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MSDS Material Safety Data Sheet
CAS

7782-42-5
1313-13-9
7439-97-6

File Name: swe_com---eveready_alkaline_manganese_dioxide_zinc.asp
MINIATURE PRODUCT SAFETY DATA SHEET                                                               Page 1 of 4




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5




PRODUCT SAFETY DATA SHEET

PRODUCT NAME: EVEREADY Battery Type No.: Volts:
TRADE NAME: ENERGIZER, Miniature Alkaline Approximate Weight:
CHEMICAL SYSTEM: Alkaline Manganese Dioxide-Zinc Designed for Recharge: No


5

SECTION I - MANUFACTURER INFORMATION

Eveready Battery Company, Inc. Telephone Number for Information
25225 Detroit Road (440) 835-7368
Westlake, OH 44145 (800) 383-7323 (USA)
Date Prepared: October 17, 2001


5

SECTION II - HAZARDOUS INGREDIENTS


IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within
or their combustion products could be harmful.


MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt.

Graphite 1-3
15 mg/m3 TWA (total 2 mg/m3 TWA (respirable
(CAS# 7782-42-5) dust) fraction)
5 mg/m3 TWA (respirable
fraction)

Manganese Dioxide 15-30
5 mg/m3 Ceiling (as Mn) 0.2 mg/m3 TWA (as Mn)
(CAS# 1313-13-9)

Mercury 0.1-0.9
0.1 mg/m3 Ceiling (as Hg) 0.025 mg/m3 TWA (as Hg:
(CAS# 7439-97-6) elemental and inorganic
compounds)




ftp://MSDSMAINT:7s6d5f4sd3@www.swe.com/EVEREADY/alkaline_miniature.html 12/7/2007
MINIATURE PRODUCT SAFETY DATA SHEET Page 2 of 4



Potassium Hydroxide None established 0-12
2 mg/m3 Ceiling
(CAS# 1310-58-3)

Sodium Hydroxide 0-12
2 mg/m3 TWA 2 mg/m3 Ceiling
(CAS# 1310-73-2)




MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt.

Zinc 4-10
15 mg/m3 TWA 10 mg/m3 TWA
(CAS# 7440-66-6) (particulates not otherwise (particulates not otherwise
regulated-total dust) classified-inhalable)
5 mg/m3 TWA 3 mg/m3 TWA (particulates
(particulates not otherwise not otherwise classified-
regulated-respirable respirable)
fraction)


5

SECTION III - FIRE AND EXPLOSION HAZARD DATA


In case of fire, it is permissible to use any class of extinguishing medium on these batteries or their packing
material. Cool exterior of batteries if exposed to fire to prevent rupture.

Fire fighters should wear self-contained breathing apparatus. Battery contains mercury which produces highly
toxic mercury vapors under fire conditions.

5

SECTION IV - HEALTH HAZARD DATA


Under normal conditions of use, the battery is hermetically sealed.

Ingestion: Swallowing a battery can be harmful.

Contents of an open battery can cause serious chemical burns of mouth, esophagus,
and gastrointestinal tract. Contents include mercury which can cause abdominal pain,
vomiting, diarrhea, liver and kidney damage, and central nervous system disorders.

If battery or open battery is ingested, do not induce vomiting or give food or drink.
Seek medical attention immediately. CALL NATIONAL BATTERY INGESTION
HOTLINE for advice and follow-up (202-625-3333) collect, day or night.

Inhalation: Contents of an open battery can cause respiratory irritation. Provide fresh
air and seek medical attention.

Skin Absorption: Mercury can be absorbed through intact skin causing symptoms
similar to those of ingestion.




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MINIATURE PRODUCT SAFETY DATA SHEET Page 3 of 4



Skin Contact: Contents of an open battery can cause skin irritation and/or chemical
burns. Remove contaminated clothing and wash skin with soap and water. If a
chemical burn occurs or if irritation persists, seek medical attention.

Eye Contact: Contents of an open battery can cause severe irritation and chemical
burns. Immediately flush eyes thoroughly with water for at least 15 minutes, lifting
upper and lower lids, until no evidence of the chemical remains. Seek medical
attention.

5

SECTION V - PRECAUTIONS FOR SAFE HANDLING AND USE


Storage: Store in a cool, well ventilated area. Elevated temperatures can result in
shortened battery life.

Mechanical Containment: If potting or sealing the battery in an airtight or watertight
container is required, consult your Eveready Battery Company representative for
precautionary suggestions. Batteries normally evolve hydrogen which, when combined
with oxygen from the air, can produce a combustible or explosive mixture unless
vented. If such a mixture is present, short circuits, high temperature, or static sparks
can cause an ignition.

Do not obstruct safety release vents on batteries. Encapsulation (potting) of batteries
will not allow cell venting and can cause high pressure rupture.

Handling: Accidental short circuit for a few seconds will not seriously affect the
battery. Prolonged short circuit will cause the battery to lose energy, and can cause
the safety release vent to open. Sources of short circuits include jumbled batteries in
bulk containers, metal jewelry, metal covered tables or metal belts used for assembly
of batteries into devices.

If soldering or welding to the battery is required, consult your Eveready Battery
Company representative for proper precautions to prevent seal damage or short
circuit.

Charging: This battery is manufactured in a charged state. It is not designed for
recharging. Recharging can cause battery leakage or, in some cases, high pressure
rupture. Inadvertent charging can occur if a battery is installed backwards.

Labeling: If the Eveready label or package warnings are not visible, it is important to
provide a package and/or device label stating:

WARNING: DO NOT DISPOSE OF IN FIRE, RECHARGE, PUT IN
BACKWARDS, MIX WITH USED OR OTHER BATTERY TYPES - MAY
EXPLODE OR LEAK AND CAUSE PERSONAL INJURY.

Where accidental ingestion of small batteries is possible, the label should include:

WARNING: (1) KEEP AWAY FROM SMALL CHILDREN. IF
SWALLOWED, PROMPTLY SEE DOCTOR; HAVE DOCTOR PHONE
(202) 625-3333 COLLECT. (2) DO NOT DISPOSE OF IN FIRE,
RECHARGE, PUT IN BACKWARDS, MIX WITH USED OR OTHER
BATTERY TYPES - MAY EXPLODE OR LEAK AND CAUSE
PERSONAL INJURY.




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MINIATURE PRODUCT SAFETY DATA SHEET Page 4 of 4



Disposal: Dispose in accordance with all applicable federal, state and local
regulations. Appropriate disposal technologies include incineration and landfilling.

The contents of this battery, as a waste, may be regulated by Resource Conservation
and Recovery Act (RCRA) as a D009 (mercury) hazardous waste.

5

SECTION VI - SPECIAL PROTECTION INFORMATION


Ventilation Requirements: Not necessary under normal conditions.

Respiratory Protection: Not necessary under normal conditions.

Eye Protection: Not necessary under normal conditions. Wear safety glasses with
side shields if handling an open or leaking battery.

Gloves: Not necessary under normal conditions. Use neoprene or natural rubber
gloves if handling an open or leaking battery.

5

SECTION VII - REGULATORY INFORMATION


The transportation of dry cell batteries manufactured or sold by Eveready Battery Company is not regulated by
the U.S. Department of Transportation or the major international regulatory bodies.

SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency
Planning and Community Right-To-Know Act.




ftp://MSDSMAINT:7s6d5f4sd3@www.swe.com/EVEREADY/alkaline_miniature.html 12/7/2007

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