**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 104170-16-3 |Tetraphenylarsonium Chloride Monohydra| ca. 100% | unlisted |
| |te | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 23/25 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation and if swallowed. Very toxic to aquatic
organisms, may cause long-term adverse effects in the aquatic
environment.The toxicological properties of this material have not
been fully investigated.Cancer suspect agent.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Harmful if
inhaled.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Containers
may explode when heated. Non-combustible, substance itself does not
burn but may decompose upon heating to produce corrosive and/or
toxic fumes. Runoff from fire control or dilution water may cause
pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. Do NOT use straight streams of water. For small
fires, use dry chemical, carbon dioxide, or water spray. For large
fires, use water spray, fog or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Do not breathe dust,
vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Avoid ingestion and inhalation. Use
only in a chemical fume hood.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 104170-16-3:
United Kingdom, WEL - TWA: (listed as arsenic compounds, n.o.s.):
mg/m3 TWA (except arsine, as As)
United Kingdom, WEL - STEL: (listed as arsenic compounds, n.o.s.)
0.3 mg/m3 STEL (except arsine, as As)
Japan: (listed as arsenic compounds, n.o.s.): 3 ??g/m3 OEL (refere
value, as As)
Spain: (listed as arsenic compounds, n.o.s.): 0.1 mg/m3 VLA-ED (a
As)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: very slightly beige
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 258 - 260 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density:
Molecular Formula: (C6H5)4AsCl.H2O
Molecular Weight: 436.82
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, oxides of arsenic.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 104170-16-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetraphenylarsonium Chloride Monohydrate -
IARC: Group 1 carcinogen (listed as Arsenic compounds, n.o.s.).
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ORGANOARSENIC COMPOUND, N.O.S.*
Hazard Class: 6.1
UN Number: 3280
Packing Group: II
IMO
Shipping Name: ORGANOARSENIC COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3280
Packing Group: II
RID/ADR
Shipping Name: ORGANOARSENIC COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3280
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/25 Toxic by inhalation and if swallowed.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 20/21 When using do not eat, drink or smoke.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 104170-16-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 104170-16-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 104170-16-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Acetylfuran, 99%
| 1192-62-7 |
|
Alizarin Complexon
| 3952-78-1 |
|
1-Phenylnaphthalene, 96% (gc)
| 605-02-7 |
|
Tetraphenylarsonium chloride monohydrate, p.a.
| 104170-16-3 |
|
VMA, 99%
| 55-10-7 |
|
3-Aminophthalimide
| 2518-24-3 |
|
Fast blue bb salt
| 15518-68-0 |
|
(R)-4-Ethenyl-1,3-Dioxolan-2-One, 99% (GC)
| |
|
Ammonium Hexachloroosmate(IV)
| 12125-08-5 |
|
3-Chloropropionaldehyde diethyl acetal, tech.
| 35573-93-4 |
|
Tin(IV) Bromide, 99%
| 7789-67-5 |
|
2-Amino-6-Chloropurine-9-Riboside, 99%
| 2004-07-1 |
|
Cyclopropylamine, 99% (GC)
| 765-30-0 |
|
3-Phenyl-1-propanol, 98%
| 122-97-4 |
|
4-Chloro-2-methylphenol, 97%
| 1570-64-5 |
|
2,6-Dichloroaniline, 98%
| 608-31-1 |
|
1,3-Dimethoxy-4-tert-butylcalix[4]arene, 99% (tlc)
| 122406-45-5 |
|
Tetrabutylammonium Hydrogen Sulfate Premixed Concentrate (low UV)
| 32503-27-8 |
|
1-Phenyl-1,2-propanedione, 99%
| 579-07-7 |
|
1-Methyl-2-pyridone, 99+%
| 694-85-9 |
|
3-Buten-2-ol, 99%
| 598-32-3 |
|
2,5-Dihydroxy-p-benzoquinone, 98%
| 615-94-1 |
|
4-Methylpyrazole, 99%
| 7554-65-6 |
|
3-Bromo-2-chlorothiophene,97%
| 40032-73-3 |
|
2,6-Dichlorobenzyl Methyl Ether, 98%
| 33486-90-7 |
|
(S)-(-)-2-Azetidinecarboxylic Acid, 99+%
| 2133-34-8 |
|
1,5-Dichloroanthraquinone, 96%
| 82-46-2 |
|
Methyl p-toluenesulfonate, 97%
| 80-48-8 |
|
Benzoic Anhydride, 98%
| 93-97-0 |
|
2-Naphthoic acid, 99%
| 93-09-4 |
|
N-Benzylpseudopelletierine, 96%
| 0-00-1 |
|
3-(Trifluoromethoxy)benzaldehyde
| 52771-21-8 |
|
(R)-(-)-gamma-Toluenesulfonylmethyl-gamma-butyrolactone, 98+%
| 58879-33-7 |
|
Diethyl 1,1-cyclopropanedicarboxylate, 97%
| 1559-02-0 |
|
Phenyl Phosphate, Disodium Salt Sesquihydrate, 93% (UV-VIS)
| 3279-54-7 |
|
1-Methyl-2-tetralone, tech., 90%
| 4024-14-0 |
|
4-Ethylnitrobenzene, 99+%
| 100-12-9 |
|
Toluene-d8, 100.0 atom % D
| 2037-26-5 |
|
2-Chloro-N-(2,6-Dichlorophenyl)-Acetamide 99%
| 3644-56-2 |
|
2-Aminoethyl Hydrogen Sulfate, 99% (Titr.)
| 926-39-6 |
|
2-Isobutylthiazole, 99%
| 18640-74-9 |
|
Tris(hydroxymethyl)aminomethane
| 77-86-1 |
|
1-Phenyl-1-propyne, 99%
| 673-32-5 |
|
Methyl 2-furoate, 98%
| 611-13-2 |
|
Hexyl Alcohol (Pract), 96% (GC)
| 111-27-3 |
|
N,N-Diethylacetamide, 99%
| 685-91-6 |
|
Ammonium Hexafluorogermanate(IV), 99.999%
| 16962-47-3 |
|
2-Butyn-1-Al Diethyl Acetal, 98%
| 2806-97-5 |
|
1,3-Diphenoxybenzene, 99% (GC)
| 3379-38-2 |
|
Sodium Phosphate Tribasic Dodecahydrate
| 7601-54-9 |
|
|