**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 373-61-5 |Boron trifluoride - acetic acid comple| 100 % | 206-768-5 |
| |x, ca. 33% BF3 | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 22 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes severe burns.Corrosive.Moisture
sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. May cause abdominal
pain, nausea, vomiting, and inflammation of the gums and mouth.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Can burn in a fire, releasing toxic vapors.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Use spark-proof tools and explosion proof
equipment. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep under a nitrogen blanket.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Exposure Limits
CAS# 373-61-5:
United States OSHA: 2.5 mg/m3 TWA (as F) (listed under Fluorides
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear
Odor: Not available.
pH: Not available.
Vapor Pressure: 9 hPa @ 20 C
Viscosity: Not available.
Boiling Point: 140 - 148 deg C @ 760.00mm Hg
Freezing/Melting Point: -47 deg C
Autoignition Temperature: Not available.
Flash Point: 84 deg C ( 183.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts
Specific Gravity/Density: 1.3500g/cm3
Molecular Formula: BF3.C4H8O4
Molecular Weight: 187.92
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, exposure
to moist air or water, temperatures above 75C (167F).
Incompatibilities with Other Materials:
Strong oxidizing agents and metals.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas, oxides of
boron.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 373-61-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Boron trifluoride - acetic acid complex, ca. 33% BF3 -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Harmful to fish and plankton on account of Ph-shift.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BORON TRIFLUORIDE ACETIC ACID COMPLEX
Hazard Class: 8
UN Number: 1742
Packing Group: II
IMO
Shipping Name: BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID or S
OLID
Hazard Class: 8
UN Number: 1742
Packing Group: II
RID/ADR
Shipping Name: BORON TRIFLUORIDE ACETIC ACID COMPLEX
Hazard Class: 8
UN Number: 1742
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 22 Harmful if swallowed.
R 35 Causes severe burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 373-61-5: No information available.
Canada
CAS# 373-61-5 is listed on Canada's NDSL List.
CAS# 373-61-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 373-61-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
6-Aminonicotinic Acid, 98%
| 3167-49-5 |
|
Rhodamine 6g Perchlorate, Laser Grade, 99% (TLC)
| 13161-28-9 |
|
3-Thiophenemalonic acid, 98+%
| 21080-92-2 |
|
Poly(Sodium-P-Styrenesulfonate), Average M.W.100.000
| 25704-18-1 |
|
3-Cyclohexylpropionaldehyde, 99%
| 4361-28-8 |
|
Tripropylamine, 99+%
| 102-69-2 |
|
1,10-Decanediol, 95% (GC)
| 112-47-0 |
|
Cyclooctanol, 99%
| 696-71-9 |
|
l-(-)-Sorbose, 99%
| 87-79-6 |
|
6-Bromo-2-Naphthyl-Beta-D-Glucopyranoside
| 15548-61-5 |
|
1-Hexadecylsulfonic acid, sodium salt, HPLC grade
| 15015-81-3 |
|
3-Carbethoxy-4-Piperidone Hydrochloride 98% (TLC)
| 4644-61-5 |
|
1,3-Dimethylurea, 98%
| 96-31-1 |
|
Diethyl 1,4-Dihydro-2,4,6-Trimethyl- 3,5-Pyridinedicarboxylate, 99%
| 632-93-9 |
|
Dimethylthiocarbamoyl Chloride, 99% (Titr.)
| 16420-13-6 |
|
3,3',5,5'-Tetramethylbenzidine, 99+%
| 54827-17-7 |
|
3,5-Diamino-1,2,4-Triazole 98%
| 1455-77-2 |
|
2-(Trifluoromethyl)benzimidazole
| 312-73-2 |
|
(1R,2R)-(+)-1,2-Diphenyl-1,2-Ethane Diamine, 99% (99% e.e.)
| 29841-69-8 |
|
1-Methyl-7-Hydroxy-6-Methoxy-3,4-Dihydroisoquinoline, 99+%
| 4602-70-4 |
|
Amberlite IRC-50 Ion-Exchange Resin
| 9002-29-3 |
|
Tetrahexylammonium Iodide, 99% (Titr.)
| 2138-24-1 |
|
L(-)-methanesulfonylethyllactate
| 63696-99-1 |
|
Tetrafluoroterephthalonitrile, 97%
| 1835-49-0 |
|
2-Furoic acid hydrazide, 98%
| 3326-71-4 |
|
4-Cyclohexylaniline, 97%
| 6373-50-8 |
|
8-Formyl-7-methoxy-1,4-dioxa-8-azaspiro[4.5]decane, tech., 85%
| |
|
(2-Hydroxybenzoyl)methylenetriphenylphosphorane, 98%
| 0-01-1 |
|
3-Acetyl-1-propanol, 96%
| 1071-73-4 |
|
4-Chlorobenzotrifluoride, 98%
| 98-56-6 |
|
p-Tolyl Isothiocyanate, 99%
| 622-59-3 |
|
Boron trifluoride - acetic acid complex, c a. 33% bf3
| 373-61-5 |
|
Titanium (IV) Oxide, 98.0 - 100.5% TiO2
| 13463-40-6 |
|
Ethylmercurithiosalicylic acid, sodium salt
| 54-64-8 |
|
1-Iodopentane, 97% (GC)
| 628-17-1 |
|
(4-Carboxybutyl)triphenylphosphonium bromide, 98%
| 17814-85-6 |
|
Dichloroacetyl Chloride, 97%
| 79-36-7 |
|
trans-Traumatic acid, 97%
| 6402-36-4 |
|
1,4-Pentadiene, 99%
| 591-93-5 |
|
2-Chloro-p-phenylenediamine dihydrochloride, 99% (uv-vis)
| 615-46-3 |
|
Calcium 2-ethylhexanoate
| 136-51-6 |
|
N-Hydroxysuccinimide, 98+%
| 6066-82-6 |
|
2,2-Diphenylpropylamine Hydrochloride, 95%
| 40691-66-5 |
|
Cerium atomic absorption standard solution 1 mg/ml Ce in 2% HNO3
| 7440-45-1 |
|
alpha-Pyridoin, 99%
| 1141-06-6 |
|
4,6-Dimethyl-2-Pyrone, 98%
| 675-09-2 |
|
Oleic acid, sodium salt, 65-90% oleic C18
| 143-19-1 |
|
(+/-)-Tetrahydropapaveroline Hydrobromide, 98%
| 4747-99-3 |
|
5-Bromo-2-fluorotoluene, 99%
| 51437-00-4 |
|
2-Methoxy-4-Methylphenol, 99% (GC)
| 93-51-6 |
|
|