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MSDS 
:
 trans-4,4-Dimethyl-2-pentene
CAS 
:
 102-71-6
SYNONYMS 
:
 None
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| |TRANS-4,4-DIMETHYL-2-PENTENE | | unlisted |
|----------------|--------------------------------------|----------|-----------|
| 102-71-6 |Triethanolamine | 31.0 | 203-049-8 |
|----------------|--------------------------------------|----------|-----------|
| 141-43-5 |Ethanolamine | 19.0 | 205-483-3 |
|----------------|--------------------------------------|----------|-----------|
| 12069-69-1 |Copper(II) carbonate hydroxide | 3.07 | 235-113-6 |
|----------------|--------------------------------------|----------|-----------|
| 31075-24-8 |Polyoxyethylen(dimethylimino)ethylene(| 26.0 | unlisted |
| |dimethylimino)ethylene dichloride | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38 20

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Harmful by
inhalation.Corrosive.

Potential Health Effects
Eye:
Causes severe eye irritation. Causes eye burns.
Skin:
May be absorbed through the skin in harmful amounts. Exposure may
cause irritation and possible burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by headache, dizziness, unconsciousness and
coma. Causes respiratory tract irritation.
Chronic:
Not available.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Destroy contaminated shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors mixed with air can explode when ignited.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then
place into a chemical waste container. Remove all sources of
ignition.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134. Always use a NIOSH-approved respirator when
necessary.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid
Appearance: Not available.
Odor: Slight odor.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Decomposition Temperature: Not available.
Solubility: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: Not available.
Molecular Weight: Not available.

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, ignition sources, acids, excess heat, strong
acids, strong oxidants, nitrites.
Incompatibilities with Other Materials:
Ethanolamine is incompatible with strong oxidizing agents, acids, and
bases. It attacks some forms of plastics, rubber and coatings. Avoid
contact with strong acids and nitrites.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# unlisted.
CAS# 102-71-6: KL9275000
CAS# 141-43-5: KJ5775000
CAS# 12069-69-1: GL6910000
CAS# 31075-24-8 unlisted.
LD50/LC50:
Not available.
CAS# 102-71-6: Oral, mouse: LD50 = 5846 mg/kg; Oral, rabbit: LD50 =
2200 mg/kg; Oral, rat: LD50 = 8 gm/kg; Skin, rabbit: LD50 = >20
gm/kg.
CAS# 141-43-5: Oral, mouse: LD50 = 700 mg/kg; Oral, rabbit: LD50 = 1
gm/kg; Oral, rat: LD50 = 1720 mg/kg; Skin, rabbit: LD50 = 1 gm/kg.
CAS# 12069-69-1: Oral, rabbit: LD50 = 159 mg/kg; Oral, rat: LD50 =
1350 mg/kg.
CAS# 31075-24-8.
Carcinogenicity:
TRANS-4,4-DIMETHYL-2-PENTENE -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Triethanolamine -
IARC: Group 3 carcinogen
Ethanolamine -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Copper(II) carbonate hydroxide -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Polyoxyethylen(dimethylimino)ethylene(dimethylimino)ethylene
dichloride -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

For further information, contact Fisher Scientific.

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

CDG/CPL
IMO
Not regulated as a hazardous material.
IATA
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Canadian TDG
No information available.

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 20 Harmful by inhalation.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# :
CAS# 102-71-6: 1
CAS# 141-43-5: 1
CAS# 12069-69-1:
CAS# 31075-24-8: 2
Canada
CAS# 102-71-6 is listed on Canada's DSL/NDSL List.
CAS# 141-43-5 is listed on Canada's DSL/NDSL List.
CAS# 12069-69-1 is listed on Canada's DSL/NDSL List.
CAS# 31075-24-8 is listed on Canada's DSL/NDSL List.
This product has a WHMIS classification of D2B.
CAS# is not listed on Canada's Ingredient Disclosure List.
CAS# 102-71-6 is listed on Canada's Ingredient Disclosure List.
CAS# 141-43-5 is listed on Canada's Ingredient Disclosure List.
CAS# 12069-69-1 is listed on Canada's Ingredient Disclosure List.
CAS# 31075-24-8 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 102-71-6:. OEL-SWEDEN:TWA 5 mg/m3;STEL 10 mg/m3
CAS# 141-43-5:. OEL-ARAB Republic of Egypt:TWA 3 ppm (6 mg/m3). OEL-A
USTRALIA:TWA 3 ppm (8 mg/m3);STEL 6 ppm (15 mg/m3). OEL-BELGIUM:TWA 3
ppm (7.5 mg/m3);STEL 6 ppm (15 mg/m3). OEL-DENMARK:TWA 6 ppm (6 mg/m3)
. OEL-FINLAND:TWA 3 ppm (7.5 mg/m3);STEL 6 ppm (15 mg/m3). OEL-FRANCE:
TWA 3 ppm (8 mg/m3). OEL-GERMANY:TWA 3 ppm (8 mg/m3). OEL-JAPAN:TWA 3
ppm (7.5 mg/m3). OEL-THE NETHERLANDS:TWA 3 ppm (8 mg/m3). OEL-THE PHIL
IPPINES:TWA 3 ppm (6 mg/m3). OEL-RUSSIA:TWA 3 ppm;STEL 0.5 mg/m3;Skin

OEL-SWITZERLAND:TWA 3 ppm (7.5 mg/m3);STEL 15 ppm (37.5 mg/m3). OEL-U
NITED KINGDOM:TWA 3 ppm (8 mg/m3);STEL 6 ppm (15 mg/m3). OEL IN BULGAR
IA, COLOMBIA, JORDAN, KOREA check ACGIH TLV. OEL IN NEW ZEALAND, SINGA
PORE, VIETNAM check ACGI TLV
CAS# 12069-69-1:. OEL-ARAB Republic of Egypt:TWA 0.1 mg(Cu)/m3 (fume)
. OEL-AUSTRALIA:TWA 0.2 mg(Cu)/m3 (fume). OEL-AUSTRALIA:TWA 1 mg(Cu)/m
3 (dust). OEL-BELGIUM:TWA 0.2 mg(Cu)/m3 (fume). OEL-BELGIUM:TWA 1 mg(C
u)/m3 (dust). OEL-DENMARK:TWA 0.1 mg(Cu)/m3 (fume). OEL-DENMARK:TWA 1
mg(Cu)/m3 (dust). OEL-FINLAND:TWA 0.2 mg(Cu)/m3 (fume). OEL-FINLAND:TW
A 1 mg(Cu)/m3. OEL-FINLAND:TWA 1 mg(Cu)/m3 (dust). OEL-FRANCE:TWA 0.2
mg(Cu)/m3 (fume). OEL-FRANCE:TWA 1 mg(Cu)/m3;STEL 2 mg(Cu)/m3 (dust. O
EL-GERMANY:TWA 0.1 mg(Cu)/m3 (fume). OEL-GERMANY:TWA 1 mg(Cu)/m3. OEL-
GERMANY:TWA 1 mg(Cu)/m3 (dust). OEL-HUNGARY:TWA 0.2 mg(Cu)/m3;STEL 0.4
mg(Cu)/m3 (dust). OEL-INDIA:TWA 0.2 mg(Cu)/m3 (fume). OEL-THE NETHERL
ANDS:TWA 02 mg(Cu)/m3 (fume). OEL-THE NETHERLANDS:TWA 1 mg(Cu)/m3 (dus
t). OEL-THE PHILIPPINES:TWA 1.0 mg(Cu)/m3 (fume) JAN9. OEL-POLAND:TWA
0.1 mg(Cu)/m3 (fume). OEL-RUSSIA:STEL 0.5 ppm (1 mg(Cu)/m3) (dust) JAN
9. OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (resp. dust). OEL-SWEDEN:TWA 0.2 mg(Cu
)/m3 (fume). OEL-SWEDEN:TWA 1 mg(Cu)/m3 (total dust). OEL-SWITZERLAND:
TWA 0.1 mg(Cu)/m3;STEL 0.2 mg(Cu)/m3 (fume)
Cu)/m3;STEL 1 mg(Cu)/m3
AILAND:TWA 1 mg(Cu)/m3
US FEDERAL
TSCA
CAS# is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 102-71-6 is listed on the TSCA inventory.
CAS# 141-43-5 is listed on the TSCA inventory.
CAS# 12069-69-1 is listed on the TSCA inventory.
CAS# 31075-24-8 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 9/01/1995 Revision #1 Date: 3/04/1996

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------


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