**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 100-41-4 |Ethylbenzene | 7 | 202-849-4 |
|----------------|--------------------------------------|----------|-----------|
| 1634-04-4 |Methyl tert-butyl ether | 70 | 216-653-1 |
|----------------|--------------------------------------|----------|-----------|
| 4039-32-1 |Lithium bis(trimethylsilyl)amide | 23 | 223-725-6 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: F C
Risk Phrases: 11 14 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Reacts violently with water. Causes severe burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. If water-reactive products are embedded
in the skin, no water should be applied. The embedded products
should be covered with a light oil.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water Reactive. Material will react with water and
may release a flammable and/or toxic gas. Flammable liquid and
vapor.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT use carbon
dioxide. Use dry chemical to fight fire. DO NOT USE WATER!
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Water free area. Store under an
inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 100-41-4:
United Kingdom, WEL - TWA: 100 ppm TWA; 441 mg/m3 TWA
United Kingdom, WEL - STEL: 125 ppm STEL; 552 mg/m3 STEL
United States OSHA: 100 ppm TWA; 435 mg/m3 TWA
Belgium - TWA: 100 ppm VLE; 442 mg/m3 VLE
Belgium - STEL: 125 ppm VLE; 551 mg/m3 VLE
France - VME: 100 ppm VME; 435 mg/m3 VME
Germany: 100 ppm TWA; 440 mg/m3 TWA
Germany: Skin absorber
Japan: 50 ppm OEL; 217 mg/m3 OEL
Malaysia: 100 ppm TWA; 434 mg/m3 TWA
Netherlands: 50 ppm MAC; 215 mg/m3 MAC
Russia: 50 mg/m3 TWA
Spain: 100 ppm VLA-ED; 441 mg/m3 VLA-ED
Spain: 200 ppm VLA-EC; 884 mg/m3 VLA-EC
CAS# 1634-04-4:
United Kingdom, WEL - TWA: 25 ppm TWA; 92 mg/m3 TWA
United Kingdom, WEL - STEL: 75 ppm STEL; 275 mg/m3 STEL
Belgium - TWA: 40 ppm VLE; 146 mg/m3 VLE
Germany: 50 ppm TWA; 180 mg/m3 TWA
Malaysia: 40 ppm TWA; 144 mg/m3 TWA
Netherlands: 100 ppm STEL; 360 mg/m3 STEL
Netherlands: 50 ppm MAC; 180 mg/m3 MAC
Russia: 100 mg/m3 TWA
Spain: 40 ppm VLA-ED; 147 mg/m3 VLA-ED
CAS# 4039-32-1:
United Kingdom, WEL - TWA: (listed as silica, amorphous): 6 mg/m3
(inhalable dust); 2.4 mg/m3 TWA (respirable dust)
United Kingdom, WEL - STEL: (listed as silica, amorphous): 18 mg/
STEL (inhalable dust); 7.2 mg/m3 STEL (respirable dust)
Russia: (listed as silica, amorphous): 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure. Chemical-resistant nitrile rubber gloves
should be worn during routine handling. Disposable
nitrile gloves may be suggested for intermittent use.
PVC, Neoprene, Viton, Butyl or natural rubber are NOT
recommended.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: -28 deg C ( -18.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: 0.8
Molecular Formula: C6H19LiNSi2
Molecular Weight: 168.2517
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, contact with water.
Incompatibilities with Other Materials:
Acids, oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-41-4: DA0700000
CAS# 1634-04-4: KN5250000
CAS# 4039-32-1 unlisted.
LD50/LC50:
CAS# 100-41-4: Draize test, rabbit, eye: 500 mg Severe; Inhalation,
mouse: LC50 = 35500 mg/m3/2H; Inhalation, rat: LC50 = 55000
mg/m3/2H; Oral, rat: LD50 = 3500 mg/kg; Oral, rat: LD50 = 3500
mg/kg; Skin, rabbit: LD50 = 17800 uL/kg.
CAS# 1634-04-4: Inhalation, mouse: LC50 = 141 gm/m3/15M; Inhalation,
mouse: LC50 = 28000 mg/m3/2H; Inhalation, rat: LC50 = 23576 ppm/4H;
Inhalation, rat: LC50 = 41000 mg/m3/4H; Oral, mouse: LD50 = 5960
uL/kg; Oral, rat: LD50 = 4 gm/kg.
CAS# 4039-32-1.
Carcinogenicity:
Ethylbenzene -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 6/11/04
IARC: Group 2B carcinogen
Methyl tert-butyl ether -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
Lithium bis(trimethylsilyl)amide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
USA RQ: CAS# 100-41-4: 1000 lb final RQ; 454 kg final RQ
USA RQ: CAS# 1634-04-4: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 14 Reacts violently with water.
R 35 Causes severe burns.
Safety Phrases:
S 8 Keep container dry.
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 100-41-4: 1
CAS# 1634-04-4: 1
CAS# 4039-32-1: No information available.
Canada
CAS# 100-41-4 is listed on Canada's DSL List.
CAS# 1634-04-4 is listed on Canada's DSL List.
CAS# 4039-32-1 is listed on Canada's NDSL List.
CAS# 100-41-4 is listed on Canada's Ingredient Disclosure List.
CAS# 1634-04-4 is not listed on Canada's Ingredient Disclosure List.
CAS# 4039-32-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-41-4 is listed on the TSCA inventory.
CAS# 1634-04-4 is listed on the TSCA inventory.
CAS# 4039-32-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 7/18/2000 Revision #1 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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