**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 102-69-2 |Tripropylamine | 99+% | 203-047-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 10 20/21 25 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation and in contact with skin. Toxic if
swallowed. Causes burns.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye burns. Causes redness and pain.
Skin:
Harmful if absorbed through the skin. Causes skin burns. Exposure
may cause irritation characterized by redness, dryness, and
inflammation. Substance is readily absorbed through the skin.
Ingestion:
Poison by ingestion. Causes gastrointestinal tract burns.
Inhalation:
Harmful if inhaled. Causes chemical burns to the respiratory tract.
May cause asthma and shortness of breath.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately. Wash mouth out
with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water
spray to keep fire-exposed containers cool. Flammable liquid and
vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Take precautionary measures against static discharges. Use
only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use adequate
general or local explosion-proof ventilation to keep airborne levels
to acceptable levels.
Exposure Limits
CAS# 102-69-2:
Russia: 2 mg/m3 TWA
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: amine-like
pH: 11.4(2.69g/laq.sol.)
Vapor Pressure: 3 mbar @ 20 deg C
Viscosity: 0.627 mPa.s
Boiling Point: 156 deg C @ 760 mmHg
Freezing/Melting Point: -93 deg C
Autoignition Temperature: 180 deg C ( 356.00 deg F)
Flash Point: 32.5 deg C ( 90.50 deg F)
Explosion Limits, lower: 0.6 vol %
Explosion Limits, upper: 5.5 vol %
Decomposition Temperature:
Solubility in water: 2.6 g/l water (20C)
Specific Gravity/Density: 0.76 g/cm3
Molecular Formula: C9H21N
Molecular Weight: 143.27
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 102-69-2: TX1575000
LD50/LC50:
CAS# 102-69-2: Inhalation, mouse: LC50 = 3800 mg/m3/2H; Inhalation,
rat: LC50 = 5100 mg/m3/4H; Oral, rat: LD50 = 96 mg/kg; Skin, rabbit:
LD50 = 570 uL/kg.
Carcinogenicity:
Tripropylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TRIPROPYLAMINE
Hazard Class: 3 (8)
UN Number: 2260
Packing Group: III
IMO
Shipping Name: TRIPROPYLAMINE
Hazard Class: 3 (8)
UN Number: 2260
Packing Group: III
RID/ADR
Shipping Name: TRIPROPYLAMINE
Hazard Class: 3
UN Number: 2260
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 10 Flammable.
R 20/21 Harmful by inhalation and in contact with
skin.
R 25 Toxic if swallowed.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 102-69-2: 2
Canada
CAS# 102-69-2 is listed on Canada's NDSL List.
CAS# 102-69-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 102-69-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/25/1999 Revision #2 Date: 4/04/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
6-Aminonicotinic Acid, 98%
| 3167-49-5 |
|
Rhodamine 6g Perchlorate, Laser Grade, 99% (TLC)
| 13161-28-9 |
|
3-Thiophenemalonic acid, 98+%
| 21080-92-2 |
|
Poly(Sodium-P-Styrenesulfonate), Average M.W.100.000
| 25704-18-1 |
|
3-Cyclohexylpropionaldehyde, 99%
| 4361-28-8 |
|
Tripropylamine, 99+%
| 102-69-2 |
|
1,10-Decanediol, 95% (GC)
| 112-47-0 |
|
Cyclooctanol, 99%
| 696-71-9 |
|
l-(-)-Sorbose, 99%
| 87-79-6 |
|
6-Bromo-2-Naphthyl-Beta-D-Glucopyranoside
| 15548-61-5 |
|
1-Hexadecylsulfonic acid, sodium salt, HPLC grade
| 15015-81-3 |
|
3-Carbethoxy-4-Piperidone Hydrochloride 98% (TLC)
| 4644-61-5 |
|
1,3-Dimethylurea, 98%
| 96-31-1 |
|
Diethyl 1,4-Dihydro-2,4,6-Trimethyl- 3,5-Pyridinedicarboxylate, 99%
| 632-93-9 |
|
Dimethylthiocarbamoyl Chloride, 99% (Titr.)
| 16420-13-6 |
|
3,3',5,5'-Tetramethylbenzidine, 99+%
| 54827-17-7 |
|
3,5-Diamino-1,2,4-Triazole 98%
| 1455-77-2 |
|
2-(Trifluoromethyl)benzimidazole
| 312-73-2 |
|
(1R,2R)-(+)-1,2-Diphenyl-1,2-Ethane Diamine, 99% (99% e.e.)
| 29841-69-8 |
|
1-Methyl-7-Hydroxy-6-Methoxy-3,4-Dihydroisoquinoline, 99+%
| 4602-70-4 |
|
Amberlite IRC-50 Ion-Exchange Resin
| 9002-29-3 |
|
Tetrahexylammonium Iodide, 99% (Titr.)
| 2138-24-1 |
|
L(-)-methanesulfonylethyllactate
| 63696-99-1 |
|
Tetrafluoroterephthalonitrile, 97%
| 1835-49-0 |
|
2-Furoic acid hydrazide, 98%
| 3326-71-4 |
|
4-Cyclohexylaniline, 97%
| 6373-50-8 |
|
8-Formyl-7-methoxy-1,4-dioxa-8-azaspiro[4.5]decane, tech., 85%
| |
|
(2-Hydroxybenzoyl)methylenetriphenylphosphorane, 98%
| 0-01-1 |
|
3-Acetyl-1-propanol, 96%
| 1071-73-4 |
|
4-Chlorobenzotrifluoride, 98%
| 98-56-6 |
|
p-Tolyl Isothiocyanate, 99%
| 622-59-3 |
|
Boron trifluoride - acetic acid complex, c a. 33% bf3
| 373-61-5 |
|
Titanium (IV) Oxide, 98.0 - 100.5% TiO2
| 13463-40-6 |
|
Ethylmercurithiosalicylic acid, sodium salt
| 54-64-8 |
|
1-Iodopentane, 97% (GC)
| 628-17-1 |
|
(4-Carboxybutyl)triphenylphosphonium bromide, 98%
| 17814-85-6 |
|
Dichloroacetyl Chloride, 97%
| 79-36-7 |
|
trans-Traumatic acid, 97%
| 6402-36-4 |
|
1,4-Pentadiene, 99%
| 591-93-5 |
|
2-Chloro-p-phenylenediamine dihydrochloride, 99% (uv-vis)
| 615-46-3 |
|
Calcium 2-ethylhexanoate
| 136-51-6 |
|
N-Hydroxysuccinimide, 98+%
| 6066-82-6 |
|
2,2-Diphenylpropylamine Hydrochloride, 95%
| 40691-66-5 |
|
Cerium atomic absorption standard solution 1 mg/ml Ce in 2% HNO3
| 7440-45-1 |
|
alpha-Pyridoin, 99%
| 1141-06-6 |
|
4,6-Dimethyl-2-Pyrone, 98%
| 675-09-2 |
|
Oleic acid, sodium salt, 65-90% oleic C18
| 143-19-1 |
|
(+/-)-Tetrahydropapaveroline Hydrobromide, 98%
| 4747-99-3 |
|
5-Bromo-2-fluorotoluene, 99%
| 51437-00-4 |
|
2-Methoxy-4-Methylphenol, 99% (GC)
| 93-51-6 |
|
|