997 ACGIH TLV N.E.
Canada - Newfoundland Withdrawn Withdrawn
and Labrador
Canada-NW Territories 5 mg/m3 2 mg/m3
Canada - Nova Scotia Withdrawn Withdrawn
Canada - Ontario 10 mg/m3 N.E.
Canada- Quebec N.E. 6 mg/m3
Canada- Saskatchewan 10 mg/m3. N.E.
20 mg/m3, 15-
min. avg.
Canada- Yukon 20 mmppcf 2 mg/m3
Territories
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16. OTHER INFORMATION
H.M.I.S. CODES Health: 1 Flammability: 0 Reactivity: 0
Abbreviations
N.A. = Not applicable
N.E. = Not established
The information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and
suitability of the product for particular uses are beyond our knowledge and control. All risks of use of the product
are assumed by the user. WE EXPRESSLY DISCLAIM ALL WARRANTIES, BOTH EXPRESS AND IMPLIED, OF
EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A
PARTICULAR PURPOSE WITH RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Appropriate
warnings and safe handling procedures are required by law to be provided to handlers and users. Alteration of this
document is strictly prohibited. Except to the extent required by law, republication or transmission of this document,
in whole or in part, is not permitted. KRONOS assumes no responsibility for the accuracy of information contained
in this or any document which is not the most current available from an official KRONOS distribution system.
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