**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 12054-48-7 |Nickel dihydroxide | 100 | 235-008-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 20/22 40 43 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Limited evidence of a
carcinogenic effect. May cause sensitization by skin contact. Very
toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.Cancer suspect agent.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Causes "nickel itch" which is a
dermatitis resulting from sensitization to nickel, which is
characterized by skin eruptions, followed by discrete ulcers that may
discharge and become crusted, or by eczema.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
May cause cancer according to animal studies. Symptoms of
overexposure to nickel can cause sensitization, dermatitis, allergic
asthma and pneumonitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 12054-48-7:
United Kingdom, WEL - TWA: (listed as nickel, inorganic compounds
insoluble): 0.5 mg/m3 TWA (except nickel tetracarbonyl, as Ni)
United Kingdom, WEL - STEL: (listed as nickel, inorganic compound
insoluble): 1.5 mg/m3 STEL (except nickel tetracarbonyl, as Ni)
United States OSHA: 1 mg/m3 TWA (as Ni) (listed under Nickel sol
compounds).
Belgium - TWA: (listed as nickel soluble compounds): 0.1 mg/m3 VL
(as Ni)
France - VME: 1 mg/m3 VME (as Ni)
Malaysia: (listed as nickel soluble compounds): 0.1 mg/m3 TWA
(inhalable fraction, as Ni)
Netherlands: (listed as nickel soluble compounds): 0.1 mg/m3 MAC
Ni)
Spain: 0.1 mg/m3 VLA-ED (as Ni)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: lime green
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 230 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 230 deg C
Solubility in water: Negligible.
Specific Gravity/Density: 4.15
Molecular Formula: H2NiO2
Molecular Weight: 92.70
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong acids.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, nickel oxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 12054-48-7: QR7040000
LD50/LC50:
CAS# 12054-48-7: Inhalation, rat: LC50 = 1200 mg/m3/4H; Oral, rat:
LD50 = 1515 mg/kg; Skin, rat: LD50 = >2 gm/kg.
Carcinogenicity:
Nickel dihydroxide -
California: carcinogen, initial date 10/1/89
NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Daphnia: Daphnia: 51mg/L; 48H
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 12054-48-7: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 22 Do not breathe dust.
S 36 Wear suitable protective clothing.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 12054-48-7: No information available.
Canada
CAS# 12054-48-7 is listed on Canada's DSL List.
CAS# 12054-48-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 12054-48-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/28/1999 Revision #2 Date: 8/02/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
M-Benzyloxybenzyl Alcohol , 97%
| 1700-30-7 |
|
Octaphenylcyclotetrasiloxane, 98%
| 546-56-5 |
|
Cetylpyridinium chloride
| 123-03-5 |
|
3,4-Difluorophenol, 99%
| 2713-33-9 |
|
1-Benzyl-4-Hydroxypiperidine, 97%
| 4727-72-4 |
|
4-tert-Butylbenzoyl chloride
| 1710-98-1 |
|
Borane-morpholine complex, 97%
| 4856-95-5 |
|
Benzyl Ether, 99%
| 103-50-4 |
|
5-Amino-1-Naphtol (Pract)
| 83-55-6 |
|
Pyridinium-P-Toluenesulfonate 98%
| 24057-28-1 |
|
Pyrogallol Red, 98% (Titr.)
| 32638-88-3 |
|
Amberlite ira 416
| 9002-26-0 |
|
3-Methoxybenzonitrile, 98%
| 1527-89-5 |
|
1-Adamantanemethanol, 99%
| 770-71-8 |
|
Inosine, 99%
| 58-63-9 |
|
Pentafluoropropionic Acid
| 422-64-0 |
|
Pyruvic Acid
| 127-17-3 |
|
Potassium hydrogen fluoride, 99+%
| 7789-29-9 |
|
Aluminum Nitride, 98% Particle Size <10 Micron
| 24304-00-5 |
|
Nickel(II) hydroxide, c.p., 60-61% Ni
| 12054-48-7 |
|
1-Adamantanamine sulfate, 99%
| 31377-23-8 |
|
S-(Thiobenzoyl)-Thioglycolic Acid, 97%
| 942-91-6 |
|
N,N-Dimethyl-P-Nitroaniline
| 100-23-2 |
|
Benzofuroxan
| 480-96-6 |
|
cis-2-Aminomethyl-1-cyclohexanol hydrochloride, 99%
| 24947-68-0 |
|
Silver Phosphate, 98% (Titr.)
| 7784-09-0 |
|
4-Cyano-4-Phenylpiperidine Hydrochloride, 99% (TLC)
| 51304-58-6 |
|
Methanesulfonamide
| 3144-09-0 |
|
gamma-Octanoic lactone, 98%
| 104-50-7 |
|
Cis,cis,cis,cis-1,2,3,4-cyclopentane- tetracarboxylic dianhydride,
| 4802-47-5 |
|
Tetrachloroethylene Carbonate, 98+%
| 22432-68-4 |
|
Oxamic Acid, 98%
| 471-47-6 |
|
1O,11-Dihydro-5H-Dibenzo(A,D)-Cycloheptene, 98%
| 833-48-7 |
|
Thallium (I) Sulfate, 99.9+%
| 7446-18-6 |
|
N-(2,6-Dimethylphenylcarbamoyl-Methyl)-Iminodiacetic Acid, 99%
| 59160-29-1 |
|
P-(Dimethylamino)cinnamic Acid, 99%
| 1552-96-1 |
|
Biebrich Scarlet, 99% (UV-VIS)
| 4196-99-0 |
|
4-Chlorobenzenediazonium hexafluoro- phosphate
| 1582-27-0 |
|
Ammonium hexachloroiridate(IV), 99.99%
| 16940-92-4 |
|
Methylamine-d2 deuteriochloride, 98+ atom % D
| 593-51-1 |
|
2,2-Bis-(4-chlorophenyl)-1,1-dichloroethylene, 99%
| 72-55-9 |
|
Nitro red
| 56431-61-9 |
|
Methyl 2,3-dichlorobenzoate, 98+%
| 2905-54-6 |
|
Isopropyl Bromoacetate, 98% (GC)
| 29921-57-1 |
|
1-Iodo-4-Nitrobenzene, 99%
| 636-98-6 |
|
4-Ethylcyclohexanol, 99% cis/trans mixture
| 4534-74-1 |
|
Fluorescamine
| 38183-12-9 |
|
Tris(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Dysprosium(III), 99+%
| 15522-69-7 |
|
3-Amino-2,2,5,5-Tetramethyl-1-Pyrrolidinyloxy, 99% (Titr.)
| 34272-83-8 |
|
3,4-Dihydroxyphenylacetic Acid,98%
| 102-32-9 |
|
|