**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 79-36-7 |Dichloroacetyl Chloride | 97% | 201-199-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN C
Risk Phrases: 21 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin. Causes severe burns.Corrosive.Moisture
sensitive.Lachrymator (substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Harmful if absorbed through the skin. Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract. May
cause abdominal pain, nausea, vomiting, and inflammation of the gums
and mouth.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Discard contaminated clothing
in a manner which limits further exposure. Destroy contaminated
shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water spray to
keep fire-exposed containers cool. Combustible liquid. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. Contact with metals may evolve flammable
hydrogen gas. Containers may explode when heated or if contaminated
with water. Substance will react with water (some violently)
releasing flammable, toxic, or corrosive gases and runoff.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. For large fires, use water spray, fog or
alcohol-resistant foam. Do NOT use straight streams of water. For
small fires, use carbon dioxide, dry chemical, dry sand, or
alcohol-resistant foam. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal. Remove all sources of ignition. Provide ventilation. Do not
get water inside containers. Do not get water on spilled substances
or inside containers. Use water spray to reduce vapors or divert
vapor cloud drift.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep container tightly closed. Keep away from
heat, sparks and flame. Do not get on skin or in eyes. Do not ingest
or inhale. Do not allow contact with water. Discard contaminated
shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames. Keep from
contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a cool,
dry, well-ventilated area away from incompatible substances.
Corrosives area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 79-36-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Penetrating odor.
pH: Not available.
Vapor Pressure: 30.6 hPa @ 20 C
Viscosity: Not available.
Boiling Point: 107 - 108 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: 585 deg C ( 1,085.00 deg F)
Flash Point: 66 deg C ( 150.80 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: Decomposes.
Specific Gravity/Density: 1.5320g/cm3
Molecular Formula: C2HCl3O
Molecular Weight: 147.39
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat,
temperatures above 65C, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 79-36-7: AO6650000
LD50/LC50:
CAS# 79-36-7: Draize test, rabbit, skin: 2 mg/24H Severe; Oral, rat:
LD50 = 2460 mg/kg; Skin, rabbit: LD50 = 650 uL/kg.
Carcinogenicity:
Dichloroacetyl Chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DICHLOROACETYL CHLORIDE
Hazard Class: 8
UN Number: 1765
Packing Group: II
IMO
Shipping Name: DICHLOROACETYL CHLORIDE
Hazard Class: 8
UN Number: 1765
Packing Group: II
RID/ADR
Shipping Name: DICHLOROACETYL CHLORIDE
Hazard Class: 8
UN Number: 1765
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN C
Risk Phrases:
R 21 Harmful in contact with skin.
R 35 Causes severe burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 79-36-7: 1
Canada
CAS# 79-36-7 is listed on Canada's DSL List.
CAS# 79-36-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 79-36-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/09/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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Rhodamine 6g Perchlorate, Laser Grade, 99% (TLC)
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3-Thiophenemalonic acid, 98+%
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Tripropylamine, 99+%
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1,10-Decanediol, 95% (GC)
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l-(-)-Sorbose, 99%
| 87-79-6 |
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| 1455-77-2 |
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| 312-73-2 |
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| 4602-70-4 |
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| 2138-24-1 |
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| 63696-99-1 |
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| 1835-49-0 |
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| 3326-71-4 |
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| 6373-50-8 |
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| |
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(2-Hydroxybenzoyl)methylenetriphenylphosphorane, 98%
| 0-01-1 |
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3-Acetyl-1-propanol, 96%
| 1071-73-4 |
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| 98-56-6 |
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p-Tolyl Isothiocyanate, 99%
| 622-59-3 |
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| 373-61-5 |
|
Titanium (IV) Oxide, 98.0 - 100.5% TiO2
| 13463-40-6 |
|
Ethylmercurithiosalicylic acid, sodium salt
| 54-64-8 |
|
1-Iodopentane, 97% (GC)
| 628-17-1 |
|
(4-Carboxybutyl)triphenylphosphonium bromide, 98%
| 17814-85-6 |
|
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| 79-36-7 |
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| 6402-36-4 |
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1,4-Pentadiene, 99%
| 591-93-5 |
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| 7440-45-1 |
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| 1141-06-6 |
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| 675-09-2 |
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| 4747-99-3 |
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| 51437-00-4 |
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| 93-51-6 |
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