**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| | | | unlisted |
|----------------|--------------------------------------|----------|-----------|
| Not available |Potassium oleate | 0.068 | unlisted |
|----------------|--------------------------------------|----------|-----------|
| 56-81-5 |Glycerol | 0.875 | 200-289-5 |
|----------------|--------------------------------------|----------|-----------|
| 64-17-5 |Ethanol | 45.0 | 200-578-6 |
|----------------|--------------------------------------|----------|-----------|
| 67-56-1 |Methanol | 2.5 | 200-659-6 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 52.5 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: F
Risk Phrases: 10
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
No information regarding skin irritation and other potential effects
was found.
Ingestion:
Harmful if swallowed. The toxicological properties of this substance
have not been fully investigated.
Inhalation:
No information available.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation
develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable Liquid. Can release vapors that form
explosive mixtures at temperatures above the flashpoint.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep from contact with oxidizing materials. Store in a
cool, dry, well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# :
United Kingdom, WEL - TWA: (listed as tellurium): 0.1 mg/m3 TWA
United Kingdom, WEL - STEL: (listed as tellurium): 0.3 mg/m3 STEL
United States OSHA: 0.1 mg/m3 TWA (listed under Tellurium).
Belgium - TWA: (listed as tellurium): 0.1 mg/m3 VLE
France - VME: (listed as tellurium): 0.1 mg/m3 VME
Germany: (listed as tellurium): 0.1 mg/m3 VME
Malaysia: (listed as tellurium): 0.1 mg/m3 TWA
Netherlands: (listed as tellurium): 0.1 mg/m3 MAC
Russia: (listed as tellurium): 0.01 mg/m3 TWA
Spain: (listed as tellurium): 0.1 mg/m3 VLA-ED
CAS# 0-00-0:
CAS# 56-81-5:
United Kingdom, WEL - TWA: 10 mg/m3 TWA (mist)
United Kingdom, WEL - STEL: 30 mg/m3 STEL (mist)
United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA
(respirable fraction)
Belgium - TWA: 10 mg/m3 VLE (mist)
France - VME: 10 mg/m3 VME
Malaysia: 10 mg/m3 TWA (mist)
Netherlands: 10 mg/m3 MAC (mist)
Spain: 10 mg/m3 VLA-ED
CAS# 64-17-5:
United Kingdom, WEL - TWA: 1000 ppm TWA; 1920 mg/m3 TWA
United Kingdom, WEL - STEL: 3000 ppm STEL; 5760 mg/m3 STEL
United States OSHA: 1000 ppm TWA; 1900 mg/m3 TWA
Belgium - TWA: 1000 ppm VLE; 1907 mg/m3 VLE
France - VME: 1000 ppm VME; 1900 mg/m3 VME
France - VLE: 5000 ppm VLE; 9500 mg/m3 VLE
Germany: 500 ppm TWA; 960 mg/m3 TWA
Malaysia: 1000 ppm TWA; 1880 mg/m3 TWA
Netherlands: 500 ppm MAC; 1000 mg/m3 MAC
Russia: 1000 mg/m3 TWA
Spain: 1000 ppm VLA-ED; 1910 mg/m3 VLA-ED
CAS# 67-56-1:
United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA
United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL
United States OSHA: 200 ppm TWA; 260 mg/m3 TWA
Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE
Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE
France - VME: 200 ppm VME; 260 mg/m3 VME
France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE
Germany: 200 ppm TWA; 270 mg/m3 TWA
Germany: Skin absorber
Japan: 200 ppm OEL; 260 mg/m3 OEL
Malaysia: 200 ppm TWA; 262 mg/m3 TWA
Netherlands: 200 ppm MAC; 260 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED
Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Not available.
Hazardous Polymerization:
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# unlisted.
CAS# 0-00-0 unlisted.
CAS# 56-81-5: MA8050000
CAS# 64-17-5: KQ6300000
CAS# 67-56-1: PC1400000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
Not available.
CAS# 56-81-5: Draize test, rabbit, eye: 126 mg Mild; Draize test,
rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H
Mild; Inhalation, rat: LC50 = >570 mg/m3/1H; Oral, mouse: LD50 =
4090 mg/kg; Oral, rabbit: LD50 = 27 gm/kg; Oral, rat: LD50 = 12600
mg/kg; Skin, rabbit: LD50 = >10 gm/kg.
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test,
rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H
Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat:
LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit:
LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 =
9000 mg/kg.
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test,
rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20
mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H;
Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300
mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600
mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
-
Not listed by ACGIH, IARC, or NTP.
Potassium oleate -
Not listed by ACGIH, IARC, or NTP.
Glycerol -
Not listed by ACGIH, IARC, or NTP.
Ethanol -
Not listed by ACGIH, IARC, or NTP.
Methanol -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ETHANOL SOLUTION
Hazard Class: 3
UN Number: 1170
Packing Group: II
IMO
Shipping Name: ETHANOL SOLUTION
Hazard Class: 3
UN Number: 1170
Packing Group: II
RID/ADR
Shipping Name: ETHANOL SOLUTION
Hazard Class: 3
UN Number: 1170
Packing group: II
USA RQ: CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 25 Avoid contact with eyes.
WGK (Water Danger/Protection)
CAS# : No information available.
CAS# 0-00-0: No information available.
CAS# 56-81-5: 0
CAS# 64-17-5: 0
CAS# 67-56-1: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 56-81-5 is listed on Canada's DSL List.
CAS# 64-17-5 is listed on Canada's DSL List.
CAS# 67-56-1 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# is not listed on Canada's Ingredient Disclosure List.
CAS# 0-00-0 is not listed on Canada's Ingredient Disclosure List.
CAS# 56-81-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 64-17-5 is listed on Canada's Ingredient Disclosure List.
CAS# 67-56-1 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 0-00-0 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 56-81-5 is listed on the TSCA inventory.
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin and
if swallowed.
R 39/23/24/25 Toxic : danger of very serious irreversible
effects through inhalation, in contact with skin and if swallowed.
MSDS Creation Date: 12/12/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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