**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7446-18-6 |Thallium(I) sulfate | 99.9+% | 231-201-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+ N
Risk Phrases: 28 38 48/25 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic if swallowed. Irritating to skin. Toxic : danger of
serious damage to health by prolonged exposure if swallowed. Toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be absorbed through the skin in
harmful amounts. May cause sensitization by skin contact.
Ingestion:
May be fatal if swallowed. May cause liver and kidney damage. May
cause alopecia (loss of hair). Ingested thallium compounds are
extremely toxic, causing convulsions, coma, conjunctivitis, runny
nose, polyneuritis, motor and sensory peripheral neuropathy,
encephalopathy, arterial hypertension, rapid heart rate, and skin
eruptions
Inhalation:
May cause respiratory tract irritation.
Chronic:
May cause reproductive and fetal effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. For small fires, use dry chemical,
carbon dioxide, water spray or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Do not get in eyes, on skin, or on clothing. Do not
ingest or inhale. Use only in a chemical fume hood. Wash clothing
before reuse. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Poison room locked.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use only under a
chemical fume hood.
Exposure Limits
CAS# 7446-18-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 632 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 4.87G/100ML (20C)
Specific Gravity/Density: 6.7700g/cm3
Molecular Formula: O4STl2
Molecular Weight: 504.79
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of sulfur, thallium fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7446-18-6: XG6800000
LD50/LC50:
CAS# 7446-18-6: Oral, mouse: LD50 = 23500 ug/kg; Oral, mouse: LD50 =
23.5 mg/kg; Oral, rat: LD50 = 16 mg/kg; Skin, rat: LD50 = 550 mg/kg.
Carcinogenicity:
Thallium(I) sulfate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1707
Packing Group: II
IMO
Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1707
Packing Group: II
RID/ADR
Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1707
Packing group: II
USA RQ: CAS# 7446-18-6: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ N
Risk Phrases:
R 28 Very toxic if swallowed.
R 38 Irritating to skin.
R 48/25 Toxic : danger of serious damage to health
by prolonged exposure if swallowed.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding
stuffs.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7446-18-6: 2
Canada
CAS# 7446-18-6 is listed on Canada's DSL List.
CAS# 7446-18-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7446-18-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
M-Benzyloxybenzyl Alcohol , 97%
| 1700-30-7 |
|
Octaphenylcyclotetrasiloxane, 98%
| 546-56-5 |
|
Cetylpyridinium chloride
| 123-03-5 |
|
3,4-Difluorophenol, 99%
| 2713-33-9 |
|
1-Benzyl-4-Hydroxypiperidine, 97%
| 4727-72-4 |
|
4-tert-Butylbenzoyl chloride
| 1710-98-1 |
|
Borane-morpholine complex, 97%
| 4856-95-5 |
|
Benzyl Ether, 99%
| 103-50-4 |
|
5-Amino-1-Naphtol (Pract)
| 83-55-6 |
|
Pyridinium-P-Toluenesulfonate 98%
| 24057-28-1 |
|
Pyrogallol Red, 98% (Titr.)
| 32638-88-3 |
|
Amberlite ira 416
| 9002-26-0 |
|
3-Methoxybenzonitrile, 98%
| 1527-89-5 |
|
1-Adamantanemethanol, 99%
| 770-71-8 |
|
Inosine, 99%
| 58-63-9 |
|
Pentafluoropropionic Acid
| 422-64-0 |
|
Pyruvic Acid
| 127-17-3 |
|
Potassium hydrogen fluoride, 99+%
| 7789-29-9 |
|
Aluminum Nitride, 98% Particle Size <10 Micron
| 24304-00-5 |
|
Nickel(II) hydroxide, c.p., 60-61% Ni
| 12054-48-7 |
|
1-Adamantanamine sulfate, 99%
| 31377-23-8 |
|
S-(Thiobenzoyl)-Thioglycolic Acid, 97%
| 942-91-6 |
|
N,N-Dimethyl-P-Nitroaniline
| 100-23-2 |
|
Benzofuroxan
| 480-96-6 |
|
cis-2-Aminomethyl-1-cyclohexanol hydrochloride, 99%
| 24947-68-0 |
|
Silver Phosphate, 98% (Titr.)
| 7784-09-0 |
|
4-Cyano-4-Phenylpiperidine Hydrochloride, 99% (TLC)
| 51304-58-6 |
|
Methanesulfonamide
| 3144-09-0 |
|
gamma-Octanoic lactone, 98%
| 104-50-7 |
|
Cis,cis,cis,cis-1,2,3,4-cyclopentane- tetracarboxylic dianhydride,
| 4802-47-5 |
|
Tetrachloroethylene Carbonate, 98+%
| 22432-68-4 |
|
Oxamic Acid, 98%
| 471-47-6 |
|
1O,11-Dihydro-5H-Dibenzo(A,D)-Cycloheptene, 98%
| 833-48-7 |
|
Thallium (I) Sulfate, 99.9+%
| 7446-18-6 |
|
N-(2,6-Dimethylphenylcarbamoyl-Methyl)-Iminodiacetic Acid, 99%
| 59160-29-1 |
|
P-(Dimethylamino)cinnamic Acid, 99%
| 1552-96-1 |
|
Biebrich Scarlet, 99% (UV-VIS)
| 4196-99-0 |
|
4-Chlorobenzenediazonium hexafluoro- phosphate
| 1582-27-0 |
|
Ammonium hexachloroiridate(IV), 99.99%
| 16940-92-4 |
|
Methylamine-d2 deuteriochloride, 98+ atom % D
| 593-51-1 |
|
2,2-Bis-(4-chlorophenyl)-1,1-dichloroethylene, 99%
| 72-55-9 |
|
Nitro red
| 56431-61-9 |
|
Methyl 2,3-dichlorobenzoate, 98+%
| 2905-54-6 |
|
Isopropyl Bromoacetate, 98% (GC)
| 29921-57-1 |
|
1-Iodo-4-Nitrobenzene, 99%
| 636-98-6 |
|
4-Ethylcyclohexanol, 99% cis/trans mixture
| 4534-74-1 |
|
Fluorescamine
| 38183-12-9 |
|
Tris(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Dysprosium(III), 99+%
| 15522-69-7 |
|
3-Amino-2,2,5,5-Tetramethyl-1-Pyrrolidinyloxy, 99% (Titr.)
| 34272-83-8 |
|
3,4-Dihydroxyphenylacetic Acid,98%
| 102-32-9 |
|
|