**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| Not available |Tris-Hydroxymethyl Amino Methane | <2.0 | unlisted |
|----------------|--------------------------------------|----------|-----------|
| 56-81-5 |Glycerine | 8.3 | 200-289-5 |
|----------------|--------------------------------------|----------|-----------|
| 67-56-1 |Methanol | 83-88 | 200-659-6 |
|----------------|--------------------------------------|----------|-----------|
| 110-16-7 |Maleic acid | <2 | 203-742-5 |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 506-59-2 |Dimethylamine hydrochloride | <1.0 | 208-046-5 |
|----------------|--------------------------------------|----------|-----------|
| 531-53-3 | Giemsa Stain Azure A | <1.0 | 208-510-7 |
|----------------|--------------------------------------|----------|-----------|
| 660-68-4 |Diethylamine hydrochloride | <1.0 | 211-541-9 |
|----------------|--------------------------------------|----------|-----------|
| 1310-58-3 |Potassium hydroxide | 0.2 | 215-181-3 |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 9002-93-1 |Ethoxylated p-tert-octylphenol | <1 | unlisted |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 68988-92-1 |Wright Stain | 0.4 | 273-541-5 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN C
Risk Phrases: 10 22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. Vapors may cause eye irritation. May cause
painful sensitization to light.
Skin:
Causes skin burns. May be absorbed through the skin in harmful
amounts. Maleic acid passes through intact skin.
Ingestion:
May be fatal or cause blindness if swallowed. May cause
gastrointestinal irritation with nausea, vomiting and diarrhea. May
cause systemic toxicity with acidosis. May cause liver and kidney
damage. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation. May
cause liver and kidney damage. May cause visual impairment and
possible permanent blindness. May cause effects similar to those
described for ingestion. May cause narcotic effects in high
concentration. May cause drowsiness, unconsciousness, and central
nervous system depression.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
inhalation and ingestion may cause effects similar to those of acute
inhalation and ingestion.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Flammable liquid and vapor. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. May be ignited by heat, sparks, and flame. Containers
may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water. For large fires, use dry chemical, carbon dioxide,
alcohol-resistant foam, or water spray. Cool containers with
flooding quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Remove all sources of ignition. Absorb spill using an absorbent,
non-combustible material such as earth, sand, or vermiculite. Do not
use combustible materials such as sawdust. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors. Water spray may
reduce vapor but may not prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Ground and bond containers when
transferring material. Do not get in eyes, on skin, or on clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep container tightly closed. Keep away from
heat, sparks and flame. Do not ingest or inhale. Use only in a
chemical fume hood. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits. Use only under a chemical fume hood.
Exposure Limits
CAS# 0-00-0:
CAS# 56-81-5:
United Kingdom, WEL - TWA: 10 mg/m3 TWA (mist)
United Kingdom, WEL - STEL: 30 mg/m3 STEL (mist)
United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA
(respirable fraction)
Belgium - TWA: 10 mg/m3 VLE (mist)
France - VME: 10 mg/m3 VME
Malaysia: 10 mg/m3 TWA (mist)
Netherlands: 10 mg/m3 MAC (mist)
Spain: 10 mg/m3 VLA-ED
CAS# 67-56-1:
United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA
United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL
United States OSHA: 200 ppm TWA; 260 mg/m3 TWA
Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE
Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE
France - VME: 200 ppm VME; 260 mg/m3 VME
France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE
Germany: 200 ppm TWA; 270 mg/m3 TWA
Germany: Skin absorber
Japan: 200 ppm OEL; 260 mg/m3 OEL
Malaysia: 200 ppm TWA; 262 mg/m3 TWA
Netherlands: 200 ppm MAC; 260 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED
Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC
CAS# 110-16-7:
CAS# 124-40-3:
United Kingdom, WEL - TWA: 2 ppm TWA; 3.8 mg/m3 TWA
United Kingdom, WEL - STEL: 6 ppm STEL; 11 mg/m3 STEL
United States OSHA: 10 ppm TWA; 18 mg/m3 TWA
Belgium - TWA: 2 ppm VLE; 3.8 mg/m3 VLE
Belgium - STEL: 5 ppm VLE; 9.4 mg/m3 VLE
France - VLE: 10 ppm VLE; 18 mg/m3 VLE
Germany: 2 ppm TWA; 3.7 mg/m3 TWA
Japan: 10 ppm OEL; 18 mg/m3 OEL
Malaysia: 5 ppm TWA; 9.2 mg/m3 TWA
Netherlands: 1 ppm MAC; 1.8 mg/m3 MAC
Russia: 1 mg/m3 TWA
Spain: 2 ppm VLA-ED; 3.8 mg/m3 VLA-ED
Spain: 5 ppm VLA-EC; 9.4 mg/m3 VLA-EC
CAS# 506-59-2:
CAS# 531-53-3:
CAS# 660-68-4:
CAS# 1310-58-3:
United Kingdom, WEL - STEL: 2 mg/m3 STEL
Belgium - STEL: 2 mg/m3 VLE
France - VLE: 2 mg/m3 VLE
Japan: 2 mg/m3 Ceiling
Malaysia: 2 mg/m3 Ceiling
Spain: 2 mg/m3 VLA-EC
CAS# 7447-40-7:
Russia: 5 mg/m3 TWA
CAS# 9002-93-1:
CAS# 10237-70-4:
CAS# 68988-92-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: dark blue
Odor: Alcohol
pH: Not available.
Vapor Pressure: 96 mm Hg
Viscosity: Not available.
Boiling Point: 66 deg C
Freezing/Melting Point: -98 deg C
Autoignition Temperature: Not available.
Flash Point: 54 deg F ( 12.22 deg C)
Explosion Limits, lower: 6.0
Explosion Limits, upper: 36.0
Decomposition Temperature:
Solubility in water: Infinite
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
The incompatibilties associated with potassium hydroxide include:
acids, bromoform, chlorine dioxide, cyclopentadiene, germanium,
hyponitrous acid, maleic anhydride, nitroalkanes, nitrobenzene,
nitrogen trichloride, 2-nitrophenol, potassium peroxodisulfate,
sugars, 2,2,3,3-tetrafluoropropanol, tetrahydrofuran, thorium
dicarbide, 2,4,6trinitrotoluene, acetic acid, acrolein,
acrylonitrile, chlorine+hydrogen peroxide, chloroform+methanol,
phosphorus, trichloroethylene, tetrachlorethane. It reacts violently
with o-nitrophenol. Reactions with 1,2-dichloroethylene produce
chloroacetylene which is explosive and spontaneously flammable in
air. Potassium hydroxide generates large amounts of heat when in
contact with water and may steam and splatter. Potassium hydroxide is
corrosive to metals such as aluminum, tin, and zinc to cause
formation of flammable hydrogen gas. The incompatibilities
associated with glycerol include: acetic anhydride, calcium
hypochlorite, chromium oxide, fluorine+lead oxide, perchloric
acid+lead oxide, and potassium permanganate. Wright's stain is
incompatible with strong oxidizing agents. The incompatibilities
associated with methanol include: oxidants, phosphorus (III) oxide,
dichloromethane, acetyl bromide, active metals, alkyl aluminum salts,
beryllium dihydride, carbon tetrachloride+metals, chloroform+heat,
chloroform+sodium hydroxide, cyanuric chloride, diethyl zinc,
potassium tertbutoxide, chromic anhydride, lead perchlorate,
perchloric acid, and chloroform+potassium hydroxide. Maleic acid is
incompatible with oxidizing agents, strong bases, and alkali metals.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide, oxides of
carbon.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 0-00-0 unlisted.
CAS# 56-81-5: MA8050000
CAS# 67-56-1: PC1400000
CAS# 110-16-7: OM9625000
CAS# 124-40-3: IP8750000
CAS# 506-59-2: IQ0220000
CAS# 531-53-3: SP5660000
CAS# 660-68-4: IA3084000
CAS# 1310-58-3: TT2100000
CAS# 7447-40-7: TS8050000
CAS# 9002-93-1: MD0907700 YM0616666 YM0683332
CAS# 10237-70-4 unlisted.
CAS# 68988-92-1 unlisted.
LD50/LC50:
Not available.
CAS# 56-81-5: Draize test, rabbit, eye: 126 mg Mild; Draize test,
rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H
Mild; Inhalation, rat: LC50 = >570 mg/m3/1H; Oral, mouse: LD50 =
4090 mg/kg; Oral, rabbit: LD50 = 27 gm/kg; Oral, rat: LD50 = 12600
mg/kg; Skin, rabbit: LD50 = >10 gm/kg.
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test,
rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20
mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H;
Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300
mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600
mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 110-16-7: Draize test, rabbit, eye: 100 mg Severe; Draize test,
rabbit, eye: 1%/2M Severe; Draize test, rabbit, skin: 500 mg/24H
Mild; Inhalation, rat: LC50 = >720 mg/m3/1H; Oral, mouse: LD50 =
2400 mg/kg; Oral, rat: LD50 = 708 mg/kg; Skin, rabbit: LD50 = 1560
mg/kg.
CAS# 124-40-3: Draize test, rabbit, eye: 50 mg/5M; Inhalation,
mouse: LC50 = 4725 ppm/2H; Inhalation, rat: LC50 = 4540 ppm/6H; Oral,
mouse: LD50 = 316 mg/kg; Oral, rabbit: LD50 = 240 mg/kg; Oral, rat:
LD50 = 698 mg/kg.
CAS# 506-59-2: Oral, mouse: LD50 = 8100 mg/kg; Oral, rabbit: LD50 =
1600 mg/kg; Oral, rat: LD50 = 1070 mg/kg.
CAS# 531-53-3.
CAS# 660-68-4: Oral, mouse: LD50 = 4860 mg/kg; Oral, rat: LD50 =
9900 mg/kg.
CAS# 1310-58-3: Draize test, rabbit, skin: 50 mg/24H Severe; Oral,
rat: LD50 = 273 mg/kg.
CAS# 7447-40-7: Draize test, rabbit, eye: 500 mg/24H Mild; Oral,
mouse: LD50 = 1500 mg/kg; Oral, rat: LD50 = 2600 mg/kg.
CAS# 9002-93-1: Draize test, rabbit, eye: 10 uL/24H Moderate; Draize
test, rabbit, skin: 500 uL/24H Mild; Oral, rat: LD50 = 1800 mg/kg;
Oral, rat: LD50 = 3800 mg/kg; Oral, rat: LD50 = 1900 mg/kg.
CAS# 10237-70-4.
CAS# 68988-92-1.
Carcinogenicity:
Tris-Hydroxymethyl Amino Methane -
Not listed by ACGIH, IARC, or NTP.
Glycerine -
Not listed by ACGIH, IARC, or NTP.
Methanol -
Not listed by ACGIH, IARC, or NTP.
Maleic acid -
Not listed by ACGIH, IARC, or NTP.
Dimethylamine -
Not listed by ACGIH, IARC, or NTP.
Dimethylamine hydrochloride -
Not listed by ACGIH, IARC, or NTP.
Giemsa Stain Azure A -
Not listed by ACGIH, IARC, or NTP.
Diethylamine hydrochloride -
Not listed by ACGIH, IARC, or NTP.
Potassium hydroxide -
Not listed by ACGIH, IARC, or NTP.
Potassium chloride -
Not listed by ACGIH, IARC, or NTP.
Ethoxylated p-tert-octylphenol -
Not listed by ACGIH, IARC, or NTP.
2-butenedioic acid (z)-, potassium salt -
Not listed by ACGIH, IARC, or NTP.
Wright Stain -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ
USA RQ: CAS# 110-16-7: 5000 lb final RQ; 2270 kg final RQ
USA RQ: CAS# 124-40-3: 1000 lb final RQ; 454 kg final RQ
USA RQ: CAS# 1310-58-3: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN C
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 28B After contact with skin, wash immediately with
plenty of water and soap.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 0-00-0: No information available.
CAS# 56-81-5: 0
CAS# 67-56-1: 1
CAS# 110-16-7: 1
CAS# 124-40-3: 2
CAS# 506-59-2: 1
CAS# 531-53-3: No information available.
CAS# 660-68-4: 1
CAS# 1310-58-3: 1
CAS# 7447-40-7: 1
CAS# 9002-93-1: 1
CAS# 10237-70-4: 1
CAS# 68988-92-1: No information available.
Canada
CAS# 56-81-5 is listed on Canada's DSL List.
CAS# 67-56-1 is listed on Canada's DSL List.
CAS# 110-16-7 is listed on Canada's DSL List.
CAS# 124-40-3 is listed on Canada's DSL List.
CAS# 506-59-2 is listed on Canada's DSL List.
CAS# 531-53-3 is listed on Canada's DSL List.
CAS# 660-68-4 is listed on Canada's DSL List.
CAS# 1310-58-3 is listed on Canada's DSL List.
CAS# 7447-40-7 is listed on Canada's DSL List.
CAS# 9002-93-1 is listed on Canada's DSL List.
CAS# 10237-70-4 is listed on Canada's DSL List.
CAS# 68988-92-1 is listed on Canada's DSL List.
CAS# 0-00-0 is not listed on Canada's Ingredient Disclosure List.
CAS# 56-81-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 67-56-1 is listed on Canada's Ingredient Disclosure List.
CAS# 110-16-7 is listed on Canada's Ingredient Disclosure List.
CAS# 124-40-3 is listed on Canada's Ingredient Disclosure List.
CAS# 506-59-2 is not listed on Canada's Ingredient Disclosure List.
CAS# 531-53-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 660-68-4 is not listed on Canada's Ingredient Disclosure List.
CAS# 1310-58-3 is listed on Canada's Ingredient Disclosure List.
CAS# 7447-40-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 9002-93-1 is listed on Canada's Ingredient Disclosure List.
CAS# 10237-70-4 is not listed on Canada's Ingredient Disclosure List.
CAS# 68988-92-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 0-00-0 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 56-81-5 is listed on the TSCA inventory.
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 110-16-7 is listed on the TSCA inventory.
CAS# 124-40-3 is listed on the TSCA inventory.
CAS# 506-59-2 is listed on the TSCA inventory.
CAS# 531-53-3 is listed on the TSCA inventory.
CAS# 660-68-4 is listed on the TSCA inventory.
CAS# 1310-58-3 is listed on the TSCA inventory.
CAS# 7447-40-7 is listed on the TSCA inventory.
CAS# 9002-93-1 is listed on the TSCA inventory.
CAS# 10237-70-4 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 68988-92-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin and
if swallowed.
R 39/23/24/25 Toxic : danger of very serious irreversible
effects through inhalation, in contact with skin and if swallowed.
MSDS Creation Date: 5/21/1998 Revision #5 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|