AroocoRegular
Amoco PremlumLeaded Gassllne
Indolene Leaded Hotor Fuel
IndustrialHygieneand ToxicologyData Sheet Nos. 5-30
Amerlcan 945 Gasollne
Indurtrirl Hygicne And Toricology Divirion Aviatlon Gasollnes
Environmcntal Conrorvation And Toxicology D.Prftmtnt
(r-7!)
Form U.I967-A
Soction I
Er*rgency Phone Number
Trade Nameand Synonyms
{312}856- 5371
Saa t.;ada n4hac I { c}ad alrnrra
wilrnlsGGment DANGER!EXTREMELY FIAMMABLI
ManufacturerName
!
USEAS A }CITOR FIJELONLY.
AToco_Oil
Coqoanr__
VAFORHARMFUL.
LEAD.
CONTAINS
Address AND/ORASPIRATED
iI,ARMFUL SI.IALI,O.IED
IF
lllinois60601
200 EastRandolphDrive, Chicago,
INIO LT]NGS.
SKIN IRRITATIONUPON
CAN PRODUCN
Product ldentification
PROI.ONGED REPEATED
OR CONTACT.
Ga sol lne
CAS Number 8006-6f -9 ication
OOT Classif
Formula
Flanmable liquid
EPA Number
$ection ll - lmportant Componontr
Gasollne
Lead addltive
C,oncentration
Exposure
Permissible
AccIH nre div 300 ppm (900 me/m3)
$cction lll - Health Effectr Of Exporure
score of 0.0/110.0 (rabbits).
P r i n a a r ye y e l r r i t a t i o n
Acute exposure to hurnansis expected to produce srlnlmal lrrltation'
S1iehtIv for acute exposures
irritating
deratrrng.
rhrough
illi:;1"3"5T"1"$:l::'::1.::?'i"ili!igI;"ili3:);klnirrirarior.
Acute dermal LDlg Sreater than 5 nl/kg- (rabbits); proctically non-toxic for acute
exposures by thii route.
Acute LCE^20.7 ng/L (rats). l{oderately toxlc for acute exposures by thls route.
Excessivd"exposure to vapors will produce synptoms o f i n t o x i c e t i o n .
See Section XI for additional informatlon.
kw viscoslty product - harnful or fataL lf swalLowed and/or aspirated into lungs.
A-cyte oral ID'O 18.8 rrl/kg (rats). Prsctically non-toxic for acute exposures by
thls route.
$cctfon lV - Emcryoncy And Firrt Ald Proccdurrr
Eye Contact plenty of water.
Flush Lrlth
SkinConracr Wash exposed skin with soap snd water., Semove contamlneted c][ot
ahoes, ind thoroughly clean and dry before reuse.
adverse effects occur, remove to uncontami.nated area. Glve artlficlal
solratlon 1f not breathing. Cet medlcal attenttoR.
Ingellron Do !g!. Get lnmedl8te medical aBtention.
lnduce vomlting.
GrCdon V. Prnon.l Ptot.ctlon Infunnrtlon
If contact wear protecttve
ls llkely, and gloves.
clothlng
Avoid breathlne vaDors.
V;ntilation lTypc Rrqsir.d)
Soctlon Vl - Flrc Pruttctlon Informrtlon
Flfih Point (lr?rhod)
Flrmmable Limits luv Volunrcin Airl
Extingrishing Media
(B-C),
Dry chemical fog, foarn (water ma
carbon dloxide, be lneffectlve).
Fire and Exglosion
Unucual Hazards
Extremely fLarnmable vapor/air mixtures form and uray flash back to source of lgnltion.
Srctilon Vll - Phyrlcrl Prop.rtf.r And f,erctlvlty Drta
Boiting&rim<{oF} Range approx. VaporPressure.l
80-430
t (oF) aPor
=
SPecif Gravity (Water 1l
ic 0.75 Solubility in Water Neelisible
{ppearrnce and
rdous Occurs Does NOT Occur
FormedWhenSubjected HighTemperature Cornbustion CombustLon - carbon, ca rbon monoxl.de,
Prodlrcts to or
cerbon dloxide, various hydrocarbons and hydrocarbon derivatlves.
Materials Avoid
to trong oxidlzers.
Vlll - Stongp rnd Envhonmentrl
tectlon Prot ctlon
Stonge Requirements
St.ore in a flanrnable liqulds storage area.
BreakageorLeakage ut off a1l sources of lgnltlon;
Sh use water spray to disperse
lf possible.
vapors; increase ventilat{on
WssteDisposal
Controlled incineration; consult local ordinances for compllance.
C yes
S Yes D No ioaccumulation
Biodegradability fl Unknown f, Unknown
ONo
Srstlon lX - lfrdratlng And Ur Regulrtrd By {Spcclffc Brgubtionr}
O Other {specity}
&ction X - Gommrntr
Label eopy: DANGER! EXTREMELYFLAMMABLE! USE AS A UOTOR FUEL oNLY! CONTAINS
LEAD! VAPOR HARHFUL! HARMFTJL FATAI IF SWAI,LOWED
OR AI{D/OR ASPI-
RATED INIO LUNGS! CAI'I PRODUCE SKIN IRRITATION UPON PROLONGED OR
R.EPEATEDCONTACT LONG-TERM EXPOSI]RE TO VAPORS IiAS CAUSED CAI.ICER
!
IN LABORATORYAT.IIMALS.
Keep away fron heat, sparks and open flame. Avoid breathing vapors.
Use vlth adequate ventilation. Avoid prolouged or repeated skin
If contact is likely,
contact. wear proiect.ive cLothing and gloves.
Remove contaminated clothing, shoes & thoroughly
lncludlng clean 6
dry before reuse. Never slp,hon by raouth.
fOR INIIALATION: If adverse effects occur, remove to uncontamlnated
aree. Glve artiflctal respirarlon Lf not breathing.
Get uedical attentlon.
r0R S K I N : I n c a s e o f c o n t a c t , w a s h e x p o s e d e k i n w i t h s o a p ' a n d F a t e r .
r0R INGESTION: If swallowed, do not lnduce vonlting. Get lunedlate
nedlcal attent'ion.
N/A - Data not available
See Section XI for addltLonal lnforsratlon
Drlr
Tatlc ReVised
tephen A. Elbert USA
rector Product Safet 983
4
2n
Slaterial Safety SectionXl-Supplement
Data $heet
Toxicltv of Gasoline
Vapor
' The Ameriean Petroleum Institute
has completeda toxicity test ln whieh rats
end miee of both s鈧瑇esurere e:(posed unl-eaded
to gasoline vapor eoneentrations
of 6?, 292, and 2056ppm for six hours/day,five diys/week for approximately
two years. Exposure-related kidney damageand kidney tumors were observed
ln male rats, effeets not s鈧琫nin female rats or in mlee. At the highest
etposure level female miee developed ineidenceof liver tumors
an
atatistically gteater then that-s鈧琫n in.the eontrols. Generally, employeeor
erpos-ures considerablyless than the exposures
are
puU-Ug grven in the.animal
toxieity studies.
In eeparate tests, Standard Oil Company(lndiana) found that eertain
componentsof gasoline produeedkidney damagein male rats, but not in
females when the rats were exposedto vapors-for 2l days. A speeial blend
eontaining these componentsin a proportion similar to inat in $asoline
produced less severe kidney damagein male rats only. All of these findings
have been reported to the EPA as required by law.
There appearsto be a resemblanee betweenthe results of the StandardOil
tests and the API test impUcating gasoline vspors. However, other petroleum
hydrocarbonsand other chemieaGhave also been reported to produeekidney
damage in male rats only. The meaningof these findings is gbseuredb$ the
fact that untreated male rats can developkidney damagewith aging.
Althougtr the meaningof thesefindings in terms of humanheatth is uneertain
at this time, it is felt that these results are not a eaus鈧琭or alarm. However,
both StandardOil and the American Petroleum lnst'itute are conducting
further studies to determine any passiblerelation of the effeets seen t6 human
health.
{ y* have any questionsabout the tests or results, eontaet S. A. Elbert,
Direetor, Product safety (usA), standard oil company (Indiana),at
(3r2) 856-?690.
Drtc: April18, 1983
buroorinoi,.et,"ih-gi;;;-tfi;il;ii,ili.il;'h;xi1JlilLrrncd In
::lf*T::*::l::ijEjl*:_bry:TJoouct
prn trom indcP.ndcnthboratoricr o' oihcr rouiccr not $nd!r irr armirrrprwniori.
nli't;#;lffiTill;fi;lfij
lnforrirrtion lr:ccsiltt, rdioblc. complctcot ropirrcntr;;;il til;.i -.v rrty thnruononly rr Buycr'r rltk. Furthrr. rincr
only Buvcr,rrlrk. Furthrr.rir
g 3lL"*1*lP-:i1.1:"li':l l}-T:l1.{ltlyiy conditioni
jj*:'lri*rl'.v,lf;:il,'iil.*#i{?r.lii;yJ;"Tr,flffi"T.*j,i+fi:f.i.{ffii'i.
j}fi
""ariwr'rii'ti,ii'riiiiilioii'lii.i,"J,"&1,1[il;il'.ili:
Gfr;,::,ri
ttsf'r(,utrr tnolot tttutt|on. |nvolvin9 rho ptoduc!'? hrndlinp rnd urc. t!!9ry.!c wo marc nd r.pr'cntlrion or wrrrrnty ol
thtt tho s,s vf u,!pe!!r er rorr presucr.tt In compflrnct
lny.ki1d proou* ula or dirpoaal of tiiir prbducr ir ln complfincc witt, i|l'r.*i.
yvtth all trwa. li-i. il;;ii;.riah
lt ir rhc obligation 6r 'nh
o|f crch r.rr ar r]rr
rrtcr of thc
ruuiocr to ccruminc rna compri wirtr-il irq-u]r.ilr;;-o'iijj jppliiiuri'i;ili;;uterionr.
Amoco.lorch & Ovol dcsgn cn rrgtta.r.d n d.nlrth:;
@ **:!d
anao tt r'a, tcanto lant 1,11p199 Congny,
OJ
AB
btplenation of Terms Used on tho
IndustrialHygieneand Toxicology
Data Sheet
I trctlon lll Ernr{rrncy md Fhn AH
Soctlon I
Procrdunr
Tredr Nemr & Synonyms
Glvt&rt rld md rmrgcncy procrdura In ctr of
The namounderwhich th鈧? productis marketed
rnd
rIr rrdlor *ln entra" hgction rcd Inhrhon.
tho common commorcialname of the product.
Produa ldcntification Socdon Y Furronrl h.clilon lrrfonnrtlon
Thc chemicalor gonoricname of singlaelamente
Eyr,$lln, Rarpirrtory
and compoundsor for compoundedproducts and
mix'tures, generoltype of product,e.g.,calcium ThettOe of protective
the eguipment i3 nocosstry
that
motor oil, polymer,gulfonSt鈧?,
complexgrease, for the grfs handlingand ure of thc product.
surfactant,etc.
Vrndtrdon
CAS l{umbcr Refers thetypergcommendadi.e.,
to : local
exha st,
u
The ChemicalAbstractsRegistrynumber, if etc.
mcchaniccl,
applicable.
EPA Humbcr
tecrloa Yl Hr.lLr.rd lrrfonrrrdon
The code numbar assignedby the Environmental
ProtectionAgency, if applicable. Fr.h Polnt l8trtr mdrod U!.dl
Thetempenture degreerF at wtrich liquidwill
in a
Formula
glvc off cnanghllrmmable.ylporto ignircin th鈧?
The chsmicaf formuls for single slemantgor
Prr$nor ot t lourcc of rgnfion.
compounds.
Artolgntdon Tmprrrtrc
DIOTClagification
ThcminimumtsmpsrEtu rcquiredfor a ru btta nco
re
The oppropriate classification determined the
as by to initirto rolt combudionin tha rbrcncsof r rpark
regulationsof the Office of HarardousMlterials, or flama.
Depanment of Transportati on.
Hrmmrbb Umhr
Tharange gat orveporconoentrrtion centby
S.ction ll of ipcr
volumein air)whichwill bum or cxplodcif rn
lmportant Componcnts ignitionrourco ir prelcnt. Lorwr mesnr tha lowsr
flammable
The major componentas well as any minor ono(s) limit rnd upporthe upporfrrmmeble
having potentialfor harm which are considersd limit given in per ccnt.
when evaluating the product.
Erdmrubhlngm.Ot
Parmisiblc Exposurc Conccntretion Specilierthc fincfiqhting lgsnt{d rhst rhould bs
ThresholdLimit Vatue(TLV),
Indicates utad to extinguithfircr.
ahv limit
e$ablishedby ?-governmental regulatorysgsncy,
Urxraul FIat rnd grdoOon llrrrrdr
or 8n estlmateafnone have beensstablishod.
Rcfcn-torpecid proccdurc rcquired unurualfirs'
il
hlzlrdr rro irwohvcd.
Soction llt Hcalth Effcctr of Erporun
Poglblc hcrtth hrzrrdr rr dartvcd lrom humrn
obeowrtion, tnirnal rtudirs or from thr rrrult d
rtudisa widr similar productt. Vl Plryrlcrl ffoprrOr rrra fllcdvity
lrctlor
Drr.
Mcdial Lsthal Dose or Conccntrrtion (LD5O, LG50l
Y+ahrlrun
Thatdoseor concentrEtion the materialwfrich
of will
produce death in 50 per cent of test animrl3. For Thc prurcuro oil t.turetcd vrpor rbo/c thc llquid
inhalation, exposuretime is indicated.
the ctqnr|.d in mm Hg rt 20cC.
lrrltrdon Indox Vfroo*ty
An empiricalscorefor eye and skin irritrtion whan A mcarurc_of rrirtivo flow of liqukl rfuc to
rhc
t_6-sted the methodsdescribedin Seaion lS0O.40
by grryity or for vircour tQuidr a mcerirrcof thc
ol lhe FederalHazarctous
Substances rql$nc.. to tuming or twirting. stlrc mdhod,
Act.
unnr Ino ttmPcrduoc.
Smrithcr
Yryor D.ndty
A cubstance which will causeon or in normellivino
tissuo,a hypersensitivity gviOont
which beeomee Thcrelctive
o"n denrityorw6i0ht v!poror ger (with
otr
reapplicationof, or exposureto, tho tamc qo trt praontl comprredwith rn cqualvolume of
eubstance. aar rmbianttcmprnturo.
rt
$
pll
The -d,egree acidity or basicity of the mrterial in
of
tp8ctrlcconcentration
Spcdfic GnvitV
T.horatiooJtheweightof a volumaof the msterirtto
rno ryarghtol an equal volume of water .
Solubllitt ln Wrtr
The solubilityof a materialby weight in wrter 8t
room tomperaturo. ^Theterms nogligibte,less than
prl ger conu slight.9.'! !o t pet ceni;"moierateI ro
1u per conu rppreciable,10 per csnt or gracter.
Appcrrango rnd Odor
The general charasterization the materisl, i.e.,
of
powder, colorlessliquid, aromaticodor, 6tc.
Hr:rrdout Polymeiretion
R9{ep ro that reactionwhich takesptacaar s rate
*lriqt releases.lorge amountsof entrsi Incticates
wnsrnerot not,t mEyoccurand underwhctdorage
conditions.
ihtlrirlr to Avoid
Indietes thoro matorial or conditionscruring the
ppduct to resct viofently,releaainglarga rrnounts
of energy.
Soctlon Vttl Stongl rnd Enylrunmrntrl
Rrotrctlon
hoccdurc in Crra of Broakaga or Lcrtrgc
precautionsnecessiry in such l"snn.
Indica-tes
- p.p
l^{ g
!1: createct, n u rocedu re ond lriraiO J ttrii m ey
Da *_"_!r i.,e.,fire, explosions,etc.
Blodrgrrd*Hf tty/8i oeccumu tatioo
Ind.icetos
whetheror nor the productwill biodegrade
or bioaccumulate.
Thr-lnfonnrtion contriad hrain ic brlcd on drta
rihblc to ur rnd ir boliwcd to bc eorrrt. SficJ
thir Infomrtign qr-y hrvc bccn obtrinod in prrt
trom Indapondcnt lrborrto,rior or othr tou?Gat not
undlr otrr dircct rugervirion, no rcprc8antrgon ii
mrdr thlt ttrc inlormation b,ccu?rtc, mtirbh;
complcte or.ap?.nntrtiyo rnd Buyrr mry rcty
tfiercon only rt Buycr'r rieh. Wr trwr mrde n6
-lort to Gtrrror nor to conccd dolrtodour rro{rctl
of thiepoduct Furtrer, dnqt w. crnnei;n6;;
o?-cofrtrd tfir mrny dltrcrmt oondhfom uhd---
nhadt thir informrtion or oor productr mry br
ufcd, wc maka no gurnntc. dhet thr hortib-rnd
tTtty prrcruUonr wc hrvr srgg.std wllf ba
aatcqrrrtc lor rll individurb rndr'or rit[tionr
Cr"\
Itwofving itt hrndllng end ulo. Utowlrc wr mth . ,.1,,r I i
r!9 gurr.ntrc or wrrnnty of my tind tlut drr ur or ti
c.''
d.r,poart of th13 p"odlrgt ir In complirncr witft rlt eii;f'sr'"'"
ttdofill, it tt o? focrl lrrvr. lt ir thr obligrtion of
t*lr urrr ol thr p?oduct mcntionrd trrriin to
det rrnfn rnd comply witft drc nquinrmrotr otrfi
appllcrbb rttnnr!.
Anoco Olt Gomprny
200Erst Rendotoh Orivc
Chicrgo.lllinoir'6090
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