GTFP PINE MOULDINGS FINGER JOINTED PRODUCTS - RESORCINOL
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MATERIEL SAFETY DATA SHEETS
IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
Not classified as hazardous according to Worksafe Australia criteria.
Not considered a dangerous substance according to
directive 67/548/EEC, point 4; and to 29 CFP 1910-1200 (USA).
SUPPLIER
Company: Green Triangle Forest Product Ltd
Address:
PO Box 330
Mount Gambier
SA 5290
Australia
Telephone: (08) 8721 8395
Fax: (08) 8721 8400
CHEMWATCH HAZARD RATINGS
Flammability: 1
Toxicity: 0
Body Contact: 0
Reactivity: 0
Chronic: 4
SCALE: Min/Nil = 0 Low = 1 Moderate = 2 High = 3 Extreme = 4
PERSONAL PROTECTIVE EQUIPMENT FOR INDUSTRIAL/COMMERCIAL
ENVIRONMENTS
GTFP PINE MOULDINGS FINGER JOINTED PRODUCTS - RESORCINOL
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MATERIEL SAFETY DATA SHEETS
TRADE NAMES
Softwoods Finger Jointed Pine Mouldings
Resorcinol Glue
MATERIAL DETAILS
CAS RN No(s) None
NIOSH No None
POISONS SCHEDULE None
UN No None
HAZCHEM None
DANGEROUS G. CLASS None
SUB RISK None
PACKAGING GROUP None
EPG None
IMO CLASS None
IMDG PAGE None
LABEL No class label assigned
SHIPPING NAME
NONE
USE
Mouldings are used in furniture or construction applications.
APPEARANCE
Pale gold to brown colour; insoluble in water. The freshly cut product may have a
faint pine odour; after the glue has cured there is not particular odour.
PHYSICAL PROPERTIES
Molecular Weight: Not applicable
Vapour Pressure(kPa): Not applicable
Boiling Range(C): Not applicable
Volatile Component(%Vol): Not available
Melting Range(C): Not applicable
Relative Vapour Density**: Not applicable
Specific Gravity*: 0.4-0.9
Flash Point(C): Not applicable
Water Solubility: Immiscible
Lower Explosive Limit(%): Not available
GTFP PINE MOULDINGS FINGER JOINTED PRODUCTS - RESORCINOL
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MATERIEL SAFETY DATA SHEETS
Upper Explosive Limit(%): Not available
pH(as supplied): Not applicable
pH(1% solution): Not applicable
Auto ignition Temp(C): >200
Evaporation Rate: Not available
Decomposition Temp(C): Not available
State: Divided solid
Legend: * Water=1, ** Air=1
INGREDIENTS
NAME CAS RN %
softwood >98
resorcinol/formaldehyde resin <1
In use, may generate
wood dust softwood Not avail. >1
SYNONYMS
softwood pine sawn and moulded profiles
HEALTH HAZARD
ACUTE HEALTH EFFECTS
SWALLOWED
Overexposure is unlikely in this form and quantity. Considered an unlikely route of
entry in commercial/industrial environments.
EYE
The dust is slightly abrasive to the eyes.
SKIN
The material may be mildly discomforting to the skin and is capable of causing skin
reactions which may lead to dermatitis.
INHALED
Not normally a hazard due to non-volatile nature of product Inhalation hazard is
increased at higher temperatures.
GTFP PINE MOULDINGS FINGER JOINTED PRODUCTS - RESORCINOL
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MATERIEL SAFETY DATA SHEETS
CHRONIC HEALTH EFFECTS
Principal routes of exposure are by skin contact and inhalation of machining dust.
FIRST AID
SWALLOWED
1. DO NOT induce vomiting.
2. If vomiting occurs, lean patient forward or place on left side (head-down position,
if possible) to maintain open airway and prevent aspiration.
3. Observe the patient carefully.
4. Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
5. Give water (or milk) to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
6. Seek medical advice.
EYE
If this product comes in contact with the eyes:
1. Immediately hold the eyes open and wash with fresh running water.
2. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye
and moving the eyelids by occasionally lifting the upper and lower lids.
3. If pain persists or recurs seek medical attention.
4. Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If product comes in contact with the skin:
1. Wash affected areas thoroughly with water (and soap if available).
2. Seek medical attention in event of irritation.
INHALED
1. If dust is inhaled, remove to fresh air.
2. Encourage patient to blow nose to ensure clear breathing passages.
3. Rinse mouth with water. Consider drinking water to remove dust from throat.
4. If ir ritation or discomfort persists seek medical attention.
5. If fumes or combustion products are inhaled: Remove to fresh air.
6. Lay patient down. Keep warm and rested.
7. Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures
8. If available, administer medical oxygen by trained personnel.
GTFP PINE MOULDINGS FINGER JOINTED PRODUCTS - RESORCINOL
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MATERIEL SAFETY DATA SHEETS
9. If breathing is shallow or has stopped, ensure clear airway and apply
resuscitation, preferably with a demand valve resuscitator, bag-valve mask
device, or pocket mask as trained. Perform CPR if necessary.
10. Transport to hospital, or doctor, without delay.
ADVICE TO DOCTOR
Treat symptomatically.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
WOOD DUST SOFTWOOD
No significant acute toxicological data identified in literature search.
CAUTION : Inhalation of wood dust by workers in the furniture industry has
been related to nasal cancer.
[ILO Encyclopaedia]
WARNING: This substance has been classified by the IARC as Group 1
CARCINOGENIC TO HUMANS.
PRECAUTIONS FOR USE
EXPOSURE STANDARDS
None assigned. Refer to individual constituents.
WOOD DUST SOFTWOOD
soft wood:
TLV TWA: 5 mg/m3; STEL: 10 mg/m3
NOTICE OF INTENDED CHANGE
TLV TWA 5 mg/m3 Sensitiser A4
NOTE: This substance has been classified by the ACGIH as A4
NOT classifiable as causing Cancer in humans.
ES TWA: 5 mg/m3; STEL: 10 mg/m3 (Sensitiser) (Under review)
wood dust: as western red cedar
TLV TWA 0.5 mg/m3 Sensitiser A4 (ACGIH Intended change/addition)
PEL: 2.5 mg/m3 OSHA
Wood dusts produce dermatitis and an increased risk of upper respiratory
disease. Epidemiological studies in furniture workers show an increased
risk of lung, tongue, pharynx and nasal cancer. An excess risk of leukaemia
amongst millwrights probably is associated with exposure to various
components used in wood preservation.
Impairment of nasal mucociliary function may occur below 5 mg/m3 and
GTFP PINE MOULDINGS FINGER JOINTED PRODUCTS - RESORCINOL
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MATERIEL SAFETY DATA SHEETS
may be important in the development of nasal adenocarcinoma amongst
furniture workers exposed to hardwoods.
Certain exotic hardwoods contain alkaloids which may produce headache,
anorexia, nausea, bradycardia and dyspnea.
The softwood TLV-TWA reflects the apparent low risk for upper respiratory
tract involvement amongst workers in the building industry. A separate
TLV-TWA, for hard woods, is based on impaired nasal mucocilliary function
reported to contribute to nasal adenocarcinoma and related hyperplasia
found in furniture workers.
The TLVs for hardwood and softwood specifically exclude the issue of
occupational asthma and related allergic respiratory response associated
with exposure to red cedar dusts and similar woods.
TRK: 2 mg/m3
(measured as inhalable fraction of the aerosol)
The technical exposure limit, TRK (Technische Richtkonzentrationen),
defines the airborne concentration of named carcinogenic materials which
is the minimum possible given the state of current technologies.
TRK values are assigned only for materials for which there is no current
MAK (German exposure standard). Observance of the TRK value is intended to
reduce the risk of adverse effects on health but does NOT completely
eliminate it. Since no threshold doses can be determined for carcinogens,
health considerations require that the exposure limits be kept as far as
possible below the TRK and that the TRK value be gradually reduced.
The limitation of exposure peaks is regulated as follows;
Short-term exposure limit: 5 x TRK
Short-term exposure duration: 15 min/average
Frequency per work shift: 5 times
Interval: 1 hour.
Report No. 35 1999, Deutsche Forschungsgemeinschaft.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer aided prediction of spray/mist or fume/dust
components and concentration :
Composite Exposure Standard for Mixture (TWA): 5.0000 mg/m3.
Operations which produce a spray/mist or fume/dust, introduce particulates to the
breathing zone.
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerat ions deem the individual to be over-exposed.
Breathing Zone Mixture
Component Conc. mg/m3 Conc.(%)
------------------------------------------------------------------------------------------------------------
wood dust softwood 5.0000 100.0
GTFP PINE MOULDINGS FINGER JOINTED PRODUCTS - RESORCINOL
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MATERIEL SAFETY DATA SHEETS
ENGINEERING CONTROLS
Avoid generating and breathing dust. Effective dust extraction and good ventilation is
required when using cutting, shaping or sanding tools. Wear a disposable dust mask
AS 1715 (1991) class P1 or P2 when machining. Avoid sawing or sanding of timber
that is wet (not dry) with treatment chemicals.
PERSONAL PROTECTION
EYE
When sawing, machining or sanding use safety glasses with side shields.
Contact lenses pose a special hazard; soft lenses absorb irritants and all lenses
concentrate them.
HANDS/FEET
Wear safety footwear. Wear impervious gloves.
Avoid contact with ash.
OTHER
Overalls Barrier cream.
Eyewash unit.
RESPIRATOR
Protection Half-Face Full-Face Powered Air
Factor Respirator Respirator Respirator
-----------------------------------------------------------------------------------------------------------------
----------
10 x ES P1 - PAPR-P1
Air-line* - -
50 x ES Air-line** P2 PAPR-P2
100 x ES - P3 -
Air-line* -
100+ x ES - Air-line** PAPR-P3
* - Negative pressure demand ** - Continuous flow.
The local concentration of material, quantity and conditions of use determine the type
of personal protective equipment required. For further information, consult site
specific CHEMWATCH data (if available), or your Occupational Health and Safety
Advisor.
HANDLING PROCEDURES
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
GTFP PINE MOULDINGS FINGER JOINTED PRODUCTS - RESORCINOL
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MATERIEL SAFETY DATA SHEETS
When handling, DO NOT eat, drink or smoke.
Always wash hands with soap and water after handling. Work clothes should be
laundered separately.
Use good occupational work practice. Observe manufacturer's storing and handling
recommendations.
CONDITION CONTRIBUTING TO INSTABILITY
Product is considered stable and hazardous polymerisation will not occur.
SAFE HANDLING
STORAGE
SUITABLE CONTAINER
Not applicable.
STORAGE INCOMPATIBILITY
None known.
STORAGE REQUIREMENTS
1. Keep dry.
2. Store under cover.
3. Store in a well ventilated area.
4. Store away from sources of heat or ignition.
5. Observe manufacturer's storing and handling recommendations.
No smoking, naked lights or ignition sources.
TRANSPORTATION
No restrictions.
SPILLS
MINOR SPILLS
Refer to major spills.
MAJOR SPILLS
1. Minor hazard.
2. Clear area of personnel.
GTFP PINE MOULDINGS FINGER JOINTED PRODUCTS - RESORCINOL
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MATERIEL SAFETY DATA SHEETS
3. Alert Fire Brigade and tell them location and nature of hazard.
4. Wear physical protective gloves e.g. Leather.
5. Contain spill/secure load if safe to do so.
6. Bundle/collect recoverable product and label for recycling.
7. Collect remaining product and place in appropriate containers for disposal.
8. Clean up/sweep up area.
9. Water may be required.
DISPOSAL
1. Recycle wherever possible or consult manufacturer for recycling options.
2. Consult State Land Waste Management Authority for disposal.
3. Bury residue in an authorised landfill.
4. Recycle containers if possible, or dispose of in an authorised landfill.
FIRE FIGHTERS REPORT
EXTINGUISHING MEDIA
Water spray or fog. Foam. Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
FIRE FIGHTING
1. Alert Fire Brigade and tell them location and nature of hazard.
2. Wear breathing apparatus plus protective gloves.
3. Prevent, by any means available, spillage from entering drains or water course.
4. Use water delivered as a fine spray to control fire and cool adjacent area.
5. Do not approach containers suspected to be hot.
6. Cool fire exposed containers with water spray from a protected location.
7. If safe to do so, remove containers from path of fire.
8. Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
Combustible Moderate fire hazard when exposed to heat or flame.
Avoid creating dust - may present dust explosion hazard. Dry dust can be
electrostatically charged by turbulence, pneumatic transport, pouring, in exhaust
ducts and during transport. Build-up of electrostatic charge may be prevented by
grounding.
Decomposes on heating and produces toxic fumes of carbon monoxide (CO) and
carbon dioxide (CO2).
GTFP PINE MOULDINGS FINGER JOINTED PRODUCTS - RESORCINOL
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MATERIEL SAFETY DATA SHEETS
FIRE INCOMPATIBILITY
Avoid reaction with oxidising agents.
ENVIRONMENTAL
No data for GTFP Pine Mouldings Finger Jointed Products - Resorcinol.
Refer to data for ingredients, which follows:
WOOD DUST SOFTWOOD:
No data for wood dust softwood.
CONTACT POINT
AUSTRALIAN POISONS INFORMATION CENTRE
24 HOUR SERVICE: 13 11 26
POLICE, FIRE BRIGADE OR AMBULANCE: 000
End of Report (REVIEW)
Date of Preparation: Wed 13-Dec-2000
Print Date: Wed 11-Apr-2001
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