**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 100-23-2 |Benzenamine, N,N-Dimethyl-4-Nitro- | ca 100 | 202-832-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation and in contact with skin. Danger of cumulative
effects.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. Methemoglobinemia is
characterized by dizziness, drowsiness, headache, shortness of
breath, cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood), rapid heart rate and chocolate-brown
colored blood. Overexposure may cause methemoglobinemia. May be
harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Methemoglobinemia is
characterized by dizziness, drowsiness, headache, shortness of
breath, cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood), rapid heart rate and chocolate-brown
blood. Inhalation of aniline causes anoxia due to the formation of
methemoglobin.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose
upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. Use water spray, dry chemical, carbon
dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 100-23-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: bright yellow
Odor: aniline-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 163.00 - 165.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H10N2O2
Molecular Weight: 166.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-23-2: BX7035000
LD50/LC50:
Not available.
Carcinogenicity:
Benzenamine, N,N-Dimethyl-4-Nitro- -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24 Toxic by inhalation and in contact with
skin.
R 33 Danger of cumulative effects.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 37 Wear suitable gloves.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 100-23-2: No information available.
Canada
CAS# 100-23-2 is listed on Canada's NDSL List.
CAS# 100-23-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-23-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
M-Benzyloxybenzyl Alcohol , 97%
| 1700-30-7 |
|
Octaphenylcyclotetrasiloxane, 98%
| 546-56-5 |
|
Cetylpyridinium chloride
| 123-03-5 |
|
3,4-Difluorophenol, 99%
| 2713-33-9 |
|
1-Benzyl-4-Hydroxypiperidine, 97%
| 4727-72-4 |
|
4-tert-Butylbenzoyl chloride
| 1710-98-1 |
|
Borane-morpholine complex, 97%
| 4856-95-5 |
|
Benzyl Ether, 99%
| 103-50-4 |
|
5-Amino-1-Naphtol (Pract)
| 83-55-6 |
|
Pyridinium-P-Toluenesulfonate 98%
| 24057-28-1 |
|
Pyrogallol Red, 98% (Titr.)
| 32638-88-3 |
|
Amberlite ira 416
| 9002-26-0 |
|
3-Methoxybenzonitrile, 98%
| 1527-89-5 |
|
1-Adamantanemethanol, 99%
| 770-71-8 |
|
Inosine, 99%
| 58-63-9 |
|
Pentafluoropropionic Acid
| 422-64-0 |
|
Pyruvic Acid
| 127-17-3 |
|
Potassium hydrogen fluoride, 99+%
| 7789-29-9 |
|
Aluminum Nitride, 98% Particle Size <10 Micron
| 24304-00-5 |
|
Nickel(II) hydroxide, c.p., 60-61% Ni
| 12054-48-7 |
|
1-Adamantanamine sulfate, 99%
| 31377-23-8 |
|
S-(Thiobenzoyl)-Thioglycolic Acid, 97%
| 942-91-6 |
|
N,N-Dimethyl-P-Nitroaniline
| 100-23-2 |
|
Benzofuroxan
| 480-96-6 |
|
cis-2-Aminomethyl-1-cyclohexanol hydrochloride, 99%
| 24947-68-0 |
|
Silver Phosphate, 98% (Titr.)
| 7784-09-0 |
|
4-Cyano-4-Phenylpiperidine Hydrochloride, 99% (TLC)
| 51304-58-6 |
|
Methanesulfonamide
| 3144-09-0 |
|
gamma-Octanoic lactone, 98%
| 104-50-7 |
|
Cis,cis,cis,cis-1,2,3,4-cyclopentane- tetracarboxylic dianhydride,
| 4802-47-5 |
|
Tetrachloroethylene Carbonate, 98+%
| 22432-68-4 |
|
Oxamic Acid, 98%
| 471-47-6 |
|
1O,11-Dihydro-5H-Dibenzo(A,D)-Cycloheptene, 98%
| 833-48-7 |
|
Thallium (I) Sulfate, 99.9+%
| 7446-18-6 |
|
N-(2,6-Dimethylphenylcarbamoyl-Methyl)-Iminodiacetic Acid, 99%
| 59160-29-1 |
|
P-(Dimethylamino)cinnamic Acid, 99%
| 1552-96-1 |
|
Biebrich Scarlet, 99% (UV-VIS)
| 4196-99-0 |
|
4-Chlorobenzenediazonium hexafluoro- phosphate
| 1582-27-0 |
|
Ammonium hexachloroiridate(IV), 99.99%
| 16940-92-4 |
|
Methylamine-d2 deuteriochloride, 98+ atom % D
| 593-51-1 |
|
2,2-Bis-(4-chlorophenyl)-1,1-dichloroethylene, 99%
| 72-55-9 |
|
Nitro red
| 56431-61-9 |
|
Methyl 2,3-dichlorobenzoate, 98+%
| 2905-54-6 |
|
Isopropyl Bromoacetate, 98% (GC)
| 29921-57-1 |
|
1-Iodo-4-Nitrobenzene, 99%
| 636-98-6 |
|
4-Ethylcyclohexanol, 99% cis/trans mixture
| 4534-74-1 |
|
Fluorescamine
| 38183-12-9 |
|
Tris(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Dysprosium(III), 99+%
| 15522-69-7 |
|
3-Amino-2,2,5,5-Tetramethyl-1-Pyrrolidinyloxy, 99% (Titr.)
| 34272-83-8 |
|
3,4-Dihydroxyphenylacetic Acid,98%
| 102-32-9 |
|
|