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MSDS 
:
 Tris Borate EDTA 10X Solution
CAS 
:
 60-00-4
SYNONYMS 
:
 Triethanolamine-Boric Acid-EDTA Solution
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 60-00-4 |Ethylenediaminetetraacetic acid (EDTA)| <1 | 200-449-4 |
|----------------|--------------------------------------|----------|-----------|
| 77-86-1 |Tris (hydroxymethyl) aminomethane | 10.8 | 201-064-4 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 83 | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 10043-35-3 |Boric acid | ~6.0 | 233-139-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Not available.

Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. May cause kidney
damage. May cause central nervous system effects.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic poisoning by boron compounds, borism, may be little more
than dry skin and mucous membranes, followed by appearance of a red
tongue, patchy alopecia (hair loss), cracked lips, and
conjunctivitis. Prolonged absorption of boron compounds may cause
anorexia, vomiting, mild diarrhea, skin rash, alopecia, convulsions,
weakness, confusion, menstrual disorders, and anemia.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid if irritation develops or persists. Wash clothing
before reuse. Flush skin with plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Provide
ventilation.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
containers tightly closed.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 60-00-4:

CAS# 77-86-1:

CAS# 7732-18-5:

CAS# 10043-35-3:

Russia: 10 mg/m3 TWA

Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid
Color: Clear
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: Mixture
Molecular Weight: 0

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Decarboxylates above 150C.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
EDTA is incompatible with: strong oxidizing agents, strong bases,
copper, copper alloys, aluminum. Tris is incompatible with strong
oxidizing agents, strong acids and strong bases. Boric acid is
incompatible with acetic anhydride and potassium. Forms borate salts
with basic compounds.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, nitrogen oxides (NOx) and ammonia
(NH3).
Hazardous Polymerization: Will not occur.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 60-00-4: AH4025000
CAS# 77-86-1: TY2900000
CAS# 7732-18-5: ZC0110000
CAS# 10043-35-3: ED4550000 ED4560000
LD50/LC50:
CAS# 60-00-4: Oral, mouse: LD50 = 30 mg/kg.
CAS# 77-86-1: Oral, rat: LD50 = 5900 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 10043-35-3: Oral, mouse: LD50 = 3450 mg/kg; Oral, rat: LD50 =
2660 mg/kg; Oral, rat: LD50 = 2500 mg/kg.
Carcinogenicity:
Ethylenediaminetetraacetic acid (EDTA) -
Not listed by ACGIH, IARC, or NTP.
Tris (hydroxymethyl) aminomethane -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Boric acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
EDTA: Catfish (tap water) 129ppm/96H.

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 60-00-4: 5000 lb final RQ; 2270 kg final RQ

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 60-00-4: 2
CAS# 77-86-1: 1
CAS# 7732-18-5: No information available.
CAS# 10043-35-3: 1
Canada
CAS# 60-00-4 is listed on Canada's DSL List.
CAS# 77-86-1 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 10043-35-3 is listed on Canada's DSL List.
CAS# 60-00-4 is not listed on Canada's Ingredient Disclosure List.
CAS# 77-86-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 10043-35-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 60-00-4 is listed on the TSCA inventory.
CAS# 77-86-1 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 10043-35-3 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

Text for R-phrases from Section 2
MSDS Creation Date: 7/15/1999 Revision #3 Date: 10/05/2004

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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