Material Safety Data Sheet - MSDS
Section 1. Chemical Product and Company Identification
Product name Classification
OERLIKON CSA AWS
OP 176; F48A3-EM12K/ F49A3-EM12K/ F48A3-EM13K/ F49A3-EM13K; F7A2-EM12K/ F7A2-EM13K/ F7A2-EL12;
OP 181; - F7A0-EM12K/ F7A0-EL12;
OP 119; - F7A2-EM12K/ F8A0-EA2-A2;
OP 139; F48A3-EM12K/ F49A3-EM12K; F7A2-EM12K/ F7A2-EM13K;
OP 41TT; - F7A6-EG-G1;
OP 121TT; F48A6-EM12K1/ F49A6-EM12; F7A6-EM12K1/ F7A6-EH12K1;
ALCROMO F537; - F8P6-EB3-B3;
OP 33; - E308L-E309L-E316L-E347 STAINLESS;
OP 76; - Stainless, Duplex and Nickel alloys;
Description : SAW - Submerged-Arc Fluxes. Generic Code : AL-J-011-0
In case of emergency : 1-514-878-1667 Date of issue : 01/30/2008
Supplier : Air Liquide Canada Inc. 1250, Ren茅-L茅vesque West, Suite 1700, Montreal, QC H3B 5E6
Section 2. Hazards Identification
Physical state and Appearance : Solid.
Emergency overview : These hazards relate to welding fumes (electrodes in use) and not to the electrodes as sold.
WARNING!
ELECTRIC SHOCK can kill.
FUMES AND GASES can be dangerous to your health.
ARC RAYS can injure eyes and burn skin.
CANCER HAZARD. CAN CAUSE CANCER.
CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: BLOOD, KIDNEYS, LUNGS, LIVER,
RESPIRATORY TRACT, SKIN, CENTRAL NERVOUS SYSTEM, EYES, NOSE, SINUSES.
MAY BE HARMFUL IF INHALED.
CAUSES EYE AND SKIN IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
Corrosive to the eyes, skin and respiratory system. Causes burns. May be harmful if absorbed through skin. Avoid exposure -
obtain special instructions before use. Do not get in eyes or on skin or clothing. Contains material that can cause target organ
damage. Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure. Use only with
adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling.
Routes of entry : Dermal contact. Eye contact. Inhalation.
Potential acute health effects
Eyes : Very hazardous by the following route of exposure: of eye contact (irritant). Inflammation of the eye is characterized by redness,
watering and itching.
Skin : Hazardous by the following route of exposure: of skin contact (sensitizer). Skin contact may produce burns. Skin inflammation is
characterized by itching, scaling, reddening or, occasionally, blistering.
Inhalation: Hazardous by the following route of exposure: of inhalation.
Ingestion : Since the product (welding fumes) is a gas and that it is mostly probable that it will be inhaled more than ingested, please consider
first to look at the preventive measures in case of inhalation.
Potential chronic health effects : Carcinogenic effects(*): Classified A4 by ACGIH, 3 by IARC [Calcium fluoride]. Classified 1 by NTP, + by NIOSH [Silca
crystalline quartz]. Classified A2 by ACGIH, 2A by IARC [Silca crystalline quartz]. Classified A4 by ACGIH [Aluminum Oxide].
Classified A4 by ACGIH [Magnesium oxide]. Classified 2B by IARC [Titanium dioxide]. Classified None. by NIOSH [Titanium
dioxide]. Classified A4 by ACGIH [Titanium dioxide]. Classified A4 by ACGIH [Zirconium oxide]. Classified A4 by ACGIH
[Chromium oxide)].
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
Medical conditions aggravated : Repeated exposure to the fumes emitted while using this material may produce general deterioration of health.
by over-exposure
(*) See Abbreviations (section 16).
Section 3. Composition, Information on Ingredients
CAS # % by weight UN number
Name
Calcium fluoride 7789-75-5 10 - 30 UN1740
Silica, Crystalline - Quartz 14808-60-7 10 - 30 Not applicable.
Aluminum Oxide 1344-28-1 10 - 30 Not applicable.
Magnesium oxide 1309-48-4 10 - 30 Not applicable.
Manganese oxide 1344-43-0 10 - 30 Not applicable.
Titanium dioxide 13463-67-7 5 - 10 Not applicable.
Calcium Oxide 1305-78-8 1-5 UN1910
Zirconium oxide 10101-52-7 1-5 Not applicable.
Iron oxide 1317-61-9 1-5 Not applicable.
Silicium Powder, Amorphous 7440-21-3 1-5 UN1346
Manganese 7439-96-5 1-5 Not applicable.
The fumes emitted by the electrodes, in use, are hazardous. This MSDS is written for workers using these electrodes.
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See Section 8 for Exposure Limits of the oxides found in the welding fumes.
Section 4. First Aid Measures
Eye contact : Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 20 minutes.
Get medical attention immediately.
Skin contact : Wash with soap and water. Get medical attention if irritation develops.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion : Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If
potentially dangerous quantities of this material have been swallowed, call a physician immediately.
Section 5. Fire Fighting Measures
Flammability of the product : Non-flammable. Emits toxic fumes when heated.
Explosibility : Non-explosive in the presence of the following materials or conditions: open flames, sparks and static discharge, heat and shocks
and mechanical impacts.
Fire-fighting media and : Use extinguishing media suitable for surrounding materials.
instructions
Section 6. Accidental Release Measures
Small/Large Spill and Leak : Use appropriate tools to transfer the spilled solid to a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Section 7. Handling and Storage
Handling : Avoid breathing dusts, vapors or fumes from burning materials. Use only with adequate ventilation. Avoid contact with eyes, skin
and clothing. Do not ingest. Keep container closed. Wash thoroughly after handling.
Storage : All filler metals in their original, unopened containers should be kept in a relatively dry storage area at temperatures between 15掳C
(60掳F) and 30掳C (80掳F) and 50% maximum relative humidity.
Section 8. Exposure Controls, Personal Protection
Engineering controls : Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants
below any recommended or statutory limits. If user operations generate dust, fumes or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal protection
Eyes
: Safety glasses with side shields. Face shield with radiation shielding.
Body
: Full suit. (Fire resistant.)
Respiratory : Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear a canister breathing apparatus (respirator) or a
supplied-air respirator, when required, to weld in a confined space or when room exhaust or ventilation does not keep exposure
below the acceptable values.
Hands : Gloves. (Fire resistant.)
Feet : Metal cap, safety boots.
Exposure limits
Product name Exposure limits
Welding fumes ACGIH (TLV) TWA: 5 mg/m3 as Iron Oxide; STEL: 3 mg/m3 as Manganese Oxide.
Calcium fluoride OSHA PEL (United States, 11/2006). TWA: 2.5 mg/m3 8 hour(s). Form: Dust
ACGIH TLV (United States, 1/2006). TWA: 2.5 mg/m3 8 hour(s). Form: All forms.
Silica, Crystalline - Quartz ACGIH TLV (United States, 1/2006). TWA: 0.025 mg/m3 8 hour(s). Form: Respirable fraction
NIOSH REL (United States, 12/2001). TWA: 0.05 mg/m3 10 hour(s). Form: All forms.
Aluminum Oxide ACGIH TLV (United States, 1/2006). TWA: 10 mg/m3 8 hour(s). Form: All forms.
NIOSH REL (United States, 12/2001). TWA: 5 mg/m3 10 hour(s). Form: All forms.
OSHA PEL (United States, 11/2006). TWA: 5 mg/m3 8 hour(s). Form: Respirable fraction TWA: 15 mg/m3 8 hour(s). Form: Total
dust
Magnesium oxide ACGIH TLV (United States, 1/2006). TWA: 10 mg/m鲁 8 hour(s). Form: Fume
OSHA PEL (United States, 11/2006). TWA: 15 mg/m鲁 8 hour(s). Form: Total particulates
Manganese oxide ACGIH TLV (United States, 1/2006). TWA: 0.2 mg/m3 8 hour(s). Form: All forms.
NIOSH REL (United States, 12/2001). STEL: 3 mg/m3 15 minute(s). TWA: 1 mg/m3 10 hour(s).
OSHA PEL (United States, 11/2006). CEIL: 5 mg/m3 Form: All forms
Titanium dioxide ACGIH TLV (United States, 1/2006). TWA: 10 mg/m3 8 hour(s). Form: All forms.
OSHA PEL (United States, 11/2006). TWA: 15 mg/m3 8 hour(s). Form: Total dust
Calcium Oxide ACGIH TLV (United States, 1/2006). TWA: 2 mg/m3 8 hour(s). Form: All forms.
NIOSH REL (United States, 12/2001). TWA: 2 mg/m3 10 hour(s). Form: All forms.
OSHA PEL (United States, 11/2006). TWA: 5 mg/m3 8 hour(s). Form: All forms.
Zirconium oxide ACGIH TLV (United States, 1/2006). STEL: 10 mg/m3 15 minute(s). TWA: 5 mg/m3 8 hour(s).
NIOSH REL (United States, 12/2001). STEL: 10 mg/m3 15 minute(s). TWA: 5 mg/m3 10 hour(s).
OSHA PEL (United States, 11/2006). TWA: 5 mg/m3 8 hour(s).
Chromium trioxide (VI) ACGIH TLV (United States, 1/2006). TWA: 0,05 mg/m3 8 hour(s). Form: Soluble TWA: 0,01 mg/m3 8 hour(s). Form: Insoluble
OSHA PEL (United States, 2/2006). TWA: 5 渭g/m鲁 8 hour(s). Form: All forms.
Consult local authorities for acceptable exposure limits.
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Section 9. Physical and Chemical Properties
Physical state and Appearance : Solid.
Color : Reddish-brown. Grayish-white.
Odor : Odorless.
Melting/freezing point : Not available.
Specific gravity : Not available.
Solubility : Insoluble in the following materials: cold water, hot water.
Section 10. Stability and Reactivity
Stability and reactivity : The product is stable.
Hazardous decomposition : Metallic oxides. Carbon oxides (CO, CO2). Arc radiation can support the production of ozone and nitrogen oxides.
products
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Section 11. Toxicological Information
Additional Toxicity data
Ingredient name Test Result Route Species
Calcium fluoride LD50 4250 mg/kg Oral Rat
Chronic effects and other toxic : CARCINOGENIC EFFECTS: See Section 2.
effects on humans Contains material which causes damage to the following organs: blood, kidneys, lungs, upper respiratory tract, skin, central nervous
system (CNS), eye.
Acute exposure to welding fumes may result in discomfort such as: dizziness, nause or dryness of nose, throat or the eyes.
Section 12. Ecological Information
Ecotoxicity data
Ingredient name Species Period Result
Nickel Daphnia magna (EC50) 48 hour(s) 1 mg/l
Manganese Daphnia magna (EC50) 48 hour(s) 40 mg/l
Chromium, Metal Daphnia magna (EC50) 48 hour(s) 0.07 mg/l
Products of degradation : Decomposition products may include the following materials: halogenated compounds. Some metallic oxides.
Section 13. Disposal Considerations
Waste information : Waste must be disposed of in accordance with federal, state and local environmental control regulations. Recycle, if possible.
Consult your local or regional authorities.
Section 14. Transport Information
No transport class is found applicable to this product.
Section 15. Regulatory Information
HCS Classification : These hazards relate to welding fumes (electrodes in use) and not to the electrodes as sold.
Contains material which may cause cancer.
Irritating material
Sensitizing material
Target organ effects
U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted.
Clean Water Act (CWA) 307: Chromium oxide
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Aluminum Oxide; Silica crystalline, quartz; Calcium fluoride; Titanium dioxide;
Silicon; Magnesium oxide; Manganese; Calcium Oxide
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Aluminum Oxide: Immediate (acute) health
hazard; Silica crystalline, quartz: Immediate (acute) health hazard, Delayed (chronic) health hazard; Calcium fluoride: Immediate
(acute) health hazard; Titanium dioxide: Delayed (chronic) health hazard; Silicon: Fire hazard, Immediate (acute) health hazard;
Magnesium oxide: Immediate (acute) health hazard; Manganese: reactive, Immediate (acute) health hazard, Delayed (chronic)
health hazard; Calcium Oxide: Immediate (acute) health hazard
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SARA 313
Form R - Reporting : Aluminum Oxide 10 - 30
Manganese oxide 10 - 30
requirements
Manganese 1-5
Supplier notification : Aluminum Oxide 10 - 30
Manganese oxide 10 - 30
Manganese 1-5
State regulations : Massachusetts Substances: The following components are listed: Silica crystalline, quartz; Aluminum Oxide; Magnesium oxide;
Titanium dioxide; Calcium Oxide; Silicon;Manganese
New Jersey Hazardous Substances: The following components are listed: Calcium fluoride; Silica crystalline, quartz; Aluminum
Oxide; Magnesium oxide; Manganese oxide; Titanium dioxide; Calcium Oxide; Silicon;Manganese
Pennsylvania RTK Hazardous Substances: The following components are listed: Silica crystalline, quartz; Aluminum Oxide;
Magnesium oxide; Manganese oxide; Titanium dioxide; Calcium Oxide; Iron Salts; Silicon;Manganese
WARNING: This product contains a chemical known to the State of California to cause cancer.
WHMIS (Canada) : These hazards relate to welding fumes (electrodes in use) and not to the electrodes as sold.
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
CEPA Toxic substances: The following components are listed: Calcium fluoride
Canadian ARET: None of the components are listed.
Canadian NPRI: The following components are listed: Calcium fluoride; Aluminum Oxide; Manganese oxide;Manganese
This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR.
Section 16. Other Information
Label requirements : See Section 2.
Hazardous Material Information System (U.S.A.) : Health: 2* Fire: 0 Reactivity: 0
National Fire Protection Association (U.S.A.) : Health: 2 Fire: 0 Reactivity: 0 Other: None
References : - 29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names,
PG. - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version 2005. - CRC Handbook of
chemistry and physics, 67th edition. CRC Press inc., Boca Raton, Florida. - Manufacturer's Material Safety Data Sheet. ANSI
Z400.5, MSDS Standard, 2004. ANSI Z49.1 Safety in Welding and Cutting, The American Welding Society, P.O. Box 351040,
Miami, FL 33135. Canadian Standard Association, CSA W117.2, Code for Safety in Welding and Cutting, 2003.
Abbreviations : ACGIH: American Conference of Governmental Industrial Hygiene.
ACGIH A2--Suspected Human Carcinogen.
ACGIH-A4-Not Classifiable as a Human Carcinogen.
IARC: International Agency for Research on Cancer.
IARC 2A: Probable for human.
IARC 2B: Possible for human.
IARC 3: Not classifiable for human.
NIOSH: National Institute of Occupational Safety and Health.
NIOSH +: Proven.
NIOSH: None.
NTP: National Toxicology program.
NTP 1: Known to be human carcinogens.
Responsible name : Atrion Regulatory Services, Inc.
Date of previous issue : 12/31/2005
Version :3
Notice to reader
THE INFORMATION, RECOMMENDATIONS AND DATA CONTAINED IN THIS DOCUMENT ARE INTENDED TO BE USED BY PROPERLY TRAINED AND
QUALIFIED PERSONNEL ONLY AND AT THEIR SOLE RISKS AND DISCRETION. THE INFORMATION, RECOMMENDATIONS AND DATA HEREIN CONTAINED
ARE DERIVED FROM SOURCES WHICH WE BELIEVE TO BE RELIABLE. HOWEVER, AIR LIQUIDE CANADA INC. MAKES NO REPRESENTATION AND GIVES
NO WARRANTY OF ANY KIND WHATSOEVER WITH RESPECT TO THEIR ACCURACY OR COMPLETENESS AND ASSUMES NO LIABILITY FOR DAMAGES OR
LOSS ARISING DIRECTLY OR INDIRECTLY FROM THEIR USE, WHETHER PROPER OR IMPROPER.
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