**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 627-18-9 |3-Bromo-1-propanol | 97 | 210-986-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to
pulmonary edema. May be harmful if inhaled. Can produce delayed
pulmonary edema. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Combustible liquid. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. Containers may explode when heated. Runoff from fire control
or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes,
skin, and clothing. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Keep container tightly closed.
Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Wash clothing before reuse. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a dry area. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 627-18-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: slight
pH: neutral (1% aq.sol.)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 62 deg C @ 5mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 65 deg C ( 149.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 167 g/l ( 20C)
Specific Gravity/Density: 1.60 g/cm3
Molecular Formula: C3H7BrO
Molecular Weight: 138.99
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, light, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 627-18-9: UA7385000
LD50/LC50:
Not available.
Carcinogenicity:
3-Bromo-1-propanol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 627-18-9: No information available.
Canada
CAS# 627-18-9 is listed on Canada's NDSL List.
CAS# 627-18-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 627-18-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/14/2000 Revision #3 Date: 7/22/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl 4-amino-3-bromobenzoate
| 106896-49-5 |
|
2,4-Dichloro-5-hydroxyaniline
| 39489-79-7 |
|
6-Chloro-4-trifluoromethoxyaniline
| 0-01-1 |
|
2,4-Dibromo-6-methylaniline
| 30273-41-7 |
|
1,4-Bis(trichloromethyl)benzene, 99%
| 68-36-0 |
|
Nicotinamide, p.a.
| 98-92-0 |
|
6-Chloro-9-(3-N-(2-chloroethyl-amino)-propylamino-2-methoxyacridine
| 17064-47-0 |
|
2-Amino-5-bromobenzotrifluoride
| 445-02-3 |
|
N,N'-p-Phenylenedimaleimide
| 3278-31-7 |
|
N,N'-m-Phenylenedimaleimide
| 3006-93-7 |
|
Allyltrimethylsilane, 97%
| 762-72-1 |
|
Celite 545
| 68855-54-9 |
|
3-Bromo-1-propanol, 97%
| 627-18-9 |
|
1,2-Epoxy-2-methylbutane
| 30095-63-7 |
|
2,3-Epoxy-2-methylbutane
| 5076-19-7 |
|
Dicyclopentadiene diepoxide
| 81-21-0 |
|
1-(3-Methylphenyl)-piperazine, 99%
| 41186-03-2 |
|
Lithium bis(trimethylsilyl)amide, 23% in methyl tert-butyl ether
| 100-41-4 |
|
Lithium bis(trimethylsilyl)amide, 20% in THF
| 100-41-4 |
|
2(2-Bromoethyl)-1,3-dioxolane, 96%
| 18742-02-4 |
|
N-(Phenylseleno)phthalimide, tech.
| 71098-88-9 |
|
Brij?? 98
| 9004-98-2 |
|
4-Fluoro-N-methylaniline
| 459-59-6 |
|
3,4,5-Trimethoxyacetophenone, 99+%
| 1136-86-3 |
|
Potassium tetracyanonickelate(II) hydrate
| 14220-17-8 |
|
Zinc peroxide, 55%
| 1314-22-3 |
|
3,4-Dimethyl-3,4-diphenylhexane
| 10192-93-5 |
|
1,4-Naphthalenediol (pract), 95% (uv-vis)
| 571-60-8 |
|
2,3-Dimethyl-2,3-diphenylbutane
| 1889-67-4 |
|
Dicumyl peroxide
| 80-43-3 |
|
Cumyl hydroperoxide
| 80-15-9 |
|
tert-Butyl cumyl peroxide
| 98-82-8 |
|
3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxynonane, 41% solution in
| 24748-23-0 |
|
Di(tert-butylperoxyisopropyl)benzene
| 2212-81-9 |
|
tert-Butyl peroxy-3,5,5-trimethylhexanoate
| 13122-18-4 |
|
tert-Butylperoxy 2-ethylhexyl carbonate
| 34443-12-4 |
|
Di-tert-butyl peroxide
| 110-05-4 |
|
1,1-Di(tert-butylperoxy)cyclohexane, 50% solution in aromatic free
| 3006-86-8 |
|
Lauroyl peroxide
| 105-74-8 |
|
tert-Butyl peroxyacetate, 50% solution in aromatic free mineral
| 107-71-1 |
|
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane
| 78-63-7 |
|
2,2-Di(tert-butylperoxy)butane, 50% solution in aromatic free mineral
| 78-93-3 |
|
Benzoylformic acid, 97%
| 611-73-4 |
|
Ethyl 7-bromoheptanoate
| 29823-18-5 |
|
16-Hydroxyhexadecanoic Acid, 98%
| 506-13-8 |
|
4-(4,6-Dimethoxy[1.3.5]triazin-2-yl)-4-methylmorpholinium chloride
| 0-00-0 |
|
3-Methoxysalicylic acid, 97%
| 877-22-5 |
|
d-alpha-Tocopherylquinone, 90-95%
| 7559-04-8 |
|
Dibutyl Maleate
| 105-76-0 |
|
Glutathione-Agarose, 4% cross-linked
| 0-01-1 |
|
|