**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4856-95-5 |Borane-morpholine complex | 97.0 | 225-450-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully
investigated.Water-reactive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause irreversible eye injury.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Reacts violently with water giving off flammable
gas which may explode. Dusts at sufficient concentrations can form
explosive mixtures with air.
Extinguishing Media:
Use dry chemical.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Do not allow water to get into the container
because of violent reaction. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Exposure Limits
CAS# 4856-95-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: clear colorless to slightly yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 97 - 99 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: may decompose
Specific Gravity/Density:
Molecular Formula: C4H12BNO
Molecular Weight: 100.96
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, contact with water, exposure to moist air or
water.
Incompatibilities with Other Materials:
Acids, acid chlorides, acid anhydrides, alcohols, and moist air or
water
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, oxides of boron,
borane, hydrogen gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4856-95-5: QD8530000
LD50/LC50:
CAS# 4856-95-5: Oral, mouse: LD50 = 554 mg/kg; Oral, rat: LD50 = 680
mg/kg.
Carcinogenicity:
Borane-morpholine complex -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 4856-95-5: No information available.
Canada
CAS# 4856-95-5 is listed on Canada's NDSL List.
CAS# 4856-95-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4856-95-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/21/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
M-Benzyloxybenzyl Alcohol , 97%
| 1700-30-7 |
|
Octaphenylcyclotetrasiloxane, 98%
| 546-56-5 |
|
Cetylpyridinium chloride
| 123-03-5 |
|
3,4-Difluorophenol, 99%
| 2713-33-9 |
|
1-Benzyl-4-Hydroxypiperidine, 97%
| 4727-72-4 |
|
4-tert-Butylbenzoyl chloride
| 1710-98-1 |
|
Borane-morpholine complex, 97%
| 4856-95-5 |
|
Benzyl Ether, 99%
| 103-50-4 |
|
5-Amino-1-Naphtol (Pract)
| 83-55-6 |
|
Pyridinium-P-Toluenesulfonate 98%
| 24057-28-1 |
|
Pyrogallol Red, 98% (Titr.)
| 32638-88-3 |
|
Amberlite ira 416
| 9002-26-0 |
|
3-Methoxybenzonitrile, 98%
| 1527-89-5 |
|
1-Adamantanemethanol, 99%
| 770-71-8 |
|
Inosine, 99%
| 58-63-9 |
|
Pentafluoropropionic Acid
| 422-64-0 |
|
Pyruvic Acid
| 127-17-3 |
|
Potassium hydrogen fluoride, 99+%
| 7789-29-9 |
|
Aluminum Nitride, 98% Particle Size <10 Micron
| 24304-00-5 |
|
Nickel(II) hydroxide, c.p., 60-61% Ni
| 12054-48-7 |
|
1-Adamantanamine sulfate, 99%
| 31377-23-8 |
|
S-(Thiobenzoyl)-Thioglycolic Acid, 97%
| 942-91-6 |
|
N,N-Dimethyl-P-Nitroaniline
| 100-23-2 |
|
Benzofuroxan
| 480-96-6 |
|
cis-2-Aminomethyl-1-cyclohexanol hydrochloride, 99%
| 24947-68-0 |
|
Silver Phosphate, 98% (Titr.)
| 7784-09-0 |
|
4-Cyano-4-Phenylpiperidine Hydrochloride, 99% (TLC)
| 51304-58-6 |
|
Methanesulfonamide
| 3144-09-0 |
|
gamma-Octanoic lactone, 98%
| 104-50-7 |
|
Cis,cis,cis,cis-1,2,3,4-cyclopentane- tetracarboxylic dianhydride,
| 4802-47-5 |
|
Tetrachloroethylene Carbonate, 98+%
| 22432-68-4 |
|
Oxamic Acid, 98%
| 471-47-6 |
|
1O,11-Dihydro-5H-Dibenzo(A,D)-Cycloheptene, 98%
| 833-48-7 |
|
Thallium (I) Sulfate, 99.9+%
| 7446-18-6 |
|
N-(2,6-Dimethylphenylcarbamoyl-Methyl)-Iminodiacetic Acid, 99%
| 59160-29-1 |
|
P-(Dimethylamino)cinnamic Acid, 99%
| 1552-96-1 |
|
Biebrich Scarlet, 99% (UV-VIS)
| 4196-99-0 |
|
4-Chlorobenzenediazonium hexafluoro- phosphate
| 1582-27-0 |
|
Ammonium hexachloroiridate(IV), 99.99%
| 16940-92-4 |
|
Methylamine-d2 deuteriochloride, 98+ atom % D
| 593-51-1 |
|
2,2-Bis-(4-chlorophenyl)-1,1-dichloroethylene, 99%
| 72-55-9 |
|
Nitro red
| 56431-61-9 |
|
Methyl 2,3-dichlorobenzoate, 98+%
| 2905-54-6 |
|
Isopropyl Bromoacetate, 98% (GC)
| 29921-57-1 |
|
1-Iodo-4-Nitrobenzene, 99%
| 636-98-6 |
|
4-Ethylcyclohexanol, 99% cis/trans mixture
| 4534-74-1 |
|
Fluorescamine
| 38183-12-9 |
|
Tris(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Dysprosium(III), 99+%
| 15522-69-7 |
|
3-Amino-2,2,5,5-Tetramethyl-1-Pyrrolidinyloxy, 99% (Titr.)
| 34272-83-8 |
|
3,4-Dihydroxyphenylacetic Acid,98%
| 102-32-9 |
|
|