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MSDS Material Safety Data Sheet
CAS

1646-88-4
116-06-3
63-25-2
67-56-1

File Name: pickeringlabs_com---1700-0063.asp
                    Carbamate Test Mixture
Products:
Cat. No. 1700-0063

Section I - General

FORMULA and CAS#:Aldicarb sulfoxide, aldicarb sulfone [1646-88-4], oxamyl [2135-22-0], methomyl [16752-77-
5], 3-hydroxycarbofuran, aldicarb [116-06-3], propoxur [114-26-1], carbofuran [1563-
66-2], carbaryl [63-25-2], 1-naphthol [90-15-3], methiocarb [2032-65-7], 4-bromo-3,5-
dimethyl-phenyl-N-methylcarbamate; 2.5 碌g/mL each in methanol [67-56-1]
Carbamates dissolved in methanol
CHEMICAL NAME:
N-methyl carbamates (urethane), alcohol
CHEMICAL FAMILY:



Section II - Hazardous Ingredients

1: TOXIC Class I & II; DANGER; WARNING: 2.5 碌g/mL of each of eleven carbamates and 1-naphthol in
methanol


Section III - Physical Data
o
65 C (approx)
BOILING POINT:
97 mm Hg @ 20oC
VAPOR PRESSURE:
Clear solution
APPEARANCE:
Methanol solution (miscible with water)
SOLUBILITY:



Section IV - Toxicity Data

Not applicable.
RTECS #:
Not applicable.
RTECS NAME:
Toxicity data are for pure carbamates; the calibration standard contains 2.5碌g/mL of each carbamate in
TOXICITY:
methanol. Aldicarb (rat): oral LD50 1 mg/kg; oxamyl (rat): oral LD50 5.4 mg/kg; propoxur (rat): oral LD50 50
mg/kg; aldicarb sulfone (rat): oral LD50 25 mg/kg; methanol (rat): oral LD50 5,628 mg/kg.
Only selected Registry of Toxic Effects of Chemical Substances (RTECS) data are presented here. Refer to
REVIEWS:
actual entry in RTECS for complete information.




Section V - Health Hazard and First Aid
1
Can be fatal if absorbed through skin; can be fatal if inhaled; can be fatal if swallowed; can cause liver and
ACUTE EFFECTS:
kidney injury; may cause seizures, nausea, vomiting, air way obstruction and increased mucous secretions in
the lungs.
CHRONIC EFFECTS:Cholinesterase inhibitor, cause kidney injury, cause nervous system injury.
Immediately flush with plenty of water for at least 15 minutes; assure adequate flushing by separating
EYE CONTACT:
eyelids with fingers. Get medical assistance.
Wash with water for 15-20 minutes. If no burns have occurred, use soap and water to cleanse skin.
SKIN CONTACT:
INHALATION: Remove to fresh air. If breathing becomes difficult, give oxygen. If not breathing, give artificial respiration. If
patient has cardiac arrest, administer CPR. Continue life support measures until medical assistance arrives.
Rinse mouth with water insuring rinse is not swallowed. Drink 2 glasses of water to dilute and induce
INGESTION:
vomiting by touching finger to back of victim鈥檚 throat. Do not administer water or induce vomiting to an
unconscious or convulsing person. If patient is in shock, keep warm & quiet. Get medical assistance
immediately. ANTIDOTE: atropine sulfate in large therapeutic doses; repeat as necessary to the point of
tolerance. Do not use 2-PAM (pralidoxime chloride); do not use cholinesterase inhibiting drugs; do not use
morphine.


Section VI - Fire and Explosion Hazards

12oC (closed cup)
FLASHPOINT:
EXTINGUISHING
Carbon dioxide, dry chemical powder, water may be effective.
MEDIA:
FIREFIGHTING
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
PROCEDURE:
UNUSUAL
HAZARDS : Very flammable liquid.
EXPLOSIVE
Closed containers exposed to heat may explode.
PROPERTIES:



Section VII - Reactivity

Stable.
GENERAL:
INCOMPATIBILITIES:Primary amines will cause non-hazardous contamination of this solution.
HAZARDOUS
COMBUSTION OR
DECOMPOSTION
Carbon dioxide and carbon monoxide.
PRODUCTS:




Section VIII - Spill or Leak Procedures


2
Wear eye protection and gloves. Soak up spill with rags, paper towels, sponge and hold for waste disposal.
SPILL PROCEDURE:
Ventilate area and wash spill-site with soap and water after material pickup is complete.
Burn in a chemical incinerator equipped with an after burner and scrubber. Comply with all federal, state,
WASTE DISPOSAL:
and local regulations.


Section IX - Precautions for Handling and Storage

SAFETY
Chemical safety goggles, laboratory coat, rubber / latex / vinyl gloves, safety-shower with eye-wash.
EQUIPMENT:
HANDLING
Avoid eye and skin contact and inhalation. Do not ingest. Wear safety glasses and gloves. Wash thoroughly
PROCEDURES:
after handling.

STORAGE
Store at 鈥?4oC.
PROCEDURES:

This information is believed to accurate and represents the best information currently available to us. IT is offered only for
your consideration, investigation, and verification. Pickering Laboratories disclaims any liability incurred from the use of
this product and shall not in any event be liable for any special, incidental, or consequential damages arising from such
use. The information provided herein relates only to the specific product designated and may not be valid where such
product may be subject to federal, state, or local laws or regulations.




3

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