x SAFETY DATA SHEET INFORMATION FORM FOR CHEMICALS
DATA
Date: 16.12.2003 Former date: 19.3.2003
1. IDENTIFICATION OF THE CHEMICAL AND OF THE MANUFACTURER, IMPORTER OR OTHER
UNDERTAKING
1.1 Identification of the substance or preparation
Trade name
庐
PANIPOL T
Code of the preparation
-
1.2 Use of the chemical
1.2.1 The intended uses of the chemical
To produce conductive surfaces
246
1.2.2 Standard industrial classification (SIC)
7
1.2.3 Use categories (UC62)
1.2.4 The chemical can be used by the general public
1.2.5 The chemical is used by the general public only
1.3 Identification of the manufacturer, importer or other undertaking
1.3.1 Manufacturer, importer, other undertaking
Panipol Oy
1.3.2 Contact information:
Ty枚pajatie 20
Street address
FIN-06150 PORVOO, FINLAND
Postcode and post office
P.O.Box 163
Post-office box
FIN-06101 PORVOO; FINLAND
Postcode and post office
+358 207 432 255
Telephone number
+358 207 432 250
Telefax
FI 1504413-7
Y code
1.3.3 Information on foreign manufacturer
-
1.4 Emergency telephone
1.4.1 Telephone number, name and address
Poison Information Centre, Stenb盲ckinkatu 11, FIN-00290 HELSINKI, FINLAND, +358-9-4711
2. COMPOSITION AND INFORMATION ON INGREDIENTS
2.1 Hazardous ingredients
2.1.1 CAS number or 2.1.2 Name of the 2.1.3 2.1.4 Warning symbol, R phrases and
other code ingredient Concentration other data on the ingredient
108-88-3 > 85% F; Xn; R11-20
Toluene
159996-80-2 < 15% Xi; R36/37
Polyaniline salt
2.1.5 There has been a request for confidentiality of a substance
according to Annex 3 of the decree
2.1.6 A substance not dangerous has been indicated as confidential
2.1.7 Other information
Conductive polyaniline solution in toluene.
3. HAZARDS IDENTIFICATION
HEALTH HAZARD: Prolonged and repeated exposure may lead to defatting of the skin and cause
inflammation. Aspiration of the ingested liquid or inhalation of mist may cause chemical pneumonitis.
ENVIROMENTAL HAZARD: Large spills may cause contamination of groundwater.
FIRE HAZARD: Toluene is highly flammable. Formation of explosible mixtures with air is possible.
Vapours heavier than air
4. FIRST AID MEASURES
4.1 Special instructions
-
_______________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________
Page 1
Trade name: PANIPOL庐 T
Date: 16.12.2003 Former date: 19.3.2003
_______________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________
4.2 Inhalation
Remove exposed person to fresh air. If symptoms persist obtain medical advice.
4.3 Skin contact
Remove contaminated clothes and rinse the skin with water. Wash with soap.
4.4 Eye contact
Wash eye thoroughly with copious quantities of water. If irritation persists consult a physician.
4.5 Ingestion
Do not induce voimiting unless directed by medical personel. Rinse mouth with water and consult with
physician.
4.6 Information to doctor or other trained persons giving first aid
Aspiration may cause chemical pneumonitis.
5. FIRE-FIGHTING MEASURES
5.1 Suitable extinguishing media
Foam, dry powder or carbon dioxide (CO2).
5.2 Extinguishing media which must not be used for safety reasons
Water.
5.3 Special exposure hazards in a fire
Thermal decomposition can lead to release of irritating gases and vapours.
Either the liquid or vapor may settle in low areas or travel some distance along the ground or surface to
ignition sources where they may ignite or explode.
5.4 Special protective equipment for fire-fighters
In case of respirable dust and/or fumes, use a self-contained breathing apparatus and dust impervious
protective suit.
5.5 Other instructions
To prevent fire make measures to prevent electrostatic charging.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions
Evacuate nonessential personnel and remove or secure ignition sources. Do not inhale vapours.
6.2 Environmental precautions
Prevent spills from entering drains, sewer, water courses or soil. Take up with liquid-absorbent (e.g.
Chemizorb). Contact local authorities if necessary.
6.3 Methods for cleaning up
Disposal should be carried out in accordance with local regulations.
6.4 Other instructions
-
7. HANDLING AND STORAGE
7.1 Handling
Keep away from sources of ignition and heat. Use adequate ventilation. Wear safety boots or shoes
when handling drums.
7.2 Storage
In a dry well-ventilated storage and tightly closed at room temperature. Prevent spills from entering
drains, sewer, water courses or soil.
7.3 Specific use(s)
-
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Exposure limit values
8.1.1 HTP values
Toluene
100 ppm (8 h) 150 ppm (15 min)
380 mg/m鲁 (8 h) 570 mg/m鲁 (15 min)
Polyaniline salt
5 mg/m鲁 (8 h) 10 mg/m鲁 (15 min)
8.1.2 Other limit values
-
8.1.3 Limit values in other countries
-
8.2 Exposure controls
_______________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________
Page 2
Trade name: PANIPOL庐 T
Date: 16.12.2003 Former date: 19.3.2003
_______________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________
8.2.1 Occupational exposure controls
Avoid inhalation of vapours and skin contact. If vapour or mist is released a respirator and/or mechanical
ventilation is recommended.
8.2.1.1 Respiratory protection
If vapour or mist is released a half mask respirator with organic vapour filter.
8.2.1.2 Hand protection
Imprevious gloves (PVA or Viton).
8.2.1.3 Eye protection
Safety glasses.
8.2.1.4 Skin protection
Wear protective clothing.
8.2.2 Environmental exposure controls
-
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 General information (physical state, colour and odour)
Dark green liquid, aromatic odour.
9.2 Important health, safety and environmental information
9.2.1 pH
Toluene: Not applicable.
Polyaniline salt: 2-3
9.2.2 Boiling point/boiling range
Toluene: > 105掳 C
Polyaniline salt: Not applicable.
9.2.3 Flash point
Toluene: + 6掳C
Polyaniline salt: Not measured.
9.2.4 Flammability (solid, gas)
Not applicable.
9.2.5 Explosive properties
9.2.5.1 Lower explosive limit
Toluene: 1.2 vol%
9.2.5.2 Upper explosive limit
Toluene: 7.0 vol%
9.2.6 Oxidising properties
-
9.2.7 Vapour pressure
Toluene: 29 mbar (20掳 C)
Polyaniline: Not applicable.
9.2.8 Relative density
Toluene: ca. 900 kg/m3
Polyaniline salt: 1.24 kg/m3
9.2.9 Solubility
9.2.9.1 Water solubility
Toluene: < 10 %
Polyaniline salt: Insoluble
9.2.9.2 Fat solubility (solvent-oil to be specified)
-
9.2.10 Partition coefficient: n-octanol/water
Toluene: log Po/w =2.7
9.2.11 Viscosity
10-30 mPa s
9.2.12 Vapour density
-
9.2.13 Evaporation rate
-
_______________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________
Page 3
Trade name: PANIPOL庐 T
Date: 16.12.2003 Former date: 19.3.2003
_______________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________
9.3 Other information
-
10. STABILITY AND REACTIVITY
10.1 Conditions to avoid
Avoid strong heating, sparks, open flame.
10.2 Materials to avoid
Oxidizing agents, nitro compounds, halogen-halogen compounds, nitric acid, sulfur/heat.
10.3 Hazardous decomposition products
CO, NOx, SOx, C6H6-R. Explosible with air in vapors.
11. TOXICOLOGICAL INFORMATION
11.1 Acute toxicity
Toluene: LD50 = 5000 mg/kg, oral, rat
LD50 =30 mg/l (4 h), inhalation, rat
Polyaniline: LD50 > 5000 mg/kg, oral, rat
11.2 Irritation and corrosiveness
Irritating to skin, may cause inflammation and dermatitis after prolonged exposure. Irritate eyes, mucosal
irritations. Irritation symptons in the respiratory tract. The product is acidic in water.
11.3 Sensitisation
Not considered as sensitizer.
11.4 Sub-acute, sub-chronic and prolonged toxicity
May cause skin irritation with prolonged or repeated contact.
11.5 Empirical data on effects on humans
After the absortion of large quantities: Toluene: CNS disorders, inebriation, spasms, unconsciousness,
respiratory arrest, cardiovascular failure.
11.6 Other information on health effects
Effects of exposure are mainly those of pure toluene.
12. ECOLOGICAL INFORMATION
12.1 Ecotoxicity
12.1.1 Aquatic toxicity
Toluene: Acute toxicity;
LC50= 70 mg/l (fish L.idus)
LC0 = 200 mg/l (microbial E.coli)
LC0 = 60 mg/l (alga Daphnia)
12.1.2 Toxicity to other organisms
-
12.2 Mobility
The product may penetrate to the soil reaching the groundwater. It can be adsorbed onto the soil or
organic material of the sediment.
12.3 Persistence and degradability
12.3.1 Biodegradation
Toluene: BOD5: 0.86g/g
Polyaniline: no data
12.3.2 Chemical degradation
Toluene: COD: 0.7 g/g
Polyaniline salt: no data
12.4 Bioaccumulative potential
-
12.5 Other adverse effects
No data available.
13. DISPOSAL CONSIDERATIONS
Residues generally count as special waste. Dispose in accordance with national and local
regulations.
14. TRANSPORT INFORMATION
14.1 UN number
3295
14.2 Packing group
II
_______________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________
Page 4
Trade name: PANIPOL庐 T
Date: 16.12.2003 Former date: 19.3.2003
_______________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________
14.3 Land transport
14.3.1 Transport class
2
14.3.2 Risk code
-
14.3.3 Name according to bill of freight
Hydrocarbons, liquid, n.o.s. (toluene liquid)
14.3.4 Other information
-
14.4 Sea transport
14.4.1 IMDG class
3
14.4.2 Correct technical name
Hydrocarbons, liquid, n.o.s. (toluene liquid)
14.4.3 Other information
-
14.5 Air transport
14.5.1 ICAO/IATA class
3
14.5.2 Correct technical name
Hydrocarbons, liquid, n.o.s. (toluene liquid)
14.5.3 Other information
-
15. REGULATORY INFORMATION
15.1 Information on the warning label
15.1.1 Letter code of the warning symbol and indications of danger for the preparation
F Highly flammable
Xn Harmful
Xi Irritant
15.1.2 Names of the ingredients given on the warning label
Toluene
Polyaniline salt
15.1.3 R phrases
R11 Highly flammable.
R20 Harmful by inhalation.
R36/37 Irritating to the eyes and the respiratory system.
15.1.4 S phrases
S16 Keep away from sources of ignition 鈥? No smoking.
S25 Avoid contact with eyes.
S26 In case of contct with eyes, rinse immediately with plenty of water and seek medical
advice.
S29 Do not empty into drains.
S33 Take precautionary measures against static discharges.
S38 In case of insufficient ventilation, wear suitable respiratory equipment.
S39 Wear eye/face protection.
15.1.5 Special regulations on certain preparations
-
15.2 National regulations
-
16. OTHER INFORMATION
16.1 List of the relevant R phrases
R11, R20, R36/37
16.2 Training advice
Contact manufacturer.
16.3 Restrictions on use
Contact manufacturer.
16.4 Further information
_______________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________
Page 5
Trade name: PANIPOL庐 T
Date: 16.12.2003 Former date: 19.3.2003
_______________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________
Panipol Ltd. P.O.Box 163, FIN-06101 Porvoo, FINLAND, tel. +358 207 432 255, fax. +358 207 432 250,
E-mail: info@panipol.com
16.5 Sources of key data used
16.6 Information which has been added, deleted or revised
_______________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________
Page 6
|