MATERIAL SAFETY DATA SHEET
LEAD ACID BATTERY
Springfield, Missouri
I. PRODUCT IDENTIFICATION:
A. Chemical/Trade Name (per on label): Lead Acid Battery
B. Chemical Family/Classification: Electrical Storage Battery
C. Manufacturer鈥檚 Name & Address: NorthStar Battery Co. LLC
4000 Continental Way
Springfield, MO 65803
D. Contact: U.S. - NSB Safety and Health Department
Phone: (417) 575-8211
Fax: (417) 575-8250
Aust. Power-One Energy Solutions Pty Ltd.
Phone: +612 9889 3111
E. Chemtrec (US, Canada & Mexico)
Emergency Information:
Phone: (800) 424-9300
Chemtrec (Outside US, Canada & Mexico)
Phone: +1 (703) 527-3887 (call collect)
F. Non-Hazardous Classification
Per US DOT, Northstar Battery Company products, submitted and tested by Wyle Labs,
have been deemed to meet all requirements as specified in 49CFR搂 173.159 (d) for
exception as hazardous material classification.
II. HAZARDOUS INGREDIENTS/IDENTITY INFORMATION:
NORTH AMERICAN INFORMATION
3
Air Exposure Limits (ug/m )
Materials % by Wt. CAS Number OSHA AGGIH (TLV) NIOSH
Lead 57 7439-92-1 50 150 100
Lead Oxide 22 1309-60-0 50 150 100
Electrolyte (Sulfuric Acid) 14 7664-93-9 1 1 1
AUSTRALIAN INFORMATION
Chemical or Material Australian Dangerous Goods Hazardous Substance Australian Poison Schedule
Classification Classification as per NOHSC Classification
Australia
Non-Spillable Exempt under A67 (NATA R34/R41 Schedule 6
Lead Acid Battery Identification Guide) and Clause 238 Agricultural, Domestic and Industrial
of the Australian Dangerous Goods Substances
Code, Appendix 3
Note: Product contains toxic chemicals that are subject to the reporting requirements of Section
302 and 313 of the Emergency Planning and Community Right-to-Know Act of 1986.
III. PHYSICAL DATA:
Material is solid at normal temperatures.
A. Electrolyte:
1. 1.250 鈥? 1.350 kg/dm3
Specific Gravity:
2. Boiling Point: 110掳C (230掳F)
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MATERIAL SAFETY DATA SHEET
LEAD ACID BATTERY
Springfield, Missouri
3. % Volatiles By Weight: Not Applicable
4. Solubility in Water: 100%
5. Melting Point Lead: 327掳C (621掳F)
6. Vapor Density Not Determined
B. Appearance and Odor
1. Electrolyte is a clear liquid with an acidic odor.
IV. HEALTH HAZARD INFORMATION:
Under normal operating conditions, because the battery is 鈥渘on-spillable鈥?, the internal material will
not be hazardous to your health. Only internally exposed material during production or case
breakage or extreme heat (fire) may be hazardous to your health.
A. Routes of Entry:
1. Inhalation: Acid mist from formation process may cause respiratory irritation.
2. Skin Contact: Acid may cause irritation, burns and/or ulceration.
3. Skin Absorption Not a significant route of entry.
4. Eye Contact: Acid may cause sever irritation, burns, cornea damage and/or
blindness.
5. Ingestion: Acid may cause irritation of mouth, throat, esophagus and stomach.
B. Signs and Symptoms of Over Exposure:
1. Acute Effects: Over exposure to lead may lead to loss of appetite, constipation,
sleeplessness and fatigue. Over exposure to acid may lead to skin irritation,
corneal damage of the eyes and upper respiratory system.
2. Chronic Effects: Lead and its components may cause damage to kidneys and
nervous system. Acid and its components may cause lung damage and
pulmonary conditions.
3. Potential to Cause Cancer: The International Agency for Research on Cancer
has classified "strong inorganic acid mist containing sulfuric acid" as a Category
1 carcinogen, a substance that is carcinogenic to humans. This classification
does not apply to liquid forms of sulfuric acid or sulfuric acid solutions contained
within a battery. Inorganic acid mist is not generated under normal use of this
product. Misuse of the product, such as overcharging, may however result in the
generation of sulfuric acid mist.
C. Emergency and First Aid Procedures:
1. Inhalation: Remove from exposure, move to fresh air, and apply oxygen if
breathing is difficult. Consult physician immediately.
2. Skin: Wash with plenty of soap and water for at least 15 minutes. Remove any
contaminated clothing. Consult physician if skin irritation appears.
3. Eyes: Flush with plenty of water immediately for at least 15 minutes, lifting lower
and upper eyelids occasionally. Consult a physician immediately.
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MATERIAL SAFETY DATA SHEET
LEAD ACID BATTERY
Springfield, Missouri
4. Ingestion: Do not induce vomiting. Give large quantities of water. Never give
anything by mouth to an unconscious person. Consult a physician immediately.
D. HANDLING AND STORAGE
1. Safe Storage: Store in a cool, dry place in closed containers. Keep away from
ignition sources and high temperatures.
1. Contact NorthStar Battery Company (417-575-8200) for shelf life information.
2. Handling: Avoid skin or eye contact. Avoid breathing vapors. Do not use near
sources of ignition
V. CARCINOGENICITY: See section IV, Part B "Signs and Symptoms of Over Exposure"
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: See section IV, Part B "Signs and
Symptoms of Over Exposure"
VI. FIRE AND EXPLOSION HAZARD DATA:
A. Flash Point: Hydrogen = 259掳C
B. Auto ignition Temperature: Hydrogen = 580掳C
C. Extinguishing Media: Dry chemical, foam, CO2
D. Unusual Fire and Explosion Hazards: Hydrogen and oxygen gases are produced in the
cells during normal battery operation (hydrogen is flammable and oxygen supports
combustion). These gases enter the air through the vent caps. To avoid the chance of a
fire or explosion, keep sparks and other sources of ignition away from the battery.
E. Firefighting PPE: Full protective clothing and
NIOSH-approved self-contained breathing apparatus
with full facepiece
VII. REACTIVITY DATA:
A. Stability: Stable
B. Conditions to Avoid: Sparks and other sources of ignition.
C. Incompatibility: (materials to avoid)
1. Lead/lead compounds: Potassium, carbides, sulfides, peroxides, phosphorus,
sulfur.
2. Battery electrolyte (acid): Combustible materials, strong reducing agents,
most metals, carbides, organic materials, chlorates, nitrates, picrates, and
fulminates.
D. Hazardous Decomposition Products:
1. Lead/lead compounds: Oxides of lead and sulfur.
2. Battery electrolyte (acid): Hydrogen, sulfur dioxide, and sulfur trioxide.
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MATERIAL SAFETY DATA SHEET
LEAD ACID BATTERY
Springfield, Missouri
E. Conditions to Avoid:
High temperature. Battery electrolyte (acid) will react with water to produce heat. Can
react with oxidizing or reducing agents.
VIII. CONTROL MEASURES:
A. Engineering Controls:
Store lead/acid batteries with adequate ventilation. Room ventilation is required for
batteries utilized for standby power generation. Never recharge batteries in an
unventilated, enclosed space.
B. Work Practices:
Do not remove vent covers. Follow shipping and handling instructions which are
applicable to the battery type. To avoid damage to terminals and seals, do not double-
stack industrial batteries.
C. Personal Protective Equipment:
1. Respiratory Protection: None required under normal handling conditions. During
battery formation (high-rate charge condition), acid mist can be generated which
may cause respiratory irritation. Also, if acid spillage occurs in a confined space,
exposure may occur. If irritation occurs, wear a respirator suitable for protection
against acid mist.
2. Eyes and Face: Chemical splash goggles are preferred. Also acceptable are
"visor-gogs" or a chemical face shield worn over safety glasses.
3. Hands, Arms, Body: Vinyl coated, VC, gauntlet type gloves with rough finish are
preferred.
4. Other Special Clothing and Equipment: Safety shoes are recommended when
handling batteries. All footwear must meet requirements of ANSI Z41.1 -Rev.
1972.
IX. ACCIDENTAL RELEASE MEASURES:
A. Not applicable under normal conditions.
B. In case of damage resulting in breakage of the battery container, see VIII, Sec. C
Personal Protective Equipment.
X. PRECAUTIONS FOR SAFE HANDLING AND USE:
A. Hygiene Practices: Following contact with internal battery components, wash hands
thoroughly before eating, drinking, or smoking.
B. Respiratory Protection: Wear safety glasses. Do not permit flames or sparks in the
vicinity of battery(s). If battery electrolyte (acid) comes in contact with clothing, discard
clothing.
C. Protective Measures:
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MATERIAL SAFETY DATA SHEET
LEAD ACID BATTERY
Springfield, Missouri
1. Remove combustible materials and all sources of ignition. Cover spills with soda
ash (sodium carbonate) or quicklime (calcium oxide). Mix well. Make certain
mixture is neutral, then collect residue and place in a drum or other suitable
container. Dispose of as hazardous waste.
2. Wear acid-resistant boots, chemical face shield, chemical splash goggles, and
acid-resistant gloves. Do not release unneutralized acid.
D. Waste Disposal Method (*):
1. Battery electrolyte (acid): Neutralize as above for a spill, collect residue, and
place in a drum or suitable container. Dispose of as hazardous waste.
2. Do not flush lead contaminated acid to sewer.
3. In case of accidental spill, utilize personal protective equipment, i.e., face shield,
rubber apron, rubber safety shoes.
4. Batteries: Send to lead smelter for reclamation following applicable Federal,
State and local regulations. Product can be recycled along with automotive (SLI)
lead acid batteries.
5. Battery may be returned, shipping pre-paid, to the manufacturer or any distributor
for recycling. See 1.C for manufacturers address of visit our web site @
www.northstarbattery.com.
*In accordance to Local, State and Federal regulations and laws.
E. Other Handling and Storage Precautions: None Required.
XI. ECOLOGICAL INFORMATION:
Lead and its compounds can pose a threat if released to the environment.
See Waste Disposal Method in Section X, Part D.
XII. NFPA HAZARD RATING: SULFURIC ACID:
Flammability (Red) = 0
Health (Blue) = 3
Reactivity (Yellow) = 2
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MATERIAL SAFETY DATA SHEET
LEAD ACID BATTERY
Springfield, Missouri
XIII. DEPARTMENT OF TRANSPORTATION AND INTERNATIONAL SHIPPING REGULATIONS:
Proper Shipping
UN2800 - Battery, wet, non-spillable (electric storage)
Name
Batteries must be packed to protect against short circuits and firmly secured to skids or pallets.
IATA
Packaging instruction 806 Not restricted per special provision A67.
Northstar Battery Company products, submitted and tested by Wyle Labs, have been deemed to
US DOT meet all requirements as specified in 49CFR搂 173.159 (d) for exception as hazardous material
classification.
Northstar Battery Company products, submitted and tested by Wyle Labs, have been deemed to
IMDG meet all requirements as specified in special provision 238 for determination of 鈥淣on-Spillable鈥? and
are not subject to the provision of this Code.
XIV. SPECIAL REQUIREMENTS:
TLV
Sulfuric Acid - Occupation Exposure Limit - AUSTRALIA TWA 1mg/m3,JAN1993
Lead - Occupation Exposure Limit - AUSTRALIA TWA 0.15 mg/m3, 2002
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