**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 14220-17-8 |Potassium tetracyanonickelate(II) hydr| | 238-082-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 22 42/43 45
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. May cause sensitization by inhalation and skin
contact. May cause cancer.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May be harmful if absorbed through the skin. May cause sensitization
by skin contact.
Ingestion:
Harmful if swallowed.
Inhalation:
May be harmful if inhaled. May cause respiratory sensitization.
Chronic:
May cause cancer in humans.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is noncombustible.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 14220-17-8:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: yellow to orange
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C4K2N4Ni
Molecular Weight: 240.9134
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Acids, bases, oxidizing agents, carbon dioxide.
Hazardous Decomposition Products:
Hydrogen cyanide, carbon monoxide, nickel oxide, oxides of potassium.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 14220-17-8: QR8650000
LD50/LC50:
CAS# 14220-17-8: Oral, mouse: LD50 = 275 mg/kg.
Carcinogenicity:
Potassium tetracyanonickelate(II) hydrate -
California: carcinogen, initial date 5/7/04 (listed as Nickel compound
NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 22 Harmful if swallowed.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 14220-17-8: No information available.
Canada
CAS# 14220-17-8 is listed on Canada's DSL List.
CAS# 14220-17-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14220-17-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/19/2000 Revision #1 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
ALL MSDS PAGES IN THIS GROUP
| NAME | CAS |
Methyl 4-amino-3-bromobenzoate
| 106896-49-5 |
2,4-Dichloro-5-hydroxyaniline
| 39489-79-7 |
6-Chloro-4-trifluoromethoxyaniline
| 0-01-1 |
2,4-Dibromo-6-methylaniline
| 30273-41-7 |
1,4-Bis(trichloromethyl)benzene, 99%
| 68-36-0 |
Nicotinamide, p.a.
| 98-92-0 |
6-Chloro-9-(3-N-(2-chloroethyl-amino)-propylamino-2-methoxyacridine
| 17064-47-0 |
2-Amino-5-bromobenzotrifluoride
| 445-02-3 |
N,N'-p-Phenylenedimaleimide
| 3278-31-7 |
N,N'-m-Phenylenedimaleimide
| 3006-93-7 |
Allyltrimethylsilane, 97%
| 762-72-1 |
Celite 545
| 68855-54-9 |
3-Bromo-1-propanol, 97%
| 627-18-9 |
1,2-Epoxy-2-methylbutane
| 30095-63-7 |
2,3-Epoxy-2-methylbutane
| 5076-19-7 |
Dicyclopentadiene diepoxide
| 81-21-0 |
1-(3-Methylphenyl)-piperazine, 99%
| 41186-03-2 |
Lithium bis(trimethylsilyl)amide, 23% in methyl tert-butyl ether
| 100-41-4 |
Lithium bis(trimethylsilyl)amide, 20% in THF
| 100-41-4 |
2(2-Bromoethyl)-1,3-dioxolane, 96%
| 18742-02-4 |
N-(Phenylseleno)phthalimide, tech.
| 71098-88-9 |
Brij?? 98
| 9004-98-2 |
4-Fluoro-N-methylaniline
| 459-59-6 |
3,4,5-Trimethoxyacetophenone, 99+%
| 1136-86-3 |
Potassium tetracyanonickelate(II) hydrate
| 14220-17-8 |
Zinc peroxide, 55%
| 1314-22-3 |
3,4-Dimethyl-3,4-diphenylhexane
| 10192-93-5 |
1,4-Naphthalenediol (pract), 95% (uv-vis)
| 571-60-8 |
2,3-Dimethyl-2,3-diphenylbutane
| 1889-67-4 |
Dicumyl peroxide
| 80-43-3 |
Cumyl hydroperoxide
| 80-15-9 |
tert-Butyl cumyl peroxide
| 98-82-8 |
3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxynonane, 41% solution in
| 24748-23-0 |
Di(tert-butylperoxyisopropyl)benzene
| 2212-81-9 |
tert-Butyl peroxy-3,5,5-trimethylhexanoate
| 13122-18-4 |
tert-Butylperoxy 2-ethylhexyl carbonate
| 34443-12-4 |
Di-tert-butyl peroxide
| 110-05-4 |
1,1-Di(tert-butylperoxy)cyclohexane, 50% solution in aromatic free
| 3006-86-8 |
Lauroyl peroxide
| 105-74-8 |
tert-Butyl peroxyacetate, 50% solution in aromatic free mineral
| 107-71-1 |
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane
| 78-63-7 |
2,2-Di(tert-butylperoxy)butane, 50% solution in aromatic free mineral
| 78-93-3 |
Benzoylformic acid, 97%
| 611-73-4 |
Ethyl 7-bromoheptanoate
| 29823-18-5 |
16-Hydroxyhexadecanoic Acid, 98%
| 506-13-8 |
4-(4,6-Dimethoxy[1.3.5]triazin-2-yl)-4-methylmorpholinium chloride
| 0-00-0 |
3-Methoxysalicylic acid, 97%
| 877-22-5 |
d-alpha-Tocopherylquinone, 90-95%
| 7559-04-8 |
Dibutyl Maleate
| 105-76-0 |
Glutathione-Agarose, 4% cross-linked
| 0-01-1 |
|
|