**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1570-64-5 |4-Chloro-2-methylphenol | 97 | 216-381-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T C N
Risk Phrases: 23 35 50
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation. Causes severe burns. Very toxic to aquatic
organisms.Dangerous for the environment.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. May cause liver and kidney
damage. May cause cardiac disturbances. May cause central nervous
system effects.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause liver and kidney damage. Causes chemical burns to
the respiratory tract. May cause cardiac abnormalities.
Chronic:
May cause liver and kidney damage. Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Containers may explode when heated. Runoff from fire control or
dilution water may cause pollution.
Extinguishing Media:
Do NOT get water inside containers. Do NOT use straight streams of
water. For small fires, use dry chemical, carbon dioxide, or water
spray. For large fires, use water spray, fog or regular foam. Cool
containers with flooding quantities of water until well after fire is
out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Do not
get in eyes, on skin, or on clothing. Keep container tightly closed.
Do not breathe dust. Use only with adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1570-64-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: off-white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 220 - 225 deg C @ 760 mmHg
Freezing/Melting Point: 45-48 deg C
Autoignition Temperature: Not applicable.
Flash Point: 106 deg C ( 222.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble
Specific Gravity/Density:
Molecular Formula: C7H7ClO
Molecular Weight: 142.58
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, bases, acid chlorides, brass, copper, copper
alloys, steel, acid anhydrides.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1570-64-5: GO7120000
LD50/LC50:
CAS# 1570-64-5: Oral, mouse: LD50 = 1320 mg/kg.
Carcinogenicity:
4-Chloro-2-methylphenol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CHLOROCRESOLS, SOLID
Hazard Class: 6.1
UN Number: 2669
Packing Group: II
IMO
Shipping Name: CHLOROCRESOLS, SOLID
Hazard Class: 6.1
UN Number: 2669
Packing Group: II
RID/ADR
Shipping Name: CHLOROCRESOLS
Hazard Class: 6.1
UN Number: 2669
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T C N
Risk Phrases:
R 23 Toxic by inhalation.
R 35 Causes severe burns.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 1570-64-5: 2
Canada
CAS# 1570-64-5 is listed on Canada's NDSL List.
CAS# 1570-64-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1570-64-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 5/21/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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3-Aminophthalimide
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(R)-4-Ethenyl-1,3-Dioxolan-2-One, 99% (GC)
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Ammonium Hexachloroosmate(IV)
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| 32503-27-8 |
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| 579-07-7 |
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1-Methyl-2-pyridone, 99+%
| 694-85-9 |
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3-Buten-2-ol, 99%
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2,5-Dihydroxy-p-benzoquinone, 98%
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3-Bromo-2-chlorothiophene,97%
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| 2133-34-8 |
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1,5-Dichloroanthraquinone, 96%
| 82-46-2 |
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Methyl p-toluenesulfonate, 97%
| 80-48-8 |
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Benzoic Anhydride, 98%
| 93-97-0 |
|
2-Naphthoic acid, 99%
| 93-09-4 |
|
N-Benzylpseudopelletierine, 96%
| 0-00-1 |
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3-(Trifluoromethoxy)benzaldehyde
| 52771-21-8 |
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| 58879-33-7 |
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Diethyl 1,1-cyclopropanedicarboxylate, 97%
| 1559-02-0 |
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Phenyl Phosphate, Disodium Salt Sesquihydrate, 93% (UV-VIS)
| 3279-54-7 |
|
1-Methyl-2-tetralone, tech., 90%
| 4024-14-0 |
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4-Ethylnitrobenzene, 99+%
| 100-12-9 |
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Toluene-d8, 100.0 atom % D
| 2037-26-5 |
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2-Chloro-N-(2,6-Dichlorophenyl)-Acetamide 99%
| 3644-56-2 |
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| 926-39-6 |
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| 77-86-1 |
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| 673-32-5 |
|
Methyl 2-furoate, 98%
| 611-13-2 |
|
Hexyl Alcohol (Pract), 96% (GC)
| 111-27-3 |
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| 685-91-6 |
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| 16962-47-3 |
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2-Butyn-1-Al Diethyl Acetal, 98%
| 2806-97-5 |
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