**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-27-3 |Hexyl Alcohol | 96 | 203-852-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause respiratory tract irritation.
Chronic:
Prolonged exposure may produce a narcotic effect.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal. Remove all sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Do not get on skin or
in eyes. Avoid ingestion and inhalation. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colourless
Odor: none reported
pH: Not available.
Vapor Pressure: 1 mm Hg @ 24.4 C
Viscosity: 5.3mPas @ 20C
Boiling Point: 157 deg C
Freezing/Melting Point: -52 deg C
Autoignition Temperature: 293 deg C ( 559.40 deg F)
Flash Point: 62 deg C ( 143.60 deg F)
Explosion Limits, lower: 1.2.
Explosion Limits, upper: 7.7
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 0.82
Molecular Formula: C6H14O
Molecular Weight: 102.0974
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition
sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-27-3: MQ4025000
LD50/LC50:
CAS# 111-27-3: Oral, mouse: LD50 = 1950 mg/kg; Oral, mouse: LD50 =
1950 mg/kg; Oral, rat: LD50 = 720 mg/kg; Oral, rat: LD50 = 710 mg/kg;
Skin, rabbit: LD50 = 3100 uL/kg.
Carcinogenicity:
Hexyl Alcohol -
Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: HEXANOLS
Hazard Class: 3
UN Number: 2282
Packing Group: III
IMO
Shipping Name: HEXANOLS
Hazard Class: 3.3
UN Number: 2282
Packing Group: III
RID/ADR
Shipping Name: HEXANOLS
Hazard Class: 3
UN Number: 2282
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 111-27-3: 1
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 111-27-3 is listed on Canada's DSL List.
CAS# 111-27-3 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 111-27-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/05/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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2-Acetylfuran, 99%
| 1192-62-7 |
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Alizarin Complexon
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1-Phenylnaphthalene, 96% (gc)
| 605-02-7 |
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Tetraphenylarsonium chloride monohydrate, p.a.
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VMA, 99%
| 55-10-7 |
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3-Aminophthalimide
| 2518-24-3 |
|
Fast blue bb salt
| 15518-68-0 |
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(R)-4-Ethenyl-1,3-Dioxolan-2-One, 99% (GC)
| |
|
Ammonium Hexachloroosmate(IV)
| 12125-08-5 |
|
3-Chloropropionaldehyde diethyl acetal, tech.
| 35573-93-4 |
|
Tin(IV) Bromide, 99%
| 7789-67-5 |
|
2-Amino-6-Chloropurine-9-Riboside, 99%
| 2004-07-1 |
|
Cyclopropylamine, 99% (GC)
| 765-30-0 |
|
3-Phenyl-1-propanol, 98%
| 122-97-4 |
|
4-Chloro-2-methylphenol, 97%
| 1570-64-5 |
|
2,6-Dichloroaniline, 98%
| 608-31-1 |
|
1,3-Dimethoxy-4-tert-butylcalix[4]arene, 99% (tlc)
| 122406-45-5 |
|
Tetrabutylammonium Hydrogen Sulfate Premixed Concentrate (low UV)
| 32503-27-8 |
|
1-Phenyl-1,2-propanedione, 99%
| 579-07-7 |
|
1-Methyl-2-pyridone, 99+%
| 694-85-9 |
|
3-Buten-2-ol, 99%
| 598-32-3 |
|
2,5-Dihydroxy-p-benzoquinone, 98%
| 615-94-1 |
|
4-Methylpyrazole, 99%
| 7554-65-6 |
|
3-Bromo-2-chlorothiophene,97%
| 40032-73-3 |
|
2,6-Dichlorobenzyl Methyl Ether, 98%
| 33486-90-7 |
|
(S)-(-)-2-Azetidinecarboxylic Acid, 99+%
| 2133-34-8 |
|
1,5-Dichloroanthraquinone, 96%
| 82-46-2 |
|
Methyl p-toluenesulfonate, 97%
| 80-48-8 |
|
Benzoic Anhydride, 98%
| 93-97-0 |
|
2-Naphthoic acid, 99%
| 93-09-4 |
|
N-Benzylpseudopelletierine, 96%
| 0-00-1 |
|
3-(Trifluoromethoxy)benzaldehyde
| 52771-21-8 |
|
(R)-(-)-gamma-Toluenesulfonylmethyl-gamma-butyrolactone, 98+%
| 58879-33-7 |
|
Diethyl 1,1-cyclopropanedicarboxylate, 97%
| 1559-02-0 |
|
Phenyl Phosphate, Disodium Salt Sesquihydrate, 93% (UV-VIS)
| 3279-54-7 |
|
1-Methyl-2-tetralone, tech., 90%
| 4024-14-0 |
|
4-Ethylnitrobenzene, 99+%
| 100-12-9 |
|
Toluene-d8, 100.0 atom % D
| 2037-26-5 |
|
2-Chloro-N-(2,6-Dichlorophenyl)-Acetamide 99%
| 3644-56-2 |
|
2-Aminoethyl Hydrogen Sulfate, 99% (Titr.)
| 926-39-6 |
|
2-Isobutylthiazole, 99%
| 18640-74-9 |
|
Tris(hydroxymethyl)aminomethane
| 77-86-1 |
|
1-Phenyl-1-propyne, 99%
| 673-32-5 |
|
Methyl 2-furoate, 98%
| 611-13-2 |
|
Hexyl Alcohol (Pract), 96% (GC)
| 111-27-3 |
|
N,N-Diethylacetamide, 99%
| 685-91-6 |
|
Ammonium Hexafluorogermanate(IV), 99.999%
| 16962-47-3 |
|
2-Butyn-1-Al Diethyl Acetal, 98%
| 2806-97-5 |
|
1,3-Diphenoxybenzene, 99% (GC)
| 3379-38-2 |
|
Sodium Phosphate Tribasic Dodecahydrate
| 7601-54-9 |
|
|